Development of polymeric and polymer-based hybrid adsorbents for pollutants removal from waters

In the past decades polymeric adsorbents have been emerging as highly effective alternatives to activated carbons for pollutants removal and subsequent recovery from industrial effluents. More recently, the development of polymer-based hybrid adsorbents has opened up the new opportunities of their application in deep removal of inorganic pollutants like heavy metals from waters. The present review focuses on preparation of these polymeric-based adsorbents, their physicochemical properties, adsorption characteristics and mechanism, as well as their application in water purification.

[1]  G. Payne,et al.  Adsorptive separations based on the differences in solute-sorbent hydrogen-bonding strengths , 1991 .

[2]  G. A. Parks,et al.  Surface complexation of Pb(II) at oxide-water interfaces: I. XAFS and bond-valence determination of mononuclear and polynuclear Pb(II) sorption products on aluminum oxides , 1997 .

[3]  N. Jain,et al.  Agricultural and agro-processing wastes as low cost adsorbents for metal removal from wastewater: A review , 2008 .

[4]  R. Schwarzenbach,et al.  Distribution of hydrophobic ionogenic organic compounds between octanol and water: organic acids , 1990 .

[5]  Jou‐Hyeon Ahn,et al.  Adsorptive removal of phenolic compounds by using hypercrosslinked polystyrenic beads with bimodal pore size distribution , 2003 .

[6]  T. Anirudhan,et al.  An investigation into the sorption of heavy metals from wastewaters by polyacrylamide-grafted iron(III) oxide. , 2002, Journal of hazardous materials.

[7]  B. E. Reed,et al.  Modeling As(V) removal by a iron oxide impregnated activated carbon using the surface complexation approach. , 2005, Water research.

[8]  Qingrui Zhang,et al.  Selective heavy metals removal from waters by amorphous zirconium phosphate: behavior and mechanism. , 2007, Water research.

[9]  A. Raichur,et al.  Abatement of fluoride from water using manganese dioxide-coated activated alumina. , 2007, Journal of hazardous materials.

[10]  D. Sherrington,et al.  Evaluation of a new hypercrosslinked polymer as a sorbent for solid-phase extraction of polar compounds. , 2005, Journal of chromatography. A.

[11]  V. G. Pangarkar,et al.  Adsorptive separation and recovery of organics from PHBA and SA plant effluents , 2004 .

[12]  F. Morel,et al.  Surface Complexation Modeling: Hydrous Ferric Oxide , 1990 .

[14]  Aimin Li,et al.  Adsorption of dyes and phenol from water on resin adsorbents: effect of adsorbate size and pore size distribution. , 2006, Journal of hazardous materials.

[15]  K. Iha,et al.  Adsorption of di-2-pyridyl ketone salicyloylhydrazone on Amberlite XAD-2 and XAD-7 resins: characteristics and isotherms. , 2008, Journal of colloid and interface science.

[16]  G. Nickless,et al.  Use of amberlite XAD-4 for extraction and recovery of chlorinated insecticides and polychlorinated biphenyls from water , 1974 .

[17]  M. Streat,et al.  Removal of Pesticides from Water Using Hypercrosslinked Polymer Phases: Part 3— Mini-Column Studies and the Effect of Fulvic and Humic Substances , 1998 .

[18]  G. Alberti,et al.  A chelating resin as a probe for the copper(II) distribution in grape wines , 2007 .

[19]  P. Veverka,et al.  Mechanism of hypercrosslinking of chloromethylated styrene–divinylbenzene copolymers , 1999 .

[20]  V. Vilar,et al.  Metal biosorption by algae Gelidium derived materials from binary solutions in a continuous stirred adsorber , 2008 .

[21]  W. Shim,et al.  Adsorption and desorption dynamics of amino acids in a nonionic polymeric sorbent XAD-16 column , 2003 .

[22]  Chao Xu,et al.  Surface characteristics of crop-residue-derived black carbon and lead(II) adsorption. , 2008, Water research.

[23]  W. Lian-sheng,et al.  Adsorption of naphthalene derivatives on different macroporous polymeric adsorbents , 1997 .

