An oxo-verdazyl radical for a symmetrical non-aqueous redox flow battery

Verdazyl free radical compounds are promising candidates for symmetrical all-organic redox flow batteries (RFBs) due to their redox stability, the ease with which their chemical structure can be varied, and their unique bipolar nature.

[1]  M. Winter,et al.  Toward Green Battery Cells: Perspective on Materials and Technologies , 2020 .

[2]  J. Chai,et al.  PEGylation-Enabled Extended Cyclability of a Non-Aqueous Redox Flow Battery. , 2020, ACS applied materials & interfaces.

[3]  S. Minteer,et al.  Realization of an Asymmetric Non-Aqueous Redox Flow Battery Through Molecular Design to Minimize Active Species Crossover and Decomposition. , 2020, Chemistry.

[4]  M. Winter,et al.  Development of Safe and Sustainable Dual‐Ion Batteries Through Hybrid Aqueous/Nonaqueous Electrolytes , 2020, Advanced Energy Materials.

[5]  A combined morphological and electrochemical characterization of carbon electrodes in vanadium redox flow batteries: Insights into positive and negative electrode performance , 2020 .

[6]  T. Zhao,et al.  A high power density and long cycle life vanadium redox flow battery , 2020 .

[7]  Marcus Gebhard,et al.  Universal Algorithm for Simulating and Evaluating Cyclic Voltammetry at Macroporous Electrodes by Considering Random Arrays of Microelectrodes , 2019, Chemphyschem : a European journal of chemical physics and physical chemistry.

[8]  L. Gubler.  Membranes and separators for redox flow batteries , 2019 .

[9]  J. Hjelm,et al.  Molecular Engineering Strategies for Symmetric Aqueous Organic Redox Flow Batteries , 2019, ACS Materials Letters.

[10]  Kathryn E. Toghill,et al.  Application of the dianion croconate violet for symmetric organic non-aqueous redox flow battery electrolytes , 2019, Journal of Power Sources.

[11]  Matthew S Sigman,et al.  Mechanism-Based Design of a High-Potential Catholyte Enables a 3.2 V All-Organic Nonaqueous Redox Flow Battery. , 2019, Journal of the American Chemical Society.

[12]  T. L. Liu,et al.  Status and Prospects of Organic Redox Flow Batteries toward Sustainable Energy Storage , 2019, ACS Energy Letters.

[13]  L. F. Arenas,et al.  Redox flow batteries for energy storage: their promise, achievements and challenges , 2019, Current Opinion in Electrochemistry.

[14]  J. Gilroy,et al.  A bipolar verdazyl radical for a symmetric all-organic redox flow-type battery , 2019, Journal of Energy Chemistry.

[15]  Matthew S. Sigman,et al.  Developing a Predictive Solubility Model for Monomeric and Oligomeric Cyclopropenium-Based Flow Battery Catholytes. , 2019, Journal of the American Chemical Society.

[16]  Yu Ding,et al.  Biredox Eutectic Electrolytes Derived from Organic Redox-Active Molecules: High-Energy Storage Systems. , 2019, Angewandte Chemie.

[17]  Marcus Gebhard,et al.  Theory of cyclic voltammetry in random arrays of cylindrical microelectrodes applied to carbon felt electrodes for vanadium redox flow batteries. , 2019, Physical chemistry chemical physics : PCCP.

[18]  N-(α-ferrocenyl)ethylphthalimide as a single redox couple for non-aqueous flow batteries , 2019, Journal of Power Sources.

[19]  Jie Li,et al.  Characteristics of charge/discharge and alternating current impedance in all-vanadium redox flow batteries , 2019, Energy.

[20]  M. Winter,et al.  Before Li Ion Batteries. , 2018, Chemical reviews.

[21]  Yu Ding,et al.  Gradient‐Distributed Metal–Organic Framework–Based Porous Membranes for Nonaqueous Redox Flow Batteries , 2018, Advanced Energy Materials.

[22]  M. N. Uvarov,et al.  Verdazyl Radical Building Blocks: Synthesis, Structure, and Sonogashira Cross‐Coupling Reactions , 2018 .

[23]  Yi‐Chun Lu,et al.  Recent progress in organic redox flow batteries: Active materials, electrolytes and membranes , 2018, Journal of Energy Chemistry.

[24]  Licheng Miao,et al.  Porphyrin-Based Symmetric Redox-Flow Batteries towards Cold-Climate Energy Storage. , 2018, Angewandte Chemie.

[25]  K. Stevenson,et al.  Cobalt and Vanadium Trimetaphosphate Polyanions: Synthesis, Characterization, and Electrochemical Evaluation for Non-aqueous Redox-Flow Battery Applications. , 2018, Journal of the American Chemical Society.

[26]  Yu Ding,et al.  Molecular engineering of organic electroactive materials for redox flow batteries. , 2018, Chemical Society reviews.

[27]  M. R. Mohamed,et al.  Recent developments in organic redox flow batteries: A critical review , 2017 .

