Electrical and structural characteristics of fish skin gelatin as alternative biopolymer electrolyte

This article presented new sequences of fish gelatin (FG) as a polymer host for solid polymer electrolytes (SPEs) impregnated with ammonium nitrate (NH4NO3) and the impact of different amounts of salt on the properties of the formed electrolyte were investigated. X-ray diffraction (XRD) analysis revealed that the electrolyte containing 25 wt.% NH4NO3 salt to be the most amorphous in nature. Fourier transform infrared (FTIR) spectroscopy analysis showed that the peak of amide III shifted to a lower wavenumber as salt increased to 25 wt.%, indicating the occurrence of interaction between the salt and polymer. The effect of variation amount of salt on the film morphology was studied using FESEM. The ionic conductivity of the undoped pure FG film at room temperature recorded a maximum value of 1.52±0.30×10−5Scm−1 at 25 wt.% NH4NO3 and the activation energy dropped to 0.454 eV. All electrolytes showed a linear conductivity-temperature plot at elevated temperatures, indicating that they all follow the Arrhenius rule. All of the electrolytes used in this study are non-Debye type, according to dielectric analysis. The findings provided in this article could help to improve the usage of FG as an alternate source of SPE in electrochemical power sources as a replacement for hazardous electrolytes.

[1]  S. Selvasekarapandian,et al.  Development of biopolymer electrolyte membrane using Gellan gum biopolymer incorporated with NH4SCN for electro-chemical application , 2021, Ionics.

[2]  Xiaoli Liu,et al.  Preparation and properties of a novel green solid polymer electrolyte for all‐solid‐state lithium battery , 2021 .

[3]  Xichang Wang,et al.  Fish oil-gelatin core-shell electrospun nanofibrous membranes as promising edible films for the encapsulation of hydrophobic and hydrophilic nutrients , 2021, LWT.

[4]  M. Prakash,et al.  Incorporation of organic additives with electron rich donors (N, O, S) in gelatin gel polymer electrolyte for dye sensitized solar cells , 2021 .

[5]  N. K. Jyothi,et al.  Thermal, Structural, Optical and Electrical Conductivity studies of pure and Mn2+ doped PVP films , 2021 .

[6]  W. Wang,et al.  A robust interface enabled by electrospun membrane with optimal resistance in lithium metal batteries , 2021, Journal of Energy Chemistry.

[7]  M. Kadir.  Non-Faradaic-based supercapacitor fabricated with fish skin gelatin biopolymer electrolyte , 2021, Ionics.

[8]  Lingzhu Zhao,et al.  Cathode/gel polymer electrolyte integration design based on continuous composition and preparation technique for high performance lithium ion batteries , 2021, RSC advances.

[9]  Lei Zhang,et al.  Ion transport in topological all‐solid‐state polymer electrolyte improved via graphene‐oxide , 2021 .

[10]  K. H. Ibnaouf,et al.  Optimization of the Electrochemical Performance of a Composite Polymer Electrolyte Based on PVA-K2CO3-SiO2 Composite , 2020, Polymers.

[11]  M. F. Shukur,et al.  Nanocomposite polymer electrolytes comprising starch-lithium acetate and titania for all-solid-state supercapacitor , 2020, Ionics.

[12]  Pan Yang,et al.  Effect of doping CeO2 and Sc2O3 on structure, thermal properties and sintering resistance of YSZ , 2020 .

[13]  Maryam A. Saeed,et al.  Effect of Structural Features on Ionic Conductivity and Dielectric Response of PVA Proton Conductor-Based Solid Polymer Electrolytes , 2020, Journal of Electronic Materials.

[14]  S. Rostam,et al.  Compatible Solid Polymer Electrolyte Based on Methyl Cellulose for Energy Storage Application: Structural, Electrical, and Electrochemical Properties , 2020, Polymers.

[15]  J. Wootthikanokkhan,et al.  Gelatin-based solid electrolytes for chromogenic windows applications: a review , 2020, Ionics.

[16]  M. F. Shukur,et al.  Effect of ammonium thiocyanate on ionic conductivity and thermal properties of polyvinyl alcohol–methylcellulose–based polymer electrolytes , 2020, Ionics.

[17]  Elham M. A. Dannoun,et al.  The Study of Plasticized Amorphous Biopolymer Blend Electrolytes Based on Polyvinyl Alcohol (PVA): Chitosan with High Ion Conductivity for Energy Storage Electrical Double-Layer Capacitors (EDLC) Device Application , 2020, Polymers.

[18]  H. Anuar,et al.  Metal framework as a novel approach for the fabrication of electric double layer capacitor device with high energy density using plasticized Poly(vinyl alcohol): Ammonium thiocyanate based polymer electrolyte , 2020, Arabian Journal of Chemistry.

[19]  Federica Stella Blasi,et al.  Marine collagen and its derivatives: Versatile and sustainable bio-resources for healthcare. , 2020, Materials science & engineering. C, Materials for biological applications.

[20]  N. A. Manan,et al.  Structural, impedance and electrochemical double-layer capacitor characteristics of improved number density of charge carrier electrolytes employing potato starch blend polymers , 2020, Ionics.

[21]  R. Mohamed,et al.  Characterization of Solid Polymer Electrolyte Membrane made of Methylcellulose and Ammonium Nitrate , 2020, Journal of Physics: Conference Series.

