Combustion Synthesis of SiAlON Ceramic Powders: A Review

SiAlON materials exhibit good mechanical properties and high chemical stability, and are attractive for both structural and functional applications. SiAlON ceramic powders can be prepared by reactive sintering or by combustion synthesis. Because of the special reaction condition with elevated reaction temperatures and high heating rates, combustion synthesis offers an opportunity for controlling grain growth and producing various grain morphologies, such as equiaxed grains, rod-like crystals, and microcubes. In comparison with reactive sintering, combustion synthesis requires a shorter processing time and less energy consumption, which can provide a more efficient way for low-cost production of SiAlON powders. This article briefly reviews recent results on combustion synthesis of SiAlON powders. At first, effects of processing parameters are discussed, including chemical composition and modifying cations, diluents, and mechanical activation of reactant powders. Then, the reaction path in combustion synthesis and growth mechanism of SiAlON crystals are studied. Finally, the sintering of combustion-synthesized SiAlON powders is mentioned.

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