Migration of gas bubbles in irradiated uranium dioxide

Migration of fission gas bubbles in irradiated UO2 was studied, using electron microscopy, under isothermal annealing conditions at 1400, 1450 and 1500° C. Bubbles with radii greater than 37 A had a dependence of bubble migration distance on bubble radius which was characteristic of a migration mechanism controlled by volume diffusion. Migration rates were very much smaller than would be predicted from a surface-diffusion-controlled mechanism. The activation energy for bubble migration was found to be 130 000 cal/mole. Smaller bubbles migrated at a slower rate than predicted by a volume-diffusion-controlled mechanism.