Tunable Magneto-Dielectric Polymer Nanocomposites for Microwave Applications

Magneto-dielectric polymer nanocomposites are investigated as a new class of functional materials well suited for RF and microwave device applications. Magnetite (Fe3O4) nanoparticles are homogeneously dispersed in a polymer matrix, which exhibits low losses at microwave frequencies. The monodispersion of the magnetic nanoparticles, with sub-10-nm diameters and tight size distribution, enhances the microwave properties of the engineered composite material by increasing the relative permeability and relative permittivity. Moreover, complex permeability and permittivity of the nanocomposite material can be tuned by an externally applied dc magnetic field with a strength that is achievable with commercial permanent magnets. Multilayered microstrip test fixtures and preexisting measurement techniques were conjointly implemented to extract the microwave properties of the nanocomposite material in the frequency range between 1-6 GHz. The measured data revealed tunability of 5.5% in the permittivity, 37% in the permeability, and more than 100× reduction in the loss tangent at specific frequencies under externally applied magnetic fields.

[1]  E. Hammerstad,et al.  Accurate Models for Microstrip Computer-Aided Design , 1980, 1980 IEEE MTT-S International Microwave symposium Digest.

[2]  T. Weller,et al.  Magnetically tunable nanocomposites for microwave applications , 2010, 2010 IEEE MTT-S International Microwave Symposium.

[3]  Analysis of linear microstrip using an arbitrary ferromagnetic substance as the substrate , 1969 .

[4]  W. R. Eisenstadt,et al.  S-parameter-based IC interconnect transmission line characterization , 1992 .

[5]  R. A. Pucel,et al.  Microstrip Propagation on Magnetic Substrates - Part I: Design Theory , 1972 .

[6]  Hariharan Srikanth,et al.  Superparamagnetic Polymer Nanocomposites with Uniform Fe3O4 Nanoparticle Dispersions , 2006 .

[7]  S. Dutz,et al.  Effects of size distribution on hysteresis losses of magnetic nanoparticles for hyperthermia , 2008, Journal of physics. Condensed matter : an Institute of Physics journal.

[8]  Y. Yao,et al.  Dielectric constant at x-band microwave frequencies for multiferroic BiFeO3 thin films , 2009 .

[9]  J. Svac̆ina Analysis of multilayer microstrip lines by a conformal mapping method , 1992 .

[10]  R. Kotsilkova,et al.  Design and characterization of polymer nanocomposites for microwave absorbing applications , 2004, 2004 International Semiconductor Conference. CAS 2004 Proceedings (IEEE Cat. No.04TH8748).

[11]  J. Dutcher,et al.  Soft materials : structure and dynamics , 2004 .

[12]  E. Yamashita Variational Method for the Analysis of Microstrip-Like Transmission Lines , 1968 .

[13]  E. J. Vanzura,et al.  Improved technique for determining complex permittivity with the transmission/reflection method , 1990 .

[14]  G. Srinivasan,et al.  Q factor of dual-tunable microwave resonators based on yttrium iron garnet and barium strontium titanate layered structures , 2008 .

[15]  J. L. Wilson,et al.  Synthesis and magnetic properties of polymer nanocomposites with embedded iron nanoparticles , 2004 .

[16]  Ta-I. Yang Low loss polymer nanoparticle composites for radio frequency applications. , 2011 .

[17]  R. Jansen,et al.  Accurate model for effective dielectric constant of microstrip with validity up to millimetre-wave frequencies , 1982 .

[18]  A. A. Semenov,et al.  Ferrite-ferroelectric layered structures for electrically and magnetically tunable microwave resonators , 2006 .

[19]  Z. Hu,et al.  A Novel Broadband Metamaterial Resonator with Negative Permittivity , 2010 .

[20]  M. Cao,et al.  Microwave absorption properties of multiferroic BiFeO3 nanoparticles , 2009 .

[21]  A. Farrar,et al.  Multilayer Microstrip Transmission Lines (Short Papers) , 1974 .

[22]  A. M. Nicolson,et al.  Measurement of the Intrinsic Properties of Materials by Time-Domain Techniques , 1970 .

[23]  Ji Zhou,et al.  Magnetic tuning of electrically resonant metamaterial with inclusion of ferrite , 2008 .

[24]  A. A. Semenov,et al.  Dual-tunable hybrid wave ferrite-ferroelectric microwave resonator , 2006 .

[25]  H. A. Wheeler Transmission-Line Properties of Parallel Wide Strips by a Conformal-Mapping Approximation , 1964 .

[26]  J. Svac̆ina A simple quasi-static determination of basic parameters of multilayer microstrip and coplanar waveguide , 1992, IEEE Microwave and Guided Wave Letters.

[27]  W. Weir Automatic measurement of complex dielectric constant and permeability at microwave frequencies , 1974 .

[28]  Ming Liu,et al.  Giant microwave tunability in FeGaB/lead magnesium niobate-lead titanate multiferroic composites , 2008 .

[29]  Q. Pankhurst,et al.  Size and Concentration Effects on High Frequency Hysteresis of Iron Oxide Nanoparticles , 2007, IEEE Transactions on Magnetics.

[30]  Nian X. Sun,et al.  Strong magnetoelectric coupling at microwave frequencies in metallic magnetic film/lead zirconate titanate multiferroic composites , 2008 .