Detection of CO2 in solution with a Pt-NiO solid-state sensor.

A metal insulator semiconductor field effect transistor (MISFET)-type sensor for the detection of CO(2) dissolved in aqueous solution is presented. This all-solid-state device is based on a Pt-NiO thin film as active sensing material on the top of a gate electrode. The fabrication of the sensor is described and its performance is characterized. In particular the transient characteristics and response curves at different biases V(RS) versus the amount of dissolved CO(2) are presented. The sensor shows a linear response to the logarithm of the concentration of dissolved CO(2) at room temperature.

[1]  Colette McDonagh,et al.  Development of an optical sensor probe for the detection of dissolved carbon dioxide , 2006 .

[2]  J. Hendrikse,et al.  THE EMOSFET AS A POTENTIOMETRIC TRANSDUCER IN AN OXYGEN SENSOR , 1998 .

[3]  Maximilian Fleischer,et al.  Investigation of the reaction mechanisms in work function type sensors at room temperature by studies of the cross-sensitivity to oxygen and water: the carbonate–carbon dioxide system , 2000 .

[4]  Piet Bergveld,et al.  Thirty years of ISFETOLOGY ☆: What happened in the past 30 years and what may happen in the next 30 years , 2003 .

[5]  A. Cornet,et al.  Study of the CO and humidity interference in La doped tin oxide CO2 gas sensor , 2003 .

[6]  Theodor Doll,et al.  Adsorbed water as key to room temperature gas-sensitive reactions in work function type sensors: the carbonate–carbon dioxide system , 1999 .

[7]  S. Fukuzumi,et al.  Accelerating effect of a proton on the reduction of CO2 dissolved in water under acidic conditions. Isolation, crystal structure, and reducing ability of a water-soluble ruthenium hydride complex. , 2003, Journal of the American Chemical Society.

[8]  Jeffrey W. Fergus A review of electrolyte and electrode materials for high temperature electrochemical CO2 and SO2 gas sensors , 2008 .

[9]  Jenshan Lin,et al.  Recent advances in wide bandgap semiconductor biological and gas sensors , 2010 .

[10]  Pietro Siciliano,et al.  Sensing characteristics of NiO thin films as NO2 gas sensor , 2002 .

[11]  C. Davis,et al.  An improved Severinghaus-type carbon dioxide microelectrode for use in biofilms , 2004 .

[12]  K. Cammann,et al.  DEVELOPMENT OF A DISSOLVED CARBON DIOXIDE SENSOR BASED ON A COULOMETRIC TITRATION , 1999 .

[13]  Jae Ho Shin,et al.  ISFET-Based Differential pCO2 Sensors Employing a Low-Resistance Gas-Permeable Membrane , 1996 .

[14]  John J. Carroll,et al.  The system carbon dioxide-water and the Krichevsky-Kasarnovsky equation , 1992 .

[15]  Jordi Riu,et al.  Gas sensors based on nanostructured materials. , 2007, The Analyst.

[16]  Wolfgang J. Parak,et al.  Lateral resolution of light-addressable potentiometric sensors: an experimental and theoretical investigation , 1997 .

[17]  T. Pan,et al.  Study of high-k Er2O3 thin layers as ISFET sensitive insulator surface for pH detection , 2009 .

[18]  J. W. Parce,et al.  Light-addressable potentiometric sensor for biochemical systems. , 1988, Science.

[19]  G. Jobst,et al.  A novel miniaturized sensor for carbon dioxide dissolved in liquids , 2001 .

[20]  M. Esashi,et al.  ISFET's using inorganic gate thin films , 1979, IEEE Transactions on Electron Devices.

[21]  Maximilian Fleischer,et al.  The influence of interfaces and interlayers on the gas sensitivity in work function type sensors , 2003 .

[22]  G. Özkan,et al.  CO2 adsorption on porous NiO as a cathode material for molten carbonate fuel cells , 2005 .

[23]  Yoshitaka Ito Long-term drift mechanism of Ta2O5 gate pH-ISFETs , 2000 .

[24]  Wen-Yaw Chung,et al.  Study on SnO2/Al/SiO2/Si ISFET with a metal light shield , 2000 .

[25]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[26]  C. Cané,et al.  Microtechnologies for PH ISFET chemical sensors , 1997 .

[27]  Ingo Klimant,et al.  Microsecond lifetime-based optical carbon dioxide sensor using luminescence resonance energy transfer , 1999 .

[28]  R. M. Lambert,et al.  CO2 adsorption on oxygen-modified Ni(111) , 1993 .

[29]  N. Yamazoe,et al.  Development of FET-type CO2 sensor operative at room temperature , 2004 .

[30]  Yu-Lung Lo,et al.  Highly sensitive and linear optical fiber carbon dioxide sensor based on sol–gel matrix doped with silica particles and HPTS , 2009 .

[31]  K. Vytras,et al.  Carbon Paste Electrodes in Modern Electroanalysis , 2001 .

[32]  Wencheng Niu,et al.  A novel dissolved oxygen sensor based on MISFET structure with Pt-LaF3 mixture film , 2002 .

[33]  H. Hosaka,et al.  Gastric PCO2 monitoring system based on a double membrane type PCO2 sensor , 1998 .

[34]  Dermot Diamond,et al.  Non-linear carbon dioxide determination using infrared gas sensors and neural networks with Bayesian regularization , 2009 .

[35]  J. Severinghaus,et al.  Electrodes for blood pO2 and pCO2 determination. , 1958, Journal of applied physiology.

[36]  N. Yamashita,et al.  Solid electrolyte CO2 sensor using NASICON and perovskite-type oxide electrode , 2000 .

[37]  Michael J. Schöning,et al.  PLD-prepared cadmium sensors based on chalcogenide glasses—ISFET, LAPS and μISE semiconductor structures , 2006 .

[38]  Michael J. Schöning,et al.  Detecting Both Physical and (Bio‐)Chemical Parameters by Means of ISFET Devices , 2004 .

[39]  Delana A. Nivens,et al.  Multilayer sol-gel membranes for optical sensing applications: single layer pH and dual layer CO(2) and NH(3) sensors. , 2002, Talanta.

[40]  A. Fuchs,et al.  Thin (NiO)1−x(Al2O3)x, Al doped and Al coated NiO layers for gas detection with HSGFET , 1998 .

[41]  C. Dafu,et al.  A new type of transcutaneous Pco2 sensor , 1995 .