Electron impact ionization and dissociation of CO2+ to C+ and O+

Absolute cross sections for electron impact ionization and dissociation of CO2+ to form C+ and O+ fragments are measured in the energy range from threshold to 2500 eV. The animated crossed-beams method has been employed. The ionization cross section shows a maximum of 4.79 x 10(-17) cm(2) at 130 eV and the corresponding threshold is found in good agreement with previous measurements. Both dissociation cross sections are shown to exhibit wide plateaux which are of the same order of magnitude. In addition, these cross sections almost coincide above 100 eV. The threshold energy and kinetic energy released are determined for both the production of C+ and O+. They are found in good agreement with the previously published data obtained in electron impact ionization experiments of neutral CO2.

[1]  A. Siari,et al.  Asymmetrical dissociative ionization of N-2(+) and O-2(+) by electron impact , 1999 .

[2]  C. Vidal,et al.  Electron impact dissociative ionization of CO2: Measurements with a focusing time-of-flight mass spectrometer , 1998 .

[3]  J. R. Peterson,et al.  Dissociative recombination and excitation of N2+: Cross sections and product branching ratios , 1998 .

[4]  A. Siari,et al.  Ionization and dissociative ionization of CO+ by electron impact , 1997 .

[5]  N. Djurić,et al.  Measurement of light fragments in dissociative excitation of molecular ions: CD+ , 1997 .

[6]  Pedersen,et al.  Production of Water Molecules from Dissociative Recombination of H3O + with Electrons. , 1996, Physical review letters.

[7]  R. Locht,et al.  The dissociative electroionization of carbon dioxide by low-energy electron impact. The C+, O+ and CO+ dissociation channels , 1995 .

[8]  H. Hogreve Stability properties of CO22 , 1995 .

[9]  M. Zambra,et al.  Electron impact double ionization of singly charged ions C + , N + , O + , F + and Ne + , 1994 .

[10]  V. Berardi,et al.  Kinetic-energy distributions of charged fragments from CO2 dissociative ionization , 1994 .

[11]  Thomas A. Field,et al.  Lifetimes of metastable molecular doubly charged ions , 1993 .

[12]  M. Grieser,et al.  Molecular physics in a storage ring: dissociative recombination and excitation of cold HD+ , 1993 .

[13]  L. Avaldi,et al.  Direct observation of vibrational states of CO2+ and N22+ by threshold photoelectrons coincidence spectroscopy , 1992 .

[14]  Mitchell,et al.  Dissociative recombination and excitation of D3+ , 1991, Physical review. A, Atomic, molecular, and optical physics.

[15]  P. A. Schulz,et al.  Electron‐impact dissociation of H3O+ , 1986 .

[16]  J. Mitchell,et al.  The dissociative recombination and excitation of CO , 1985 .

[17]  W. Claeys,et al.  Crossed beam measurement of absolute cross sections: an alternative method and its application to the electron impact ionisation of He+ , 1981 .

[18]  J. Eland,et al.  Mass spectra and doubly charged ions in photoionization at 30.4 nm and 58.4 nm , 1980 .

[19]  H. Klein,et al.  Ionisation of CO2+ ions by electron impact , 1980 .

[20]  C. E. Brion,et al.  Absolute oscillator strengths for valence-shell ionic photofragmentations of N2O and CO2 (8–75 eV) , 1980 .

[21]  T. Märk,et al.  Cross section for single and double ionization of carbon dioxide by electron impact from threshold up to 180 eV , 1978 .

[22]  P. Marmet,et al.  Ionization and dissociative ionization of CO2 by electron impact , 1977 .

[23]  J. McConkey,et al.  Dissociative ionization by electron impact 111. O', CO' and C' from CO2 , 1974 .

[24]  T. A. Williams,et al.  The observation of “forbidden” transitions in He II photoelectron spectra , 1974 .

[25]  K. McCulloh Photoionization of carbon dioxide , 1973 .

[26]  J. Eland Predissociation of triatomic ions studied by photo-electron-photoion coincidence spectroscopy and photoion kinetic energy analysis: I. CO2+ , 1972 .

[27]  J. Eland,et al.  Photoelectron spectra and ionic structure of carbon dioxide, carbon disulphide and sulphur dioxide , 1968 .

[28]  J. Cuthbert,et al.  Sequential mass spectrometry III. Ions and fragments from carbon dioxide and disulphide , 1968 .

[29]  G. Dunn,et al.  DISSOCIATION OF N$sub 2$$sup +$ AND O$sub 2$$sup +$ BY ELECTRON IMPACT. , 1967 .

[30]  James A. Walker,et al.  Mass-Spectrometric Study of Photoionization. VI. O 2 , CO 2 , COS, and CS 2 † , 1967 .

[31]  J. Peek Theory of Dissociation of H 2 + by Fast Electrons , 1967 .

[32]  G. Dunn,et al.  Electron Impact Dissociation of H+2 , 1967 .

[33]  M. Harrison The determination of atomic collision cross sections using crossed electron and ion beams (and some sources of error in such experiments) , 1966 .

[34]  A. Sciamanna,et al.  METASTABLE STATE OF THE DOUBLY CHARGED CARBON DIOXIDE ION , 1964 .