Techno-Economic Analysis of the Stabilization of Bio-Oil Fractions for Insertion into Petroleum Refineries

This study investigates the costs and greenhouse gas (GHG) emissions of a commercial-scale, 2000 dry MT/day, red oak biorefinery designed to stabilize and upgrade pyrolysis oil into drop-in fuels. Stabilization improves the compatibility of bio-oil with crude refinery intermediate streams and equipment, but the costs of this process are not known. A discounted cash flow rate of return (DCFROR) analysis is conducted to evaluate the economic feasibility of the bio-oil stabilization biorefinery based on a 30-year plant life and 10% internal rate of return. Four economic scenarios representing different biorefinery configurations and byproducts are analyzed. The installed equipment cost for the stand-alone hydrocarbons (SH) is estimated as $277 million, and the minimum fuel-selling price (MFSP) for the SH scenario is evaluated as $2.85 per gallon. With mixed alcohols as a byproduct, the MFSP can be lowered to $2.77 per gallon or to $2.33 per gallon by colocating with a refinery. Sensitivity analysis of the sy...

[1]  Susanne B. Jones,et al.  Understanding Uncertainties in the Economic Feasibility of Transportation Fuel Production using Biomass Gasification and Mixed Alcohol Synthesis , 2016 .

[2]  Qi Dang,et al.  Ultra-Low Carbon Emissions from Coal-Fired Power Plants through Bio-Oil Co-Firing and Biochar Sequestration. , 2015, Environmental science & technology.

[3]  Robert C. Brown,et al.  Stabilization of bio-oils using low temperature, low pressure hydrogenation , 2015 .

[4]  Robert C. Brown,et al.  Hydrocarbon Liquid Production via Catalytic Hydroprocessing of Phenolic Oils Fractionated from Fast Pyrolysis of Red Oak and Corn Stover , 2015 .

[5]  M. Wright,et al.  Product Selection and Supply Chain Optimization for Fast Pyrolysis and Biorefinery System , 2014 .

[6]  Zhong-yang Luo,et al.  Environmental life cycle assessment of bio-fuel production via fast pyrolysis of corn stover and hydroprocessing , 2014 .

[7]  Rajeeva Thilakaratne,et al.  A techno-economic analysis of microalgae remnant catalytic pyrolysis and upgrading to fuels , 2014 .

[8]  Yihua Li,et al.  Mild catalytic pyrolysis of biomass for production of transportation fuels: a techno-economic analysis , 2014 .

[9]  D. Resasco,et al.  Ketonization of Carboxylic Acids: Mechanisms, Catalysts, and Implications for Biomass Conversion , 2013 .

[10]  Yong Wang,et al.  Recent Advances in Hydrotreating of Pyrolysis Bio-Oil and Its Oxygen-Containing Model Compounds , 2013 .

[11]  Tristan R. Brown,et al.  Techno-economic analysis of biomass to transportation fuels and electricity via fast pyrolysis and hydroprocessing , 2013 .

[12]  Dustin L. Dalluge,et al.  Pyrolytic sugars from cellulosic biomass. , 2012, ChemSusChem.

[13]  Abolghasem Shahbazi,et al.  Bio-oil production and upgrading research: A review , 2012 .

[14]  Zhenglong Li,et al.  Mild electrocatalytic hydrogenation and hydrodeoxygenation of bio-oil derived phenolic compounds using ruthenium supported on activated carbon cloth , 2012 .

[15]  R. Fox,et al.  Experimental validation and CFD modeling study of biomass fast pyrolysis in fluidized-bed reactors , 2012 .

[16]  N. H. Ravindranath,et al.  Jatropha cultivation in southern India: assessing farmers' experiences , 2012 .

[17]  A. Bridgwater Review of fast pyrolysis of biomass and product upgrading , 2012 .

[18]  Amgad Elgowainy,et al.  Well-to-wheels analysis of fast pyrolysis pathways with the GREET model. , 2011 .

[19]  Peter Arendt Jensen,et al.  A review of catalytic upgrading of bio-oil to engine fuels , 2011 .

[20]  Manuel Garcia-Perez,et al.  Production and fuel properties of fast pyrolysis oil/bio-diesel blends , 2010 .

[21]  Avelino Corma,et al.  Processing biomass in conventional oil refineries: Production of high quality diesel by hydrotreating vegetable oils in heavy vacuum oil mixtures , 2007 .

[22]  A. Corma,et al.  Processing biomass-derived oxygenates in the oil refinery: Catalytic cracking (FCC) reaction pathways and role of catalyst , 2007 .

[23]  W. Baldauf,et al.  Production of a bio-gasoline by upgrading biomass flash pyrolysis liquids via hydrogen processing and catalytic cracking , 1998 .

[24]  C. Daw,et al.  Coupling DAEM and CFD for simulating biomass fast pyrolysis in fluidized beds , 2016 .

[25]  Robert C. Brown,et al.  Techno-economic analysis of transportation fuels from defatted microalgae via hydrothermal liquefaction and hydroprocessing , 2015 .

[26]  Abhijit Dutta,et al.  Conceptual Process Design and Techno-Economic Assessment of Ex Situ Catalytic Fast Pyrolysis of Biomass: A Fixed Bed Reactor Implementation Scenario for Future Feasibility , 2015, Topics in Catalysis.

[27]  Robert C. Brown,et al.  The effect of pyrolysis temperature on recovery of bio-oil as distinctive stage fractions , 2014 .

[28]  Tristan R. Brown,et al.  Techno-economic analysis of monosaccharide production via fast pyrolysis of lignocellulose. , 2013, Bioresource technology.

[29]  Marjorie Rover,et al.  Characterization of bio-oil recovered as stage fractions with unique chemical and physical properties , 2012 .

[30]  Tristan R. Brown,et al.  Techno‐economic analysis of biobased chemicals production via integrated catalytic processing , 2012 .