Negative refractive index in the near-UV from Au-coated CuCl nanoparticle superlattices

Nanoparticle superlattices consisting of CuCl spheres coated with a gold (Au) nanoshell are shown to exhibit negative index of refraction in the near-UV regime. These predictions are based on calculations of the effective refractive index by use of the extended Maxwell–Garnett theory. The results for the refractive index are supplemented by multiple-scattering calculations of light-transmittance curves from finite slabs of nanoparticle superlattices. (© 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)

[1]  V. Veselago The Electrodynamics of Substances with Simultaneously Negative Values of ∊ and μ , 1968 .

[2]  H. Mizoguchi,et al.  Formation process of CuCl nano-particles in silica glass by ion implantation , 1999 .

[3]  Vassilios Yannopapas,et al.  Negative refraction in random photonic alloys of polaritonic and plasmonic microspheres , 2007 .

[4]  J. Stewart Aitchison,et al.  Three-dimensional array of dielectric spheres with an isotropic negative permeability at infrared frequencies , 2005 .

[5]  J. Pendry,et al.  Negative refraction makes a perfect lens , 2000, Physical review letters.

[6]  E. Matijević,et al.  Precipitation and recrystallization of uniform CuCl particles formed by aggregation of nanosize precursors , 2003 .

[7]  Lixin Ran,et al.  Experimental observation of left-handed behavior in an array of standard dielectric resonators. , 2007, Physical review letters.

[8]  R. W. Christy,et al.  Optical Constants of the Noble Metals , 1972 .

[9]  Tom G. Mackay,et al.  Meet the Metamaterials , 2007 .

[10]  John B. Pendry,et al.  Photonic band-gap effects and magnetic activity in dielectric composites , 2002 .

[11]  Photoexcitation-induced magnetism in arrays of semiconductor nanoparticles with a strong excitonic oscillator strength , 2006 .

[12]  Vaios T. Karathanos,et al.  Scattering of electromagnetic waves by periodic structures , 1992 .

[13]  J. Stewart Aitchison,et al.  Coated nonmagnetic spheres with a negative index of refraction at infrared frequencies , 2006 .

[14]  Vassilios Yannopapas,et al.  Negative refractive index metamaterials from inherently non-magnetic materials for deep infrared to terahertz frequency ranges , 2005, Journal of physics. Condensed matter : an Institute of Physics journal.

[15]  R. Ruppin,et al.  Evaluation of extended Maxwell-Garnett theories , 2000 .

[16]  M. Artoni,et al.  Resonantly absorbing one-dimensional photonic crystals. , 2005, Physical review. E, Statistical, nonlinear, and soft matter physics.

[17]  Doyle,et al.  Optical properties of a suspension of metal spheres. , 1989, Physical review. B, Condensed matter.

[18]  Vassilios Yannopapas,et al.  Heterostructures of photonic crystals: frequency bands and transmission coefficients , 1998 .