Adsorptive Stripping Voltammetry for Trace Determination of Quinalphos Employing Silicon Carbide Nanoparticles Modified Glassy Carbon Electrode

A silicon carbide nanoparticle-coated glassy carbon electrode (SiCNPs-GCE) was employed for electrochemical determination of Quinalphos (QNP) using different electroanalytical techniques. QNP showed an enhancement in the reduction peak current at SiCNPs modified GCE in pH 7.0 (BR Buffer). The peak current was found to be linear with the QNP concentration in the range from 6.69×10−9 to 1.34×10−6 M (r=0.995) with detection limit of 1.34×10−9 M (S/N=3). The developed sensor (SiCNPs-GCE) was employed for QNP determination in tap water, lake water, soil, mango as well as in biological samples.

[1]  M. Richmond,et al.  Unusual chemical transformations of acetone thiosemicarbazone mediated by ruthenium: C–H bond activation, thiolation, and C–N bond cleavage , 2014 .

[2]  R. A. Dar,et al.  Electrocatalytic oxidative determination of reserpine at electrochemically functionalized single walled carbon nanotube with polyaniline , 2013 .

[3]  A. Srivastava,et al.  Adsorptive stripping voltammetric determination of imipramine, trimipramine and desipramine employing titanium dioxide nanoparticles and an Amberlite XAD-2 modified glassy carbon paste electrode. , 2013, The Analyst.

[4]  Pradeep Mathur,et al.  Biomimetic sensor for certain catecholamines employing copper(II) complex and silver nanoparticle modified glassy carbon paste electrode. , 2013, Biosensors & bioelectronics.

[5]  A. Srivastava,et al.  Adsorptive stripping differential pulse voltammetric determination of metoprolol at Nafion-CNT-nano-composite film sensor , 2013 .

[6]  Hong Dai,et al.  A new metal electrocatalysts supported matrix: Palladium nanoparticles supported silicon carbide nanoparticles and its application for alcohol electrooxidation , 2012 .

[7]  D. Sud,et al.  Photocatalytic degradation of quinalphos in aqueous TiO2 suspension: Reaction pathway and identification of intermediates by GC/MS , 2012 .

[8]  H. Eskandari,et al.  Preparation of magnetite/poly(styrene-divinylbenzene) nanoparticles for selective enrichment-determination of fenitrothion in environmental and biological samples. , 2012, Analytica chimica acta.

[9]  A. Srivastava,et al.  Multiwalled carbon nanotube-4-tert-butyl calix[6]arene composite electrochemical sensor for clenbuterol hydrochloride determination by means of differential pulse adsorptive stripping voltammetry , 2012, Journal of Applied Electrochemistry.

[10]  S. Karna,et al.  Potentiometric stripping analysis of methyl and ethyl parathion employing carbon nanoparticles and halloysite nanoclay modified carbon paste electrode. , 2012, Analytica chimica acta.

[11]  A. Srivastava,et al.  Determination of amiloride at Nafion–CNT-nano-composite film sensor employing adsorptive stripping differential pulse voltammetry , 2012 .

[12]  Rahul Kumar,et al.  In vitro and in vivo studies on degradation of quinalphos in rats. , 2012, Journal of hazardous materials.

[13]  P. Ugo,et al.  Electroanalysis of trace inorganic arsenic with gold nanoelectrode ensembles , 2012 .

[14]  I. Palchetti,et al.  Dipyridine‐Containing Macrocyclic Polyamine – Nafion‐Modified Screen‐Printed Carbon Electrode for Voltammetric Detection of Lead , 2012 .

[15]  A. Srivastava,et al.  Graphite Electrode Coated with a 7,16‐Dibenzyl‐1,4,10,13‐tetraoxa‐7,16‐diazacyclooctadecane‐Multiwalled Carbon Nanotube Composite as Sensor For Detection of Samarium , 2011 .

[16]  A. Salimi,et al.  SiC nanoparticles-modified glassy carbon electrodes for simultaneous determination of purine and pyrimidine DNA bases. , 2011, Biosensors & bioelectronics.

[17]  A. Kumaravel,et al.  A biocompatible nano TiO2/nafion composite modified glassy carbon electrode for the detection of fenitrothion , 2011 .

[18]  Haoyu Hu,et al.  A novel chemiluminescence assay of organophosphorous pesticide quinalphos residue in vegetable with luminol detection , 2010, Chemistry Central journal.

[19]  Rassoul Dinarvand,et al.  Simultaneous voltammetric determination of tramadol and acetaminophen using carbon nanoparticles modified glassy carbon electrode , 2010 .

[20]  P C Abhilash,et al.  Pesticide use and application: an Indian scenario. , 2009, Journal of hazardous materials.

[21]  A. Salimi,et al.  Electrooxidation of insulin at silicon carbide nanoparticles modified glassy carbon electrode , 2009 .

[22]  Govindasamy Agoramoorthy,et al.  Can India meet the increasing food demand by 2020 , 2008 .

[23]  Ashwini K. Srivastava,et al.  Voltammetric determination of para-aminobenzoic acid using carbon paste electrode modified with macrocyclic compounds , 2006 .

[24]  A. Muñoz de la Peña,et al.  Stopped-flow and kinetic-fluorimetric determination of quinalphos in water samples. , 2006, Talanta.

[25]  E. Gallardo,et al.  Determination of quinalphos in blood and urine by direct solid-phase microextraction combined with gas chromatography-mass spectrometry. , 2006, Journal of chromatography. B, Analytical technologies in the biomedical and life sciences.

[26]  K. Kumar,et al.  Extractive Spectrofluorometric Determination of Quinalphos Using Fluorescein in Environmental Samples , 2005, Environmental monitoring and assessment.

[27]  N. Pant,et al.  Testicular and spermatotoxic effects of quinalphos in rats , 2003, Journal of applied toxicology : JAT.

[28]  K. Mohanakumar,et al.  Effects of an organophosphate pesticide, quinalphos, on the hypothalamo-pituitary-gonadal axis in adult male rats , 2000 .

[29]  Y. Shukla,et al.  Evaluation of carcinogenic and co-carcinogenic potential Quinalphos in mouse skin. , 2000, Cancer letters.

[30]  C. Colosio,et al.  Risk assessment and management of occupational exposure to pesticides. , 1999, Toxicology letters.

[31]  A. L. Simplício,et al.  Validation of a solid-phase microextraction method for the determination of organophosphorus pesticides in fruits and fruit juice. , 1999, Journal of chromatography. A.

[32]  G. Font,et al.  Determination of triazines and organophosphorus pesticides in water samples using solid-phase extraction. , 1991, Journal of chromatography.

[33]  N. C. Dey,et al.  Gravimetric determination of quinalphos by the direct precipitation of the 2-hydroxyquinoxaline-copper chloride complex with copper(I) chloride , 1984 .