Scaling Effect on Silicon Nitride Memristor with Highly Doped Si Substrate.

A feasible approach is reported to reduce the switching current and increase the nonlinearity in a complementary metal-oxide-semiconductor (CMOS)-compatible Ti/SiNx /p+ -Si memristor by simply reducing the cell size down to sub-100 nm. Even though the switching voltages gradually increase with decreasing device size, the reset current is reduced because of the reduced current overshoot effect. The scaled devices (sub-100 nm) exhibit gradual reset switching driven by the electric field, whereas that of the large devices (≥1 µm) is driven by Joule heating. For the scaled cell (60 nm), the current levels are tunable by adjusting the reset stop voltage for multilevel cells. It is revealed that the nonlinearity in the low-resistance state is attributed to Fowler-Nordheim tunneling dominating in the high-voltage regime (≥1 V) for the scaled cells. The experimental findings demonstrate that the scaled metal-nitride-silicon memristor device paves the way to realize CMOS-compatible high-density crosspoint array applications.

[1]  Sung-Jin Choi,et al.  Compact Two-State-Variable Second-Order Memristor Model. , 2016, Small.

[2]  Byung-Gook Park,et al.  Improved resistive switching characteristics in Ni/SiNx/p++-Si devices by tuning x , 2017 .

[3]  Fei Zeng,et al.  Forming-free and self-rectifying resistive switching of the simple Pt/TaOx/n-Si structure for access device-free high-density memory application. , 2015, Nanoscale.

[4]  Simon M. Sze,et al.  Nitrogen Buffering Effect on Oxygen in Indium-Tin-Oxide-Capped Resistive Random Access Memory With NH3 Treatment , 2015, IEEE Electron Device Letters.

[5]  Ru Huang,et al.  Self-selection effects and modulation of TaOx resistive switching random access memory with bottom electrode of highly doped Si , 2016 .

[6]  Rainer Waser,et al.  Complementary resistive switches for passive nanocrossbar memories. , 2010, Nature materials.

[7]  Adnan Mehonic,et al.  Electrically tailored resistance switching in silicon oxide , 2012, Nanotechnology.

[8]  Fei Zhou,et al.  Demonstration of Synaptic Behaviors and Resistive Switching Characterizations by Proton Exchange Reactions in Silicon Oxide , 2016, Scientific Reports.

[9]  K. Hsieh,et al.  Future challenges of flash memory technologies , 2009 .

[10]  P. Zhou,et al.  In Situ Observation of Compliance-Current Overshoot and Its Effect on Resistive Switching , 2010, IEEE Electron Device Letters.

[11]  Lifeng Liu,et al.  Gd-doping effect on performance of HfO2 based resistive switching memory devices using implantation approach , 2011 .

[12]  Shibing Long,et al.  Graphene and Related Materials for Resistive Random Access Memories , 2017 .

[13]  L. Goux,et al.  On the bipolar resistive-switching characteristics of Al2O3- and HfO2-based memory cells operated in the soft-breakdown regime , 2014 .

[14]  L. Goux,et al.  Sub-10 nm low current resistive switching behavior in hafnium oxide stack , 2016 .

[15]  Byung-Gook Park,et al.  Nano-cone resistive memory for ultralow power operation. , 2017, Nanotechnology.

[16]  Maas,et al.  Dynamic behavior of hydrogen in silicon nitride and oxynitride films made by low-pressure chemical vapor deposition. , 1993, Physical review. B, Condensed matter.

[17]  H. Hwang,et al.  In-Depth Study on the Effect of Active-Area Scale-Down of Solution-Processed $\hbox{TiO}_{x}$ , 2012, IEEE Electron Device Letters.

[18]  H. Schroeder Poole-Frenkel-effect as dominating current mechanism in thin oxide films—An illusion?! , 2015 .

[19]  R. Dittmann,et al.  Redox‐Based Resistive Switching Memories – Nanoionic Mechanisms, Prospects, and Challenges , 2009, Advanced materials.

[20]  O. Gorshkov,et al.  Role of highly doped Si substrate in bipolar resistive switching of silicon nitride MIS-capacitors , 2018 .

[21]  Wei Li,et al.  The Ultra‐Low Power Performance of a‐SiNxOy:H Resistive Switching Memory , 2018, physica status solidi (a).

[22]  Byung-Gook Park,et al.  Understanding rectifying and nonlinear bipolar resistive switching characteristics in Ni/SiNx/p-Si memory devices , 2017 .

[23]  Ru Huang,et al.  Modulation of nonlinear resistive switching behavior of a TaOx-based resistive device through interface engineering , 2017, Nanotechnology.

[24]  R. Waser,et al.  Thermochemical resistive switching: materials, mechanisms, and scaling projections , 2011 .

[25]  Umesh Chand,et al.  Enhancement of resistive switching properties in nitride based CBRAM device by inserting an Al2O3 thin layer , 2017 .