[24]  B. Dempsey,et al.  Coadsorption of arsenic(III) and arsenic(V) onto hydrous ferric oxide: effects on abiotic oxidation of arsenic(III), extraction efficiency, and model accuracy. , 2008, Environmental science & technology.

[25]  A. Gürses,et al.  Adsorption of cationic dye from aqueous solutions by activated carbon , 2008 .

[26]  F. Morel,et al.  Sorption of Copper and Lead by Hydrous Ferric Oxide , 1980 .

[27]  Yong‐Ill Lee,et al.  A chelating resin containing 1-(2-thiazolylazo)-2-naphthol as the functional group; synthesis and sorption behavior for trace metal ions , 2001 .

[28]  V. V. Azanova,et al.  Sorption properties of macroporous and hypercrosslinked copolymers , 1999 .

[29]  Lee Blaney,et al.  Hybrid anion exchanger for trace phosphate removal from water and wastewater. , 2007, Water research.

[30]  K. Abburi.  Adsorption of phenol and p-chlorophenol from their single and bisolute aqueous solutions on Amberlite XAD-16 resin. , 2003, Journal of hazardous materials.

[31]  Najma Memon,et al.  Sawdust: A green and economical sorbent for thallium removal , 2008 .

[32]  B. Pan,et al.  Removal of aromatic sulfonates from aqueous media by aminated polymeric sorbents: Concentration-dependent selectivity and the application , 2008 .

[33]  Qingrui Zhang,et al.  Adsorptive removal of phenol from aqueous phase by using a porous acrylic ester polymer. , 2008, Journal of hazardous materials.

[34]  M. Dinu,et al.  Heavy metals adsorption on some iminodiacetate chelating resins as a function of the adsorption parameters , 2008 .

[35]  P. Huck,et al.  Adsorption characteristics of selected pharmaceuticals and an endocrine disrupting compound-Naproxen, carbamazepine and nonylphenol-on activated carbon. , 2008, Water research.

[36]  M. Bilgili.  Adsorption of 4-chlorophenol from aqueous solutions by xad-4 resin: isotherm, kinetic, and thermodynamic analysis. , 2006, Journal of hazardous materials.

[37]  J. Greenleaf,et al.  Arsenic removal using a polymeric/inorganic hybrid sorbent. , 2003, Water research.

[38]  S. Raisuddin,et al.  Genotoxic effects of arsenic: prevention by functional food-jaggery. , 2008, Cancer letters.

[39]  P. Chung,et al.  Adsorption of dichloromethane from water onto a hydrophobic polymer resin XAD-1600. , 2005, Water research.

[40]  A. Imyim,et al.  Extraction and preconcentration of toxic metal ions from aqueous solution using benzothiazole-based chelating resins , 2007 .

[41]  Qingrui Zhang,et al.  Selective sorption of lead, cadmium and zinc ions by a polymeric cation exchanger containing nano-Zr(HPO3S)2. , 2008, Environmental science & technology.

[42]  M. Soylak,et al.  Chromium speciation by solid phase extraction on Dowex M 4195 chelating resin and determination by atomic absorption spectrometry. , 2008, Journal of hazardous materials.

[43]  Y. Agrawal,et al.  Functionalization of XAD-4 resin for the separation of lanthanides using chelation ion exchange liquid chromatography , 2005 .

[44]  F. Cannon,et al.  Preloading hydrous ferric oxide into granular activated carbon for arsenic removal. , 2008, Environmental science & technology.

[45]  T. Tyson,et al.  Modeling Pb sorption to microporous amorphous oxides as discrete particles and coatings. , 2005, Journal of colloid and interface science.

[46]  A. Zouboulis,et al.  Removal of arsenic from contaminated water sources by sorption onto iron-oxide-coated polymeric materials. , 2002, Water research.

[47]  Ying Yu,et al.  Adsorption of Water-Soluble Dye onto Functionalized Resin , 2001 .

