Effect of rate of application on degradation of imazethapyr in groundnut and soil under tropical Indian condition

Pesticides though formulated to be biologically degradable, few herbicides reported to cause surface and groundwater contamination which needs the monitoring of herbicide residues in environment continuously. Thus, to monitor the persistence and residues in crops, imazethapyr degradation studies were conducted in soil with groundnut cropping under Indian tropical condition. A groundnut field was treated with different doses of imazethapyr as early post emergence. Results showed that the degradation of imazethapyr in soil and groundnut plant followed first order reaction kinetics irrespective of the dose. The residue of imazethapyr persists in soil up to 60 days at higher rates of application while it persists up to 30 days in plant with the calculated half life of 2.8 to 7.4 days in soil and 5.1 to 5.9 days in plant. At the time of harvest, the residue of imazethapyr in soil, groundnut haulm or pods were below the detectable limit of 0.008 mg/kg across different doses of application. However, the continuous and inappropriate use in light textured soils may cause groundwater contamination and bioaccumulation in plant system. Hence, a pre harvest interval of 75 days must be allowed after the application of imazethapyr for the weed control in groundnut.

[1]  S. Sondhia Herbicides residues in soil, water, plants and non-targeted organisms and human health implications: an Indian perspective , 2014 .

[2]  C. Chinnusamy,et al.  Field dissipation of oxyfluorfen in onion and its dynamics in soil under Indian tropical conditions , 2013, Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes.

[3]  S. Sondhia Evaluation of imazethapyr leaching in soil under natural rainfall conditions , 2013 .

[4]  A. Dwivedi,et al.  Residues of imazethapyr in soybean grain, straw and soil under application of long term fertilizers in Typic Haplustert , 2011 .

[5]  J. Chovelon,et al.  Study of the phototransformation of imazaquin in aqueous solution : A kinetic approach , 2005 .

[6]  J. Welsh,et al.  Weed control in organic cereals and pulses , 2002 .

[7]  R. Kookana,et al.  SORPTION OF AMETRYN AND IMAZETHAPYR IN TWENTY-FIVE SOILS FROM PAKISTAN AND AUSTRALIA , 2001, Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes.

[8]  C. Reinhardt,et al.  A Bioassay Technique Detects Imazethapyr Leaching and Liming-Dependent Activity1 , 2001, Weed Technology.

[9]  D. Shaner,et al.  Time-dependent adsorption of imazethapyr to soil , 2000, Weed Science.

[10]  J. Schoenau,et al.  Analysis of imazethapyr in agricultural soils by ion exchange membranes and a canola bioassay , 1999 .

[11]  G. D’ascenzo,et al.  Rapid and simple method for extraction and determination of imidazolinone herbicides in soil , 1998 .

[12]  W. Witt,et al.  Microbial degradation of imazaquin and imazethapyr , 1997, Weed Science.

[13]  A. Pusino,et al.  Adsorption and Desorption of Imazapyr by Soil , 1997 .

[14]  M. Loux,et al.  Effect of Soil Type and pH on Persistence and Carryover of Imidazolinone Herbicides , 1993, Weed Technology.

[15]  W. Curran,et al.  Effects of Tillage and Application Method on Clomazone, Imazaquin, and Imazethapyr Persistence , 1992, Weed Science.

[16]  Edward E. Gbur,et al.  Degradation and Field Persistence of Imazethapyr , 1990, Weed Science.

[17]  P. Shea,et al.  Effect of Soil Type and pH on Adsorption, Mobility, and Efficacy of Imazaquin and Imazethapyr , 1990, Weed Science.

[18]  W. Witt,et al.  Efficacy, Phytotoxicity, and Persistence of Imazaquin, Imazethapyr, and Clomazone in No-Till Double-Crop Soybeans (Glycine max) , 1989, Weed science.