Volcanic Sunset-Glow Stratum: Origin
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Reexamination of the phenomenon of volcanic-dust sunsets, as typified by the Krakatoa event, supports a theory that the scattering layer is produced by the interaction of ozone and sulfur dioxide in much the same manner as is the normal "Junge"aerosol layer at 20 kilometers.
[1] S. Mossop. Stratospheric particles at 20 km altitude , 1965 .
[2] A B Meinel,et al. Late Twilight Glow of the Ash Stratum from the Eruption of Agung Volcano , 1963, Science.