A spatio-temporal geostatistical approach to predicting pollution levels: The case of mono-nitrogen oxides in Madrid

Abstract In spite of the effort made in the last years, NO x is still one of the main pollution problems in large cities. This is why the literature related to predicting NO x levels is certainly extensive. However, most of this literature does not take into account the spatio-temporal dependencies of such NO x levels. As spatio-temporal dependencies are a core aspect of pollution, we propose both a spatio-temporal kriging and a functional kriging strategy to incorporate such dependencies into the prediction procedure. We also use an innovative method for estimating the parameters of the non separable space–time covariance function involved in the spatio-temporal kriging strategy, which significantly reduces the computational burden of traditional likelihood-based methods. The empirical study focuses on Madrid City and is backed by a massive hourly database. Results indicate that the functional strategy outperforms the spatio-temporal procedure at non peripheral sites, which is a remarkable finding due to the high computational requirements of spatio-temporal kriging.

[1]  J. Schwartz,et al.  Associations Between Measures of Socioeconomic Position and Chronic Nitrogen Dioxide Exposure in Worcester, Massachusetts , 2008, Journal of toxicology and environmental health. Part A.

[2]  Subhash R. Lele,et al.  A composite likelihood approach to semivariogram estimation , 1999 .

[3]  José Manuel Palma-Oliveira,et al.  Air Quality Monitoring and Management in Lisbon , 2000 .

[4]  Gavin C. Cawley,et al.  Extensive evaluation of neural network models for the prediction of NO2 and PM10 concentrations, compared with a deterministic modelling system and measurements in central Helsinki , 2003 .

[5]  M. Fuentes Approximate Likelihood for Large Irregularly Spaced Spatial Data , 2007, Journal of the American Statistical Association.

[6]  Modelling of nitrogen dioxide (NO2) and fine particulate matter (PM10) air pollution in the metropolitan areas of Barcelona and Bilbao, Spain , 2009 .

[7]  Ravendra Singh,et al.  Nonlinear Dynamical Characterization and Prediction of Ambient Nitrogen Dioxide Concentration , 2005 .

[8]  D. E. Myers,et al.  Nonseparable Space-Time Covariance Models: Some Parametric Families , 2002 .

[9]  Michael L. Stein,et al.  Statistical methods for regular monitoring data , 2005 .

[10]  Brigitte Buchmann,et al.  Ozone, carbon monoxide and nitrogen oxides time series at four alpine GAW mountain stations in central Europe , 2010 .

[11]  S. Vitabile,et al.  Two-days ahead prediction of daily maximum concentrations of SO2, O3, PM10, NO2, CO in the urban area of Palermo, Italy , 2007 .

[12]  L. Tsimring,et al.  The analysis of observed chaotic data in physical systems , 1993 .

[13]  P. Switzer,et al.  The variability of rainfall acidity , 1983 .

[14]  O Obodeh,et al.  Evaluation of Artificial Neural Network Performance in Predicting Diesel Engine NOx Emissions , 2009 .

[15]  P. Badari Narayana,et al.  Application of Artificial Neural Networks for Emission Modelling of Biodiesels for a C.I Engine under Varying Operating Conditions , 2010 .

[16]  J. Ramsay,et al.  Some Tools for Functional Data Analysis , 1991 .

[17]  A simple spatio‐temporal procedure for the prediction of air pollution levels , 2002 .

[18]  Phaedon C. Kyriakidis,et al.  Stochastic modeling of atmospheric pollution: a spatial time-series framework. Part II: application to monitoring monthly sulfate deposition over Europe , 2001 .

[19]  Grégoire Dubois,et al.  Spatial Correlation Analysis of Nitrogen Dioxide Concentrations in the Area of Milan, Italy , 2002 .

[20]  Noel A Cressie,et al.  Statistics for Spatio-Temporal Data , 2011 .

[21]  Sancho Salcedo-Sanz,et al.  Spatial regression analysis of NOx and O3 concentrations in Madrid urban area using Radial Basis Function networks , 2009 .

[22]  G. Christakos,et al.  Spatiotemporal analysis and mapping of sulfate deposition data over Eastern U.S.A. , 1997 .

[23]  M. Gardner,et al.  Neural network modelling and prediction of hourly NOx and NO2 concentrations in urban air in London , 1999 .

[24]  J. Ayres,et al.  Air pollution and the heart. , 2005, Occupational medicine.

[25]  S. De Iaco,et al.  Space-time variograms and a functional form for total air pollution measurements , 2002, Comput. Stat. Data Anal..

[26]  Clemens Mensink,et al.  Spatial interpolation of air pollution measurements using CORINE land cover data , 2008 .

[27]  Alfred Stein,et al.  External drift kriging of NOx concentrations with dispersion model output in a reduced air quality monitoring network , 2009, Environmental and Ecological Statistics.