[26]  Shuang Gao,et al.  Implementation of Complete Boolean Logic Functions in Single Complementary Resistive Switch , 2015, Scientific Reports.

[27]  Byung-Gook Park,et al.  Nonlinear and multilevel resistive switching memory in Ni/Si3N4/Al2O3/TiN structures , 2016 .

[28]  Byung-Gook Park,et al.  Fully Si compatible SiN resistive switching memory with large self-rectification ratio , 2016 .

[29]  Kate J. Norris,et al.  Trilayer Tunnel Selectors for Memristor Memory Cells , 2015, Advanced materials.

[31]  Byung-Gook Park,et al.  Ultralow power switching in a silicon-rich SiNy/SiNx double-layer resistive memory device. , 2017, Physical chemistry chemical physics : PCCP.

[32]  I-Ting Wang,et al.  3D Ta/TaOx/TiO2/Ti synaptic array and linearity tuning of weight update for hardware neural network applications , 2016, Nanotechnology.

[33]  F. Zeng,et al.  Recent progress in resistive random access memories: Materials, switching mechanisms, and performance , 2014 .

[34]  Chun-Wei Huang,et al.  Direct Observation of Dual-Filament Switching Behaviors in Ta2 O5 -Based Memristors. , 2017, Small.

[35]  Jacques-Olivier Klein,et al.  Failure and reliability analysis of STT-MRAM , 2012, Microelectron. Reliab..

[36]  Resistive switching characteristics of Al/Si3N4/p-Si MIS-based resistive switching memory devices , 2016, 1605.06006.

[37]  M. Rozenberg,et al.  Manganite-based memristive heterojunction with tunable non-linear I-V characteristics. , 2015, Nanoscale.

[38]  Shinhyun Choi,et al.  Tuning resistive switching characteristics of tantalum oxide memristors through Si doping. , 2014, ACS nano.

[39]  H. Wong,et al.  Nanometer-Scale ${\rm HfO}_{x}$ RRAM , 2013 .

[40]  H-S Philip Wong,et al.  Multi-level control of conductive nano-filament evolution in HfO2 ReRAM by pulse-train operations. , 2014, Nanoscale.

[41]  Byung-Gook Park,et al.  Resistive Switching Characteristics of Silicon Nitride-Based RRAM Depending on Top Electrode Metals , 2015, IEICE Trans. Electron..

[42]  S. Maikap,et al.  Impact of device size and thickness of Al2O3 film on the Cu pillar and resistive switching characteristics for 3D cross-point memory application , 2014, Nanoscale Research Letters.

[43]  Fei Zhou,et al.  Study of self-compliance behaviors and internal filament characteristics in intrinsic SiOx-based resistive switching memory , 2016 .

[44]  Jianhui Zhao,et al.  Superior resistive switching memory and biological synapse properties based on a simple TiN/SiO2/p-Si tunneling junction structure , 2017 .

[45]  Jun Yeong Seok,et al.  Highly Uniform, Electroforming‐Free, and Self‐Rectifying Resistive Memory in the Pt/Ta2O5/HfO2‐x/TiN Structure , 2014 .

[46]  Doo Seok Jeong,et al.  A Review of Three‐Dimensional Resistive Switching Cross‐Bar Array Memories from the Integration and Materials Property Points of View , 2014 .

[47]  Nirmal Ramaswamy,et al.  Frenkel-Poole trap energy extraction of atomic layer deposited Al2O3 and HfxAlyO thin films , 2007 .

[48]  D. Ielmini,et al.  Phase change materials and their application to nonvolatile memories. , 2010, Chemical reviews.

[49]  Sungjoo Lee,et al.  $\hbox{HfO}_{2}$-Based RRAM Devices With Varying Contact Sizes and Their Electrical Behavior , 2012, IEEE Electron Device Letters.

[50]  Qi Liu,et al.  Super non-linear RRAM with ultra-low power for 3D vertical nano-crossbar arrays. , 2016, Nanoscale.

[51]  U-In Chung,et al.  Highly Uniform Switching of Tantalum Embedded Amorphous Oxide Using Self-Compliance Bipolar Resistive Switching , 2011, IEEE Electron Device Letters.

[52]  Umesh Chand,et al.  Mechanism of Nonlinear Switching in HfO2-Based Crossbar RRAM With Inserting Large Bandgap Tunneling Barrier Layer , 2015, IEEE Transactions on Electron Devices.

[53]  Hangbing Lv,et al.  Self-Rectifying Resistive-Switching Device With $ \hbox{a-Si/WO}_{3}$ Bilayer , 2013, IEEE Electron Device Letters.

[54]  Resistive-switching behavior in Ti/Si3N4/Ti memory structures for ReRAM applications , 2012 .

[55]  Jung-Hyun Lee,et al.  High Density Plasma Etching of Nickel Thin Films Using a Cl2/Ar Plasma , 2007 .

