A polygeneration system for the methanol production and the power generation with the solar–biomass thermal gasification☆

Abstract A polygeneration system of generating methanol and power with the solar thermal gasification of the biomass is proposed in this work. The endothermic reactions of the biomass gasification are driven by the concentrated solar thermal energy in a range of 1000–1500 K. The syngas from the biomass gasification is used to produce the methanol via a synthesis reactor. The un-reacted gas is used for the power generation via a combined cycle power unit. The thermodynamic and economic performances of the polygeneration system are investigated. A portion of the concentrated solar thermal energy can be chemically stored into the syngas, and thus the energy level of the solar thermal energy is improved. Numerical simulations are implemented to evaluate the thermal performances of the proposed polygeneration system. The results indicate that H2/CO molar ratio of the syngas reaches 1.43–1.89, which satisfies the requirements of the methanol synthesis. The highest energy efficiency and the exergy efficiency of the polygeneration system approximately are 56.09% and 54.86%, respectively. The proposed polygeneration system can achieve the stable utilization of the solar energy and the mitigation of CO2 emission, and thus a promising approach is introduced for the efficient utilization of the abundant solar and biomass resources in the Western China.

[1]  J. C. Bruno,et al.  State of the art on reactor designs for solar gasification of carbonaceous feedstock , 2013 .

[2]  Linghong Zhang,et al.  Overview of recent advances in thermo-chemical conversion of biomass. , 2010 .

[3]  A. Kruse Hydrothermal biomass gasification , 2009 .

[4]  Qiang Lu,et al.  Overview of fuel properties of biomass fast pyrolysis oils , 2009 .

[5]  T. Kodama High-temperature solar chemistry for converting solar heat to chemical fuels , 2003 .

[6]  Tatsuya Kodama,et al.  CO2 gasification of coal cokes using internally circulating fluidized bed reactor by concentrated Xe-light irradiation for solar gasification , 2012 .

[7]  Alberto Coronas,et al.  Review and analysis of biomass gasification models , 2010 .

[8]  A. Bridgwater Review of fast pyrolysis of biomass and product upgrading , 2012 .

[9]  Gilles Flamant,et al.  Synthetic fuels from biomass using concentrated solar energy – A review , 2012 .

[10]  K. Stȧhl,et al.  IGCC power plant for biomass utilisation, Värnamo, Sweden , 1997 .

[11]  R. Moghadam,et al.  Investigation on syngas production via biomass conversion through the integration of pyrolysis and air–steam gasification processes , 2014 .

[12]  Theodoros Damartzis,et al.  Thermochemical conversion of biomass to second generation biofuels through integrated process design—A review , 2011 .

[13]  I. Dincer Renewable energy and sustainable development: a crucial review , 2000 .

[14]  Thore Berntsson,et al.  System aspects of biomass gasification with methanol synthesis – Process concepts and energy analysis , 2012 .

[15]  A. Steinfeld,et al.  Solar-Driven Coal Gasification in a Thermally Irradiated Packed-Bed Reactor , 2008 .

[16]  R. Williams,et al.  Co-production of hydrogen, electricity and CO2 from coal with commercially ready technology. Part B: Economic analysis , 2005 .

[17]  A. Faaij,et al.  Exploration of the possibilities for production of Fischer Tropsch liquids and power via biomass gasification , 2002 .

[18]  J. Davidson,et al.  Integration of Solar Gasification With Conventional Fuel Production: The Roles of Storage and Hybridization , 2014 .

[19]  Ashok A. Kaniyal,et al.  Polygeneration of Liquid Fuels and Electricity by the Atmospheric Pressure Hybrid Solar Gasification of Coal , 2013 .

[20]  Eric D. Larson,et al.  Synthetic fuel production by indirect coal liquefaction , 2003 .

[21]  Xiangping Zhang,et al.  Concentrating-solar biomass gasification process for a 3rd generation biofuel. , 2009, Environmental science & technology.

[22]  M. Romero,et al.  Hydrogen production by steam-gasification of petroleum coke using concentrated solar power—II Reactor design, testing, and modeling , 2006 .

[23]  S. Iniyan,et al.  A review of solar thermal technologies , 2010 .

[24]  A. Steinfeld,et al.  Experimental investigation of a packed-bed solar reactor for the steam-gasification of carbonaceous feedstocks , 2009 .

[25]  V. Kirubakaran,et al.  A review on gasification of biomass , 2009 .

[26]  A. Steinfeld,et al.  Solar-driven gasification of carbonaceous feedstock-a review , 2011 .

[27]  Ibrahim Dincer,et al.  Thermodynamic assessment of an integrated solar power tower and coal gasification system for multi-generation purposes , 2013 .