Activity and Stability of Carbon Supported PtxY Alloys for the ORR Determined by RDE and Single-Cell PEMFC Measurements

Bimetallic alloys based on Pt and Y are potential cathode catalysts for proton exchange membrane fuel cells (PEMFCs) due to their high oxygen reduction reaction (ORR) activity. Nevertheless, the synthesis of carbon supported Pt x Y catalysts is challenging due to the low standard reduction potential of yttrium compared to platinum. Hence, extended electrochemical testing in actual PEMFCs remains elusive, especially with respect to catalyst degradation upon voltage-cycling. In this publication, we present the synthesis of a bimetallic Pt x Y/C catalyst via impregnation of commercial Pt/C with an yttrium halide precursor and subsequent heat-treatment in H 2 at 1200 ◦ C. This catalyst showed a high specific ORR activity, at a mass activity similar to Pt/C due to its comparably low electrochemical surface area ( ECSA ). On the other hand, the large particle size of the here synthesized Pt x Y/C catalyst ( ≈ 10 nm) resulted in a significantly enhanced stability versus degradation in an accelerated stress test (AST) based on voltage-cycling between 0.6 and 1.0 V RHE at 50 mV s − 1 , showing a superior ECSA , ORR activity and H 2 /air performance after 30000 cycles compared to a standard Pt/C catalyst. particle size ), , i 0 . 9 V , i 0 . 9 V and the enhancement factor of the specific ORR activity ( f spec ) and ORR mass activity ( f mass ) compared to the Pt/C The data from this study represents the leached Pt x Y/C catalyst, activated by 50 cycles between 0.05 and 1.20 V RHE 50 mV s − and measured in 2 -saturated 0.1 M 4 25 10 mV s