[28]  Martin Winter,et al.  Lithium ion, lithium metal, and alternative rechargeable battery technologies: the odyssey for high energy density , 2017, Journal of Solid State Electrochemistry.

[29]  M. Mench,et al.  Elucidating effects of cell architecture, electrode material, and solution composition on overpotentials in redox flow batteries , 2017 .

[30]  Sean E. Doris,et al.  Macromolecular Design Strategies for Preventing Active-Material Crossover in Non-Aqueous All-Organic Redox-Flow Batteries. , 2017, Angewandte Chemie.

[31]  Ulrich S. Schubert,et al.  Redox‐Flow Batteries: From Metals to Organic Redox‐Active Materials , 2016, Angewandte Chemie.

[32]  U. Schubert,et al.  A bipolar nitronyl nitroxide small molecule for an all-organic symmetric redox-flow battery , 2017 .

[33]  M. Winter,et al.  Best Practice: Performance and Cost Evaluation of Lithium Ion Battery Active Materials with Special Emphasis on Energy Efficiency , 2016 .

[34]  David M. Reed,et al.  A High-Current, Stable Nonaqueous Organic Redox Flow Battery , 2016 .

[35]  Zijing Ding,et al.  Networked Spin Cages: Tunable Magnetism and Lithium Ion Storage via Modulation of Spin-Electron Interactions. , 2016, Inorganic chemistry.

[36]  Alexandre Lucas,et al.  Smart Grid Energy Storage Controller for Frequency Regulation and Peak Shaving, using a Vanadium Redox Flow Battery , 2016 .

[37]  R. Kühnel,et al.  "Water-in-salt" electrolytes enable the use of cost-effective aluminum current collectors for aqueous high-voltage batteries. , 2016, Chemical communications.

[38]  U. Schubert,et al.  Polymer-Based Organic Batteries. , 2016, Chemical reviews.

[39]  Fikile R. Brushett,et al.  A symmetric organic-based nonaqueous redox flow battery and its state of charge diagnostics by FTIR , 2016 .

[40]  Wei Wang,et al.  Energy storage: Redox flow batteries go organic. , 2016, Nature chemistry.

[41]  James R. McKone,et al.  On the Benefits of a Symmetric Redox Flow Battery , 2016 .

[42]  N. Doltsinis,et al.  Effect of the C(3)-Substituent in Verdazyl Radicals on their Profluorescent Behavior. , 2016, Chimia.

[43]  Ke Gong,et al.  Nonaqueous redox-flow batteries: organic solvents, supporting electrolytes, and redox pairs , 2015, Energy & Environmental Science.

[44]  Joaquín Rodríguez-López,et al.  Evolutionary Design of Low Molecular Weight Organic Anolyte Materials for Applications in Nonaqueous Redox Flow Batteries. , 2015, Journal of the American Chemical Society.

[45]  T. J. Davies,et al.  The electrochemical characterisation of graphite felts , 2015 .

[46]  N. Doltsinis,et al.  Profluorescent verdazyl radicals – synthesis and characterization† †Electronic supplementary information (ESI) available. CCDC 1051008–1051011. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc00724k Click here for additional data file. Click here for addition , 2015, Chemical science.

[47]  Sam F. Y. Li,et al.  Nonaqueous redox-flow batteries: features, challenges, and prospects , 2015 .

[48]  Gao Yan,et al.  A coupled three dimensional model of vanadium redox flow battery for flow field designs , 2014 .

[49]  Kevin G. Gallagher,et al.  Pathways to Low Cost Electrochemical Energy Storage: A Comparison of Aqueous and Nonaqueous Flow Batteries , 2014 .

[50]  C. Roth,et al.  Determination of Overpotentials in All Vanadium Redox Flow Batteries , 2014 .

[51]  A. Lasia.  Electrochemical Impedance Spectroscopy and its Applications , 2014 .

[52]  Seung-Hyeon Moon,et al.  A review of current developments in non-aqueous redox flow batteries: characterization of their membranes for design perspective , 2013 .

[53]  S. Ramanathan,et al.  Effect of potential drifts and ac amplitude on the electrochemical impedance spectra , 2011 .

[54]  V. Nikonenko,et al.  Electrical equivalent circuit of an ion-exchange membrane system , 2011 .

[55]  R. Hicks.  Stable radicals : fundamentals and applied aspects of odd-electron compounds , 2010 .

[56]  R. Compton,et al.  The Influence of Electrode Porosity on Diffusional Cyclic Voltammetry , 2008 .

[57]  R. Compton,et al.  Cyclic voltammetry on electrode surfaces covered with porous layers: An analysis of electron transfer kinetics at single-walled carbon nanotube modified electrodes , 2008 .

[58]  B. Koivisto,et al.  Electrochemical studies of verdazyl radicals. , 2007, Organic letters.

[59]  B. Koivisto,et al.  The magnetochemistry of verdazyl radical-based materials , 2005 .