Synmetamorphic veining: origin of andalusite‐bearing veins in the Vedrette di Ries contact aureole, Eastern Alps, Italy

Discordant andalusite-biotite-quartz-bearing veins occur in the contact aureole of the Vedrette di Ries pluton (Italian Eastern Alps), never outside the area of contact metamorphic andalusite development. Andalusite veins are found only within andalusite-bearing hornfelses, and vein biotite occurs wherever host-rock garnet is partially replaced by biotite. Veins formed during contact metamorphism, synchronously with the crystallization of andalusite and biotite within host rocks. Their pegmatitic structure and their orientation suggest that vein parageneses crystallized within fluid-filled cavities that opened by hydraulic fracturing. A mechanism of synmetamorphic veining is proposed to explain rock failure and subsequent mineral deposition within veins. During hydrofracturing induced by dehydration reactions in response to heating in the aureole, fissures were immediately filled with locally derived fluids. The lack of large-scale flux, together with high fluid pressures required by hydrofracturing, suggest fluid in the cavities was a virtually stagnant, passive medium, and that mass-transport toward fractures was driven by intergranular diffusion. Because temperature and Pf values within veins are similar to those in the host rock, vein assemblages are interpreted as the stable, high-T side of reactions taking place within pelitic schists, at the time when fractures opened. Once nucleation of product phases occurred, chemical components released by dissolution of reactant minerals were driven to precipitation sites by chemical potential gradients. Since nucleation was favoured at the strained grains of vein walls, andalusite and biotite simultaneously grew in vein and host rock. The proposed genetic model contrasts with generally adopted metasomatic mechanisms for the genesis of Al2SiO5-bearing veins, in not requiring large fluid/rock ratios or a highly ‘aggressive’ fluid composition. The mechanism of synmetamorphic veining may be particularly useful in the interpretation of vein occurrences in medium- and deep-crustal rocks which have undergone extensive devolatilization.

[1]  R. Hanson Effects of fluid production on fluid flow during regional and contact metamorphism , 1992 .

[2]  P. Philippot,et al.  Trace-element-rich brines in eclogitic veins: implications for fluid composition and transport during subduction , 1991 .

[3]  A. Lasaga,et al.  Kinetics of Heterogeneous Reactions , 1991 .

[4]  P. Philippot “Crack seal” vein geometry in eclogitic rocks , 1987 .

[5]  K. Furlong,et al.  Modeling thermal regimes , 1991 .

[6]  B. Leake,et al.  The Metamorphism of Fe-rich Pelites from Connemara, Ireland , 1980 .

[7]  P. Philippot,et al.  Chemical-microstructural changes in eclogite-facies shear zones (Monviso, Western Alps, north Italy) as indicators of strain history and the mechanism and scale of mass transfer , 1989 .

[8]  D. Rubie The catalysis of mineral reactions by water and restrictions on the presence of aqueous fluid during metamorphism , 1986, Mineralogical Magazine.

[9]  T. Nishiyama Kinetics of hydrofracturing and metamorphic veining , 1989 .

[10]  W. Carlson The significance of intergranular diffusion to the mechanisms and kinetics of porphyroblast crystallization , 1989 .

[11]  S. White Tectonic deformation and recrystallisation of oligoclase , 1975 .

[12]  B. Yardley Quartz veins and devolatilization during metamorphism , 1983, Journal of the Geological Society.

[13]  A. Peccerillo,et al.  The Vedrette di Ries (rieserferner) plutonic complex: Petrological and geochemical data bearing on its genesis , 1981 .

[14]  B. Cesare Hercynite as the product of staurolite decomposition in the contact aureole of Vedrette di Ries, eastern Alps, Italy , 1994 .

[15]  R. Tracy,et al.  Phase equilibria and thermobarometry of metapelites , 1991 .

[16]  S. Hoernes,et al.  Stable Isotope Geochemistry on the Intrusive Complex and Its Metamorphic Aureole , 1991 .

[17]  C. Guidotti Micas in metamorphic rocks , 1984 .

[18]  B. Wood,et al.  Rate and mechanism in prograde metamorphism , 1984 .

[19]  W. J. Phillips,et al.  Hydraulic fracturing and mineralization , 1972, Journal of the Geological Society.

[20]  P. Misch Paracrystalline microboudinage of zoned grains and other criteria for synkinematic growth of metamorphic minerals , 1969 .

[21]  H. Ramberg The Origin of Metamorphic and Metasomatic Rocks: A TREATISE ON RECRYSTALLIZATION AND REPLACEMENT IN THE EARTH'S CRUST , 1952 .

[22]  A. Lasaga The atomistic basis of kinetics; defects in minerals , 1981 .

[23]  J. Walther,et al.  Volatile production and transport in regional metamorphism , 1982 .

[24]  J. Ridley Modelling of the relations between reaction enthalpy and the buffering of reaction progress in metamorphism , 1986, Mineralogical Magazine.

[25]  R. L. Gresens Tectonic-hydrothermal pegmatites , 1967 .

[26]  C. A. Chapman The Origin of Metamorphic and Metasomatic Rocks. Hans Ramberg , 1954 .

[27]  C. Heinrich Eclogite Facies Regional Metamorphism of Hydrous Mafic Rocks in the Central Alpine Adula Nappe , 1986 .

[28]  E. Ghent,et al.  Pressure-temperature and evolution of fluid compositions of Al2SiO5-bearing rocks, Mica Creek, B.C., in light of fluid inclusion data and mineral equilibria , 1986 .

[29]  A. Thompson,et al.  The Role of Mineral Kinetics in the Development of Metamorphic Microtextures , 1986 .

[30]  A. B. Thompson,et al.  Some aspects of fluid motion during metamorphism , 1987, Journal of the Geological Society.

[31]  A. Lasaga Metamorphic reaction rate laws and development of isograds , 1986, Mineralogical Magazine.

[32]  J. Connolly,et al.  Migration of metamorphic fluid: some aspects of mass and heat transfer , 1992 .

[33]  D. Kerrick Al2SiO5-bearing segregations in the Lepontine Alps, Switzerland: Aluminum mobility in metapelites , 1988 .

[34]  S. Bottrell,et al.  Silica mobility and fluid movement during metamorphism of the Connemara schists, Ireland , 1992 .

[35]  J. Brenan Development and maintenance of metamorphic permeability; implications for fluid transport , 1991 .

[36]  J. Connolly,et al.  Fluid and enthalpy production during regional metamorphism , 1989 .

[37]  B. Yardley Fluid Migration and Veining in the Connemara Schists, Ireland , 1986 .