[28]  M. Ardestani,et al.  DETERMINATION OF AIR POLLUTION MONITORING STATIONS , 2008 .

[29]  Rong Chen,et al.  Ozone Exposure and Population Density in Harris County, Texas , 1997 .

[30]  D. E. Myers,et al.  The Linear Coregionalization Model and the Product–Sum Space–Time Variogram , 2003 .

[31]  Phaedon C. Kyriakidis,et al.  Geostatistical Space–Time Models: A Review , 1999 .

[32]  Jan van de Kassteele,et al.  A model for external drift kriging with uncertain covariates applied to air quality measurements and dispersion model output , 2006 .

[33]  Description of the seasonal pattern in ozone concentration time series by using the strange attractor multifractal formalism , 2010, Environmental monitoring and assessment.

[34]  Jo Eidsvik,et al.  A class of covariate-dependent spatiotemporal covariance functions. , 2011, The annals of applied statistics.

[35]  Douglas W. Nychka,et al.  Covariance Tapering for Likelihood-Based Estimation in Large Spatial Data Sets , 2008 .

[36]  Donato Posa,et al.  Total Air Pollution And Space-Time Modelling , 2001 .

[37]  Mike Rees,et al.  5. Statistics for Spatial Data , 1993 .

[38]  Jorge Mateu,et al.  Estimating Space and Space-Time Covariance Functions for Large Data Sets: A Weighted Composite Likelihood Approach , 2012 .

[39]  M. Sherman Spatial Statistics and Spatio-Temporal Data: Covariance Functions and Directional Properties , 2010 .

[40]  T. Holford,et al.  Modeling effects of traffic and landscape characteristics on ambient nitrogen dioxide levels in Connecticut. , 2010, Atmospheric Environment.

[41]  Timothy C. Haas,et al.  Statistical assessment of spatio-temporal pollutant trends and meteorological transport models , 1998 .

[42]  Daehyon Kim,et al.  Application of Neural Network Model to Vehicle Emissions , 2010 .

[43]  Richard A. Bilonick,et al.  The space-time distribution of sulfate deposition in the northeastern United States , 1985 .

[44]  D. Myers,et al.  Space–time analysis using a general product–sum model , 2001 .

[45]  Noel A Cressie,et al.  Statistics for Spatial Data. , 1992 .

[46]  Peter Guttorp,et al.  A simple non-separable, non-stationary spatiotemporal model for ozone , 2009, Environmental and Ecological Statistics.

[47]  Irma J. Terpenning,et al.  STL : A Seasonal-Trend Decomposition Procedure Based on Loess , 1990 .

[48]  J. Sánchez-Ollero,et al.  A Threshold Autoregressive Asymmetric Stochastic Volatility Strategy to Alert of Violations of the Air Quality Standards , 2011 .

[49]  Ramon Giraldo Henao,et al.  Geostatistical analysis of functional data , 2009 .

[50]  T. Gneiting Nonseparable, Stationary Covariance Functions for Space–Time Data , 2002 .

[51]  Guohe Huang,et al.  A stepwise cluster analysis method for predicting air quality in an urban environment , 1992 .

[52]  Marija Zlata Boznar,et al.  A neural network-based method for short-term predictions of ambient SO2 concentrations in highly polluted industrial areas of complex terrain , 1993 .

[53]  David M Stieb,et al.  Meta-Analysis of Time-Series Studies of Air Pollution and Mortality: Effects of Gases and Particles and the Influence of Cause of Death, Age, and Season , 2002, Journal of the Air & Waste Management Association.

[54]  Donato Posa,et al.  Product‐sum covariance for space‐time modeling: an environmental application , 2001 .

[55]  Gavin C. Cawley,et al.  Maximum likelihood cost functions for neural network models of air quality data , 2003 .

[56]  A. V. Vecchia Estimation and model identification for continuous spatial processes , 1988 .

[57]  Jorge Mateu,et al.  Statistics for spatial functional data: some recent contributions , 2009 .

[58]  Li Chen,et al.  A class of nonseparable and nonstationary spatial temporal covariance functions , 2008, Environmetrics.

[59]  Margaret Bell,et al.  Risks of exceeding the hourly EU limit value for nitrogen dioxide resulting from increased road transport emissions of primary nitrogen dioxide , 2007 .

[60]  A. B. Chelani,et al.  Forecasting nitrogen dioxide concentration in ambient air using artificial Neural‐networks , 2001 .

[61]  P. Grassberger,et al.  NONLINEAR TIME SEQUENCE ANALYSIS , 1991 .

[62]  Guozhu Mao,et al.  A Bayesian hierarchical model for urban air quality prediction under uncertainty , 2008 .

[63]  P. Haan Applied comprehensive NO2 and particulate matter dispersion modelling for Switzerland , 2009 .

[64]  P. Vieu,et al.  Nonparametric Functional Data Analysis: Theory and Practice (Springer Series in Statistics) , 2006 .