[56]  Chao Du,et al.  Emulation of synaptic metaplasticity in memristors. , 2017, Nanoscale.

[57]  Victor B. Kazantsev,et al.  Field‐ and irradiation‐induced phenomena in memristive nanomaterials , 2016 .

[58]  Byung-Gook Park,et al.  Resistive switching characteristics of Si3N4-based resistive-switching random-access memory cell with tunnel barrier for high density integration and low-power applications , 2015 .

[59]  Ru Huang,et al.  Engineering incremental resistive switching in TaOx based memristors for brain-inspired computing. , 2016, Nanoscale.

[60]  Sungho Kim,et al.  Self-rectifying resistive switching behavior observed in Si3N4-based resistive random access memory devices , 2015 .

[61]  Tomoji Kawai,et al.  Scaling Effect on Unipolar and Bipolar Resistive Switching of Metal Oxides , 2013, Scientific Reports.

[62]  Jeonghwan Song,et al.  Resistance controllability and variability improvement in a TaOx-based resistive memory for multilevel storage application , 2015 .

[63]  Tseung-Yuen Tseng,et al.  Resistive Switching Characteristics of WO3/ZrO2 Structure With Forming-Free, Self-Compliance, and Submicroampere Current Operation , 2015, IEEE Electron Device Letters.

[64]  Y. Liu,et al.  Linear Scaling of Reset Current Down to 22-nm Node for a Novel $\hbox{Cu}_{x}\hbox{Si}_{y}\hbox{O}$ RRAM , 2012, IEEE Electron Device Letters.

[65]  Tae Geun Kim,et al.  Effect of Work Function Difference Between Top and Bottom Electrodes on the Resistive Switching Properties of SiN Films , 2013, IEEE Electron Device Letters.

[66]  Fei Zhou,et al.  Electroforming and resistive switching in silicon dioxide resistive memory devices , 2015 .

[67]  Byung Joon Choi,et al.  High‐Speed and Low‐Energy Nitride Memristors , 2016 .

[68]  Wen Wang,et al.  Nanocrystalline Si pathway induced unipolar resistive switching behavior from annealed Si-rich SiNx/SiNy multilayers , 2014 .

[69]  Ling Xu,et al.  a-SiNx:H-based ultra-low power resistive random access memory with tunable Si dangling bond conduction paths , 2015, Scientific Reports.

[70]  Roles of oxygen and nitrogen in control of nonlinear resistive behaviors via filamentary and homogeneous switching in an oxynitride thin film memristor , 2016 .

[71]  W. J. Liu,et al.  A Self-Rectifying $\hbox{AlO}_{y}$ Bipolar RRAM With Sub-50-$\mu\hbox{A}$ Set/Reset Current for Cross-Bar Architecture , 2012, IEEE Electron Device Letters.

[72]  Kinam Kim,et al.  A fast, high-endurance and scalable non-volatile memory device made from asymmetric Ta2O(5-x)/TaO(2-x) bilayer structures. , 2011, Nature materials.

[73]  Tae Geun Kim,et al.  Effect of nanopyramid bottom electrodes on bipolar resistive switching phenomena in nickel nitride films-based crossbar arrays , 2014, Nanotechnology.

[74]  Byung-Gook Park,et al.  Analog Synaptic Behavior of a Silicon Nitride Memristor. , 2017, ACS applied materials & interfaces.

[75]  Yao-Feng Chang,et al.  Proton exchange reactions in SiOx-based resistive switching memory: Review and insights from impedance spectroscopy , 2016 .

[76]  V. Gritsenko,et al.  Electronic structure of memory traps in silicon nitride , 2009 .

[77]  Xu Jing,et al.  Resistive Random Access Memory Cells with a Bilayer TiO2/SiOX Insulating Stack for Simultaneous Filamentary and Distributed Resistive Switching , 2017 .

[78]  Improved resistive switching phenomena observed in SiNx‐based resistive switching memory through oxygen doping process , 2014 .

[79]  Yue Bai,et al.  Study of Multi-level Characteristics for 3D Vertical Resistive Switching Memory , 2014, Scientific reports.

[80]  Hong Wang,et al.  Effect of nitrogen-accommodation ability of electrodes in SiNx-based resistive switching devices , 2017 .

[81]  W. J. Liu,et al.  Highly Uniform, Self-Compliance, and Forming-Free ALD $\hbox{HfO}_{2}$ -Based RRAM With Ge Doping , 2012, IEEE Transactions on Electron Devices.

[82]  G. Reimbold,et al.  Accurate analysis of parasitic current overshoot during forming operation in RRAMs , 2011 .

[83]  An Chen Area and Thickness Scaling of Forming Voltage of Resistive Switching Memories , 2014, IEEE Electron Device Letters.

[84]  Li Ji,et al.  Integrated one diode-one resistor architecture in nanopillar SiOx resistive switching memory by nanosphere lithography. , 2014, Nano letters.