[48]  M. Benjamin,et al.  Use of iron oxide-coated sand to remove strontium from simulated Hanford tank wastes. , 2001, Environmental science & technology.

[49]  T. E. Browne,et al.  Sorption of organics from aqueous solution onto polymeric resins , 1993 .

[50]  Aimin Li,et al.  Adsorption of phenolic compounds from aqueous solutions by a water-compatible hypercrosslinked polymeric adsorbent. , 2002, Chemosphere.

[51]  P. Cornel,et al.  Sorption of dissolved organics from aqueous solution by polystyrene resins—I. Resin characterization and sorption equilibrium , 1986 .

[52]  Brown,et al.  Bile Salt Anion Sorption by Polymeric Resins: Comparison of a Functionalized Polyacrylamide Resin with Cholestyramine. , 2000, Journal of colloid and interface science.

[53]  F. Borrull,et al.  Influence of chemical modification of polymeric resin on retention of polar compounds in solid-phase extraction , 1999 .

[54]  B. Pan,et al.  Enhanced adsorption of p-nitroaniline from water by a carboxylated polymeric adsorbent , 2007 .

[55]  Xuejun Guo,et al.  Removal of arsenic by bead cellulose loaded with iron oxyhydroxide from groundwater. , 2005, Environmental science & technology.

[56]  C. Chiang,et al.  Removal of heavy metal ions by a chelating resin containing glycine as chelating groups , 2007 .

[57]  Aimin Li,et al.  Polanyi-based models for the adsorption of naphthalene from aqueous solutions onto nonpolar polymeric adsorbents. , 2008, Journal of colloid and interface science.

[58]  Aimin Li,et al.  Adsorption of aromatic acids on an aminated hypercrosslinked macroporous polymer , 2002 .

[59]  A. Zouboulis,et al.  Arsenic Removal Using Iron Oxide Loaded Alginate Beads , 2002 .

[60]  Arabinda Das,et al.  Determination of mercury species with a resin functionalized with a 1,2-bis(o-aminophenylthio)ethane moiety , 2003 .

[61]  T. Tyson,et al.  XAS studies of Ni and Zn sorbed to hydrous manganese oxide. , 2001, Environmental science & technology.

[62]  L. Lv,et al.  Highly effective removal of heavy metals by polymer-based zirconium phosphate: a case study of lead ion. , 2007, Journal of colloid and interface science.

[63]  Steven C. Smith,et al.  ADSORPTION AND DISSOCIATION OF CO-EDTA COMPLEXES IN IRON OXIDE-CONTAINING SUBSURFACE SANDS , 1995 .

[64]  A. Das,et al.  Synthesis, characterization, and application of a new chelating resin functionalized with dithiooxamide , 2007 .

[65]  Chuh-Yean Chen,et al.  Recovery of Cu(II) and Cd(II) by a chelating resin containing aspartate groups. , 2008, Journal of hazardous materials.

[66]  C. Ríos,et al.  Removal of heavy metals from acid mine drainage (AMD) using coal fly ash, natural clinker and synthetic zeolites. , 2008, Journal of hazardous materials.

[67]  R. Apak,et al.  The Use of Palmitoyl Hydroxyquinoline-Functionalized Amberlite XAD-2 Copolymer Resin for the Preconcentration and Speciation Analysis of Gallium(III) , 2000 .

[68]  D. Kinniburgh,et al.  Adsorption of alkaline earth transition and heavy metal cations by hydrous oxide gels of iron and aluminum , 1976 .

[69]  M. I. Bhanger,et al.  The efficacy of nitrosonaphthol functionalized XAD-16 resin for the preconcentration/sorption of Ni(II) and Cu(II) ions. , 2007, Talanta.

[70]  J. Zachara,et al.  Adsorption-Dissolution Reactions Affecting the Distribution and Stability of CoIIEDTA in Iron Oxide-Coated Sand. , 1994, Environmental science & technology.

[71]  V. Davankov,et al.  Macronet isoporous gels through crosslinking of dissolved polystyrene , 2007 .