[22]  S. Selvasekarapandian,et al.  Impact of lithium triflate (LiCF3SO3) salt on tamarind seed polysaccharide-based natural solid polymer electrolyte for application in electrochemical device , 2020, Polymer Bulletin.

[23]  M. Isa,et al.  Correlation between structural, ion transport and ionic conductivity of plasticized 2-hydroxyethyl cellulose based solid biopolymer electrolyte , 2020 .

[24]  M. Brza,et al.  Protonic EDLC cell based on chitosan (CS): methylcellulose (MC) solid polymer blend electrolytes , 2020, Ionics.

[25]  M. S. Su’ait,et al.  Bio-Based Polymer Electrolytes for Electrochemical Devices: Insight into the Ionic Conductivity Performance , 2020, Materials.

[26]  N. A. Manan,et al.  Solid-state double layer capacitors and protonic cell fabricated with dextran from Leuconostoc mesenteroides based green polymer electrolyte , 2020 .

[27]  M. F. Shukur,et al.  Influence of $$\hbox {NH}_{4}$$Br as an ionic source on the structural/electrical properties of dextran-based biopolymer electrolytes and EDLC application , 2020 .

[28]  Yanhua Zhang,et al.  Construction of Polymer Electrolyte Based on Soybean Protein Isolate and Hydroxyethyl Cellulose for a Flexible Solid-State Supercapacitor , 2019, Polymers.

[29]  M. Kadir,et al.  A Promising Polymer Blend Electrolytes Based on Chitosan: Methyl Cellulose for EDLC Application with High Specific Capacitance and Energy Density , 2019, Molecules.

[30]  H. Wiemhöfer,et al.  Insights into a layered hybrid solid electrolyte and its application in long lifespan high-voltage all-solid-state lithium batteries , 2019, Journal of Materials Chemistry A.

[31]  S. Selvasekarapandian,et al.  Impact of lithium chlorate salts on structural and electrical properties of natural polymer electrolytes for all solid state lithium polymer batteries , 2019, Vacuum.

[32]  A. S. Samsudin,et al.  Study on the effect of PEG in ionic transport for CMC-NH4Br-based solid polymer electrolyte , 2018, Ionics.

[33]  M. Kadir,et al.  A conceptual review on polymer electrolytes and ion transport models , 2018 .

[34]  M. Alagar,et al.  Conductive bio-polymer electrolyte iota-carrageenan with ammonium nitrate for application in electrochemical devices , 2018 .

[35]  Vanja Mandrić Radivojević,et al.  Measuring the Dielectric Constant of Paper Using a Parallel Plate Capacitor , 2018 .

[36]  M. Kadir,et al.  Green electrolytes based on dextran-chitosan blend and the effect of NH4SCN as proton provider on the electrical response studies , 2018, Ionics.

[37]  M. A. Rasheed,et al.  Incorporation of NH4NO3 into MC-PVA blend-based polymer to prepare proton-conducting polymer electrolyte films , 2018, Ionics.

[38]  K. Lee,et al.  Fish gelatin nanofibers prevent drug crystallization and enable ultrafast delivery , 2017 .

[39]  J. Álvarez-Ramírez,et al.  The order of addition of corn starch/lithium perchlorate/glycerol affects the optical, mechanical, and electrical properties of a solid polymer electrolyte , 2017, Ionics.

[40]  M. Premalatha,et al.  Biopolymer agar‐agar doped with NH4SCN as solid polymer electrolyte for electrochemical cell application , 2017 .

[41]  S. Ramesh,et al.  Ionic conductivity enhancement studies of composite polymer electrolyte based on poly (vinyl alcohol)-lithium perchlorate-titanium oxide , 2017 .

[42]  S. Pugalendhi,et al.  Development of proton conducting biopolymer membrane based on agar–agar for fuel cell , 2017, Ionics.

[43]  M. Premalatha,et al.  Investigations on proton conducting biopolymer membranes based on tamarind seed polysaccharide incorporated with ammonium thiocyanate , 2016 .

[44]  M. C. Garrigós,et al.  Gelatin-Based Films and Coatings for Food Packaging Applications , 2016 .

[45]  S. Tarafdar,et al.  Influence of gamma irradiation on the electrical properties of LiClO 4 -gelatin solid polymer electrolytes: Modelling anomalous diffusion through generalized calculus , 2016 .

[46]  S. Karthikeyan,et al.  Preparation and characterization of biopolymer electrolyte based on cellulose acetate for potential applications in energy storage devices , 2016, Journal of Materials Science: Materials in Electronics.

[47]  M. Muthuvinayagam,et al.  Characterization of proton conducting polymer blend electrolytes based on PVdF-PVA , 2015 .

[48]  K. Abdelhady,et al.  Gelatin-based solid electrolyte releasing Li+ for smart window applications ☆ , 2014 .

[49]  M. Silva,et al.  Ionic liquids for solid-state electrolytes and electrosynthesis , 2014 .

[50]  M. F. Shukur,et al.  Electrical and transport properties of NH4Br-doped cornstarch-based solid biopolymer electrolyte , 2014, Ionics.

[51]  L. Rodrigues,et al.  Novel polymer electrolytes based on gelatin and ionic liquids , 2012 .

[52]  A. Arof,et al.  Proton-conducting polymer electrolyte films based on chitosan acetate complexed with NH4NO3 salt , 2005 .