Synthesis and reactivity of tetramethylthioureatriosmium clusters: crystal structures of [(μ-H)Os3(CO)8(μ3-S)(μ-OMeCO){η1-SC(NMe2)2}] and [Os3(CO)9(μ-OH)(μ-OMeCO)(PPh3)]

[1]  M. Shahiduzzaman,et al.  Triosmium clusters derived from the reactions of thioureas with dodecacarbonyltriosmium: Crystal structures of [Os3(CO)11{η1-SC(NMe2)2}], [Os3(CO)9(μ-OH)(μ-OMeOCO){η1-SC(NMe2)2}] and [(μ-H)Os3(CO)9{μ3-NHC(S)NH2}] , 1996 .

[2]  M. Hursthouse,et al.  Triosmium and triruthenium clusters containing the 4-methylthiazolide ligand: crystal structures of [Os3(µ-H)(CO)10(µ-2,3-η2-CNCMeCHS)], [Os3(µ-H)(CO)9(µ-2,3-η2-CNCMeCHS)(PPh3)] and [Os3(µ-H)(CO)8(µ-2,3-η2-CNCMeCHS)(PPh3)2] , 1996 .

[3]  M. Irving,et al.  Synthesis and reactivity of $$(\mu - H)(\mu _3 - \eta ^2 - H_2 )_4 )Os_3 (CO)_9 $$ : An unusually reactive triosmium cluster , 1994 .

[4]  A. Lees,et al.  Synthesis and photochemical reactivity of phenylthioureatotriosmium cluster complexes: crystal structures of [Os3H(CO)10{µ-SC(NPh)(NHPh)}] and [Os3H(CO)9{µ3-SC(NPh)(NHPh)}] , 1994 .

[5]  J. Darr,et al.  A dimeric calcium siloxide lightly stabilized by ammonia ligands , 1993 .

[6]  T. McPhillips,et al.  SYNTHESIS, STRUCTURE, AND LIGAND DYNAMICS OF TRIOSMIUM IMIDOYL CLUSTERS AND THEIR ISOCYANIDE DERIVATIVES , 1993 .

[7]  Ulf Bodensieck,et al.  Novel hexanuclear ruthenium clusters with unusual metal framework geometries: ‘boat’ and ‘sofa’ configurations of the Ru6 core , 1993 .

[8]  Ulf Bodensieck,et al.  Multicenter ligand transformations of thioureas on ruthenium clusters , 1992 .

[9]  Georg Süss-Fink,et al.  Rutheniuminduzierter abbau von tetramethylthioharnstoff zu carbenliganden. Synthese und molekülstruktur der cluster Ru4(μ2-CO)2(CO) 9-n(μ4-S)2[C(NMe2)2]n (n = 1, 2) und (μ2-H)Ru3(CO)9[μ3-SRu3(CO)3(η 2-CH2 NMeCNMe2) , 1992 .

[10]  Georg Süss-Fink,et al.  Rutheniuminduzierter abbau von tetramethylthioharnstoff zu carbin- und dicarbenliganden. Synthese und molekülstruktur der cluster Ru4 (CO)10(μ2-CNMe2)(μ3-S)[μ3-SRu(CO)3(η2-CH2NMeCNMe2)], Ru5(CO)11(μ2-CNMe2)2 (μ4-S)2 und RU4(μ2-CO)3(CO)6(μ4-S)2(η2-Me2NCNMeCH2CNMe2) , 1992 .

[11]  R. D. Adams,et al.  Thermal and photoassisted ring opening of thietane in a triosmium cluster complex , 1992 .

[12]  Ulf Bodensieck,et al.  Tetranuclear ruthenium clusters containing a pseudo-octahedral Ru4S2 framework and diaminocarbene ligands , 1992 .

[13]  D. Osella,et al.  PHOSPHINE ADDITION AND SUBSTITUTION-REACTIONS ON UNUSUALLY REACTIVE TRIOSMIUM CLUSTERS - (MU-H)(MU-3-ETA-2-C=NCH2CH2CH2)OS3(CO)9 AND (MU-H)(MU-3-ETA-2-CH3CH2C=NCH2CH2CH3)OS3(CO)9 , 1991 .

[14]  R. Fish,et al.  Heteroaromatic nitrogen ligand studies with the (.eta.5-pentamethylcyclopentadienyl)ruthenium cation: .eta.1(N) and .eta.6(.pi.) bonding modes and factors that influence a nitrogen to .pi. rearrangement , 1991 .

[15]  A. Deeming,et al.  Triple oxidative addition of the diselenide PhSeSePh to the cluster [Os3(CO)10(MeCN)2] to give the osmium(II) compound [Os3(µ-Ph)(µ-PhCO)(µ3-Se)2(CO)8] , 1991 .

[16]  Georg Süss-Fink,et al.  Fixierung von Harnstoffen und Thioharnstoffen auf dreikernigen Ruthenium‐Clustern: Synthese und Molekülstruktur von (μ2‐H)Ru3(CO)9(μ3‐NPhCSNHPh) , 1990 .

[17]  G. Sheldrick Phase annealing in SHELX-90: direct methods for larger structures , 1990 .

[18]  Ulf Bodensieck,et al.  Room temperature activation of an aliphatic C–H bond: synthesis and structure of the ruthenium clusters [(µ2-H)Ru3(CO)8(µ3-S)(η2-CH2CMe2NHCNHBut)] and [(µ2-H)Ru3(CO)9{µ3-S-Ru(CO)3(η2-CH2CMe2NHCNHBut)}] , 1990 .

[19]  H. Kim,et al.  Bonding studies of nitrogen heterocyclic ligands to (.eta.5-cyclopentadienyl)ruthenium cation: a novel nitrogen-to-.pi. rearrangement , 1989 .

[20]  P. Raithby,et al.  Trinuclear osmium clusters containing bidentate Ph2PCH2PPh2 and Me2PCH2PMe2 ligands: X-ray crystal structures of the complexes [Os3H(CO)9(Me2PCHPMe2)] and [Os3H(OH)(CO)8(Ph2PCH2PPh2)] , 1987 .

[21]  S. Kabir,et al.  Acid-induced displacement of acetaldehyde from a µ-vinyloxy-triosmium cluster , 1985 .

[22]  C. Knobler,et al.  Alkylation of salts of the triosmium anions [Os3(eq-.eta.1-COMe)(CO)11]-, [Os3(.mu.-O:CMe)(CO)10]- and [Os3(COR)(.mu.-H;.mu.-O:CMe)(CO)9]- (R = Me or Ph). Crystal and molecular structure of Os3(1-.eta.1-CMeOMe)(1,2-.mu.-H;1,2-.mu.-O:CMe)(CO)9 , 1984 .

[23]  N. Walker,et al.  Triosmium clusters with ligands derived from αβ-unsaturated ketones. X-ray crystal structures of [Os3H(CO)10(cis-MeCCHCOMe)] and [Os3H(OH)(CO)9(PMe2Ph)] , 1984 .

[24]  C. Knobler,et al.  Synthesis and structure determination of Os3[1,2-.mu.-H;1,2-.mu.-O:C(Me)][1-C(OMe)Me][CO)9: the first cluster complex containing a Fischer-type carbene group , 1982 .

[25]  P. Raithby,et al.  Reaction of [Os3(CO)10(NCMe)2] with amides and aldehydes; X-ray crystal structure of [Os3(CO)10(μ-H)(COCH2Ph)] , 1981 .

[26]  G. Sheldrick,et al.  1,1,1,2,2,2,2,3,3,3,3-Undecacarbonyl(trimethyl phosphite)-triangulo-triosmium , 1978 .