[72]  M. Streat,et al.  Removal of Pesticides from Water Using Hypercrosslinked Polymer Phases: Part 2— Sorption Studies , 1998 .

[73]  D. Das,et al.  Synthesis and characterization of a new resin functionalized with 2-naphthol-3,6-disulfonic acid and its application for the speciation of chromium in natural water. , 2002, Talanta.

[74]  H. Raissi,et al.  Synthesis and application of a new chelating resin functionalized with 2,3-dihydroxy benzoic acid for Fe(III) determination in water samples by flame atomic absorption spectrometry , 2006 .

[75]  V. G. Pangarkar,et al.  Adsorptive recovery of water soluble essential oil components , 1994 .

[76]  S. Min,et al.  Hydrous ferric oxide incorporated diatomite for remediation of arsenic contaminated groundwater. , 2007, Environmental science & technology.

[77]  M. Saikia.  Revisiting adsorption of biomolecules on polymeric resins , 2008 .

[78]  Paul Westerhoff,et al.  A Hybrid Sorbent Utilizing Nanoparticles of Hydrous Iron Oxide for Arsenic Removal from Drinking Water , 2007 .

[79]  Qingrui Zhang,et al.  Adsorption of Pb2+, Zn2+, and Cd2+ from waters by amorphous titanium phosphate. , 2008, Journal of colloid and interface science.

[80]  P. Sylvester,et al.  Effect of silica and pH on arsenic uptake by resin/iron oxide hybrid media. , 2008, Water research.

[81]  S. Min,et al.  Removal of arsenite and arsenate using hydrous ferric oxide incorporated into naturally occurring porous diatomite. , 2006, Environmental science & technology.

[82]  R. Apak,et al.  Preconcentration of manganese(II) from natural and sea water on a palmitoyl quinolin-8-ol functionalized XAD copolymer resin and spectrophotometric determination with the formaldoxime reagent , 2003 .

[83]  C. Branger,et al.  Synthesis and characterization of a polystyrenic resin functionalized by catechol: Application to retention of metal ions , 2008 .

[84]  A. Rodrigues,et al.  Binary Adsorption of Phenol and m-Cresol Mixtures onto a Polymeric Adsorbent , 1999 .

[85]  F. Rigas,et al.  Removal of atrazine from water by use of nonionic polymeric resins , 1997 .

[86]  Qingrui Zhang,et al.  Efficient removal of aromatic sulfonates from wastewater by a recyclable polymer: 2-naphthalene sulfonate as a representative pollutant. , 2008, Environmental Science and Technology.

[87]  Aimin Li,et al.  Adsorption Mechanism of Aromatic Sulfonates onto Resins with Different Matrices , 2007 .

[88]  M. Elimelech,et al.  Enhanced aggregation of alginate-coated iron oxide (hematite) nanoparticles in the presence of calcium, strontium, and barium cations. , 2007, Langmuir : the ACS journal of surfaces and colloids.

[89]  G. Rao,et al.  Sorption behaviour of lanthanum(III), neodymium(III), terbium(III), thorium(IV) and uranium(VI) on Amberlite XAD-4 resin functionalized with bicine ligands. , 1999, Talanta.

[90]  A. Onjia,et al.  Metal sorption on macroporous poly(GMA-co-EGDMA) modified with ethylene diamine , 2004 .

[91]  T. Walsh,et al.  ARSENATE SORPTION BY HYDROUS FERRIC OXIDE INCORPORATED ONTO GRANULAR ACTIVATED CARBON WITH PHENOL FORMALDEHYDE RESINS COATING , 2008, Environmental technology.

[92]  D. Sparks,et al.  Sorption of Pentachlorophenol to HDTMA-Clay as a Function of Ionic Strength and pH. , 1994, Environmental Science and Technology.

[93]  H. Stephan,et al.  Removal of ethoxylated aliphatic amines from zinc containing effluents by adsorption on macroporous resins , 1994 .

[94]  B. Pan,et al.  Sorption enhancement of aromatic sulfonates onto an aminated hyper-cross-linked polymer. , 2005, Environmental science & technology.

