Modeling and simulation of a MOSFET gas sensor with platinum gate for hydrogen gas detection

A mathematical model of the MOSFET gas sensor together with its operational specification towards the various hydrogen pressures are reported. The modeling is done for steady-state conditions. When the MOSFET sensor is exposed to hydrogen gas, chemical reactions are occurred and eventually come to equilibrium. In such circumstances, a linear relation between the shift in the threshold voltage and the different hydrogen pressures is observed which can be used to predict the response of the sensor to the different hydrogen pressures. An excellent agreement is found between the experimental data and the simulation results exhibiting the proof of the model.

[1]  Mats Eriksson,et al.  Kinetic modeling of hydrogen adsorption/absorption in thin films on hydrogen‐sensitive field‐effect devices: Observation of large hydrogen‐induced dipoles at the Pd‐SiO2 interface , 1995 .

[2]  Ingemar Lundström,et al.  Why bother about gas-sensitive field-effect devices? , 1996 .

[3]  P. Moseley,et al.  Solid state gas sensors , 1997 .

[4]  O. Sugino,et al.  DFT calculation of vibrational frequency of hydrogen atoms on Pt electrodes: Analysis of the electric field dependence of the Pt–H stretching frequency , 2007 .

[5]  Andreas Mandelis,et al.  Solid‐state sensors for trace hydrogen gas detection , 1990 .

[6]  Walter Gordy,et al.  A Relation between Bond Force Constants, Bond Orders, Bond Lengths, and the Electronegativities of the Bonded Atoms , 1946 .

[7]  B. J. Polk ChemFET arrays for chemical sensing microsystems , 2002, Proceedings of IEEE Sensors.

[8]  G. Collins,et al.  Hydrogen binding in vacancy clusters in platinum , 1993 .

[9]  Ricardo Gutierrez-Osuna,et al.  The how and why of electronic noses , 1998 .

[10]  A. Spetz,et al.  Hydrogen and ammonia response of metal‐silicon dioxide‐silicon structures with thin platinum gates , 1988 .

[11]  Andrew Wilkinson Compendium of Chemical Terminology , 1997 .

[12]  Y. Tsividis Operation and modeling of the MOS transistor , 1987 .

[13]  I. Lundstrom,et al.  Hydrogen sensitive MOS structures , 1975, 1975 International Electron Devices Meeting.

[14]  B. Lalevic,et al.  Transition metal-gate MOS gaseous detectors , 1982, IEEE Transactions on Electron Devices.

[15]  Ingemar Lundström,et al.  Hydrogen Sensing Mechanisms of Metal−Insulator Interfaces , 1998 .

[16]  E. Schaller,et al.  ‘Electronic Noses’ and Their Application to Food , 1998 .

[17]  H. S. Fogler,et al.  Elements of Chemical Reaction Engineering , 1986 .