Vapor Sensing Using Waveguide-Based Multiple Surface Plasmon Resonance Sensors

Multiple surface plasmon resonance (SPR) sensors were prepared on a waveguide, and vapor sensing was carried out. A BK-7 slide glass was used as a waveguide core, and three pairs of Ag films (50 nm)/polymer films with various thicknesses were prepared separately on the waveguide. White light was input from the substrate edge, and the spectrum of the output light was observed. Discrete SPR dips can be observed in the output light spectra by selecting the dielectric constant and the thickness of the polymer film, which govern the SPR condition. The sensors with poly(vinyl alcohol) as sensing material were prepared and the water vapor sorption properties were investigated. Furthermore, polyisoprene, poly(vinyl carbazole), poly(methyl methacrylate), and perfluorinated polymer were used as sensing materials, and the detection of various vapors was carried out.

[1]  A. Hillier,et al.  Surface plasmon resonance imaging of biomolecular interactions on a grating-based sensor array. , 2006, Analytical chemistry.

[2]  S. El-zaiat,et al.  Interferometric investigation of the effects, on the refractive index of PVA, of doping with lead acetate and gamma irradiation , 1997 .

[3]  I. Pockrand,et al.  Nonradiative decay of excited molecules near a metal surface , 1980 .

[4]  K. Shinbo,et al.  Enhancement of optical absorption and photocurrents in solar cells of merocyanine Langmuir–Blodgett films utilizing surface plasmon excitations , 2002 .

[5]  May-Britt Hägg,et al.  Swelling behavior and gas permeation performance of PVAm/PVA blend FSC membrane , 2010 .

[6]  Futao Kaneko,et al.  Alignment Properties of Liquid Crystal Molecules under AC and DC Voltage Application Studied by Surface Plasmon Resonance and Optical Waveguide Spectroscopy , 2010 .

[7]  R. Corn,et al.  Long-range surface plasmon resonance imaging for bioaffinity sensors. , 2005, Analytical chemistry.

[8]  W. Knoll,et al.  Interfaces and thin films as seen by bound electromagnetic waves. , 1998, Annual review of physical chemistry.

[9]  Futao Kaneko,et al.  Adsorption and Surface Plasmon Emission Light of Polystyrene Spheres with Fluorescent Dye on Ag Thin Film , 2008, IEICE Trans. Electron..

[10]  Dieter Mergel,et al.  Density and refractive index of TiO2 films prepared by reactive evaporation , 2000 .

[11]  Y. Kawakami,et al.  Modeling and test of fiber-optics fast SPR sensor for biological investigation , 2005 .

[12]  Futao Kaneko,et al.  Multimode Surface Plasmon Excitations on Organic Thin Film/Metallic Diffraction Grating , 2010 .

[13]  Masayuki Morisawa,et al.  Plastic optical fiber sensors for detecting leakage of alkane gases and gasoline vapors , 1998, Other Conferences.

[14]  T. Majima,et al.  Photocurrent generation of a porphyrin self-assembly monolayer on a gold film electrode by surface plasmon excitation using near-infrared light , 2000 .

[15]  R. J. Bell,et al.  Optical properties of the metals Al, Co, Cu, Au, Fe, Pb, Ni, Pd, Pt, Ag, Ti, and W in the infrared and far infrared. , 1983, Applied optics.

[16]  J. Homola Surface plasmon resonance based sensors , 2006 .

[17]  Futao Kaneko,et al.  Electrochemically controlled surface plasmon resonance immunosensor for the detection of human immunoglobulin G on poly(3-aminobenzoic acid) ultrathin films , 2010 .

[18]  Fabrication and fundamental characteristics of fiber optic surface plasmon sensor , 1997 .

[19]  Istvan Rajta,et al.  Refractive index depth profile in PMMA due to proton irradiation , 2007 .

[20]  S. Okubayashi,et al.  A kinetic study of moisture sorption and desorption on lyocell fibers , 2004 .

[21]  Wolfgang Knoll,et al.  Evanescent field in surface plasmon resonance and surface plasmon field-enhanced fluorescence spectroscopies. , 2004, Analytical chemistry.

[22]  M. Thommes,et al.  Effect of carbon paper substrate of the gas diffusion layer on the performance of proton exchange membrane fuel cell , 2010 .

[23]  Wolfgang Knoll,et al.  Immunosensor with self-referencing based on surface plasmon diffraction. , 2004, Analytical chemistry.

[24]  J. Homola,et al.  Surface plasmon resonance biosensor based on integrated optical waveguide , 2001 .

[25]  M. Sankarapandian,et al.  Novel carbazole phenoxy-based methacrylates to produce high-refractive index polymers , 2006 .

[26]  Tomohiko Matsushita,et al.  Development of new single-mode waveguide surface plasmon resonance sensor using a polymer imprint process for high-throughput fabrication and improved design flexibility , 2008 .

[27]  Satoshi Kawata,et al.  Enhancement of surface plasmon-mediated radiative energy transfer through a corrugated metal cathode in organic light-emitting devices , 2008 .

[28]  S. Kawata,et al.  Enhancement of electroluminescence through a two-dimensional corrugated metal film by grating-induced surface-plasmon cross coupling. , 2005, Optics letters.

[29]  Futao Kaneko,et al.  Surface Plasmon Emission Light Property due to Molecular Luminescence and Molecular Interaction , 2005 .

[30]  M. Knite,et al.  Polyisoprene-carbon nano-composites for application in multifunctional sensors , 2007 .

[31]  C. Hunter,et al.  Surface plasmon resonance properties and gas response in porphyrin Langmuir–Blodgett films , 2002 .

[32]  Joaquín Sevilla,et al.  Optical fiber relative-humidity sensor with polyvinyl alcohol film. , 2004, Applied optics.