[95]  Quan-xing Zhang,et al.  Applications of Porous Resin Sorbents in Industrial Wastewater Treatment and Resource Recovery , 2003 .

[96]  E. Diamadopoulos,et al.  Adsorption of polluting substances on activated carbons prepared from rice husk and sugarcane bagasse , 2008 .

[97]  B. Rivas,et al.  Sorption properties of poly(styrene-co-divinylbenzene) amine functionalized weak resin , 2001 .

[98]  V. Soldatov,et al.  A new hybrid (polymer/inorganic) fibrous sorbent for arsenic removal from drinking water , 2007 .

[99]  Krishna Gopal,et al.  Chlorination byproducts, their toxicodynamics and removal from drinking water. , 2007, Journal of hazardous materials.

[100]  Ching-Yuan Chang,et al.  Adsorptive removal of the pesticide methomyl using hypercrosslinked polymers. , 2008, Journal of hazardous materials.

[101]  O. Okay,et al.  Macroporous copolymer networks , 2000 .

[102]  A. Rodrigues,et al.  Comparative study of the adsorption of phenol and salicylic acid from aqueous solution onto nonionic polymeric resins , 2005 .

[103]  P. Chattopadhyay,et al.  A new chelating resin containing azophenolcarboxylate functionality: synthesis, characterization and application to chromium speciation in wastewater. , 2007, Analytica chimica acta.

[104]  M. Kawashima.  Phosphate adsorption onto hydrous manganese(IV) oxide in the presence of divalent cations , 1986 .

[105]  R. Summers,et al.  Sorption of dissolved organics from aqueous solution by polystyrene resins—II. External and internal mass transfer , 1986 .

[106]  Aimin Li,et al.  Adsorption of resorcinol and catechol from aqueous solution by aminated hypercrosslinked polymers , 2005 .

[107]  M. L. Pierce,et al.  Adsorption of arsenite and arsenate on amorphous iron hydroxide , 1982 .

[108]  Qingrui Zhang,et al.  Improved adsorption of 4-nitrophenol onto a novel hHyper-cross-linked polymer. , 2007, Environmental science & technology.

[109]  M. Streat,et al.  Physical and adsorptive properties of Hypersol-MacronetTM polymers , 1997 .

[110]  B. Pan,et al.  Equilibrium and heat of adsorption of diethyl phthalate on heterogeneous adsorbents. , 2008, Journal of colloid and interface science.

[111]  J. Lehto,et al.  Ion-exchange of nickel by iminodiacetic acid chelating resin Chelex 100 , 2000 .

[112]  A. Denizli,et al.  Methacryloylamidoglutamic Acid Incorporated Porous Poly(methyl methacrylate) Beads for Heavy-Metal Removal , 2004 .

[113]  R. Kunin.  Polymeric adsorbents for treatment of waste effluents , 1977 .

[114]  Tanju Karanfil,et al.  Trichloroethylene adsorption by fibrous and granular activated carbons: aqueous phase, gas phase, and water vapor adsorption studies. , 2004, Environmental science & technology.

[115]  S. Holmes,et al.  Novel and modified materials for wastewater treatment applications , 2008 .

[116]  A. Donia,et al.  Removal of some hazardous heavy metals from aqueous solution using magnetic chelating resin with iminodiacetate functionality , 2008 .

[117]  L. Lv,et al.  Preparation of polymer-supported hydrated ferric oxide based on Donnan membrane effect and its application for arsenic removal , 2008 .

[118]  L. Cumbal,et al.  Arsenic removal using polymer-supported hydrated iron(III) oxide nanoparticles: role of donnan membrane effect. , 2005, Environmental science & technology.

[119]  W. Arnold,et al.  Degradation of chloropicrin in the presence of zero‐valent iron , 2005, Environmental toxicology and chemistry.

[120]  R. Juang,et al.  Adsorption isotherms of phenols from water onto macroreticular resins. , 1999, Journal of hazardous materials.

[121]  R. Kunin.  The Use of Macroreticular Polymeric Adsorbents for the Treatment of Waste Effluents , 1976 .