API gravities, vanadium, nickel, sulfur, and their relation to gross composition: Implications for the origin and maturation of crude oils in Western Desert, Egypt

ABSTRACT In the present study, the geochemical analyses of API gravities, vanadium, nickel, sulfur, and bulk composition were performed on eight samples from productive wells in Gindi, South Deep Abu-gharadig, Abu-gharadig, Dahab-Merier, and Faghure basins locates in the North Western Desert. The results were used to describe the source organic matter input, depositional environment, assess the degree of thermal maturity, and to correlate between crude oils to determine the genetic relationship between hydrocarbon generation and their source rock for the studied oil samples. The results showed that a wide range of crude oil parameters exists in this data, indicating that a variety of oil types is represented. Crude oils range from unaltered to altered by vanadium, nickel, and sulfur concentrations, V/Ni and saturate fraction were used to classify the oils. Oils are classified into two groups. Group I contains oil samples from Gindi, South deep Abu-gharadig and Abu-gharadig, and Dahab-Merier that are generated from organic matter input deposited in marine environment under anoxic to suboxic conditions. Group II from Faghur basin possess high Pr/Ph ratios suggesting high contribution of terreginous organic matter deposited under relatively oxic conditions.

[1]  A. Barwise Role of nickel and vanadium in petroleum classification , 1990 .

[2]  Douglas W. Waples,et al.  Geochemistry in Petroleum Exploration , 1985, Geological Sciences Series.

[3]  M. E. El Nady,et al.  Crude Oil Geochemistry and Its Relation to the Potential Source Beds for Some Meleiha Oil Fields in the North Western Desert, Egypt , 2003 .

[4]  D. Martín,et al.  Thermal characteristics of crude oils treated with rheology modifiers , 1997 .

[5]  R. Philp Petroleum Formation and Occurrence , 1985 .

[6]  M. Lewan Factors controlling the proportionality of vanadium to nickel in crude oils , 1984 .

[7]  Y. Duan,et al.  Lipid geochemistry in a sediment core from Ruoergai Marsh deposit (Eastern-Qinghai-Tibet plateau, China) , 2001 .

[8]  M. E. El Nady,et al.  Oil–Source Rocks Correlation Based on the Biomarker Distribution of EWD and Qarun Oilfields, North Western Desert, Egypt , 2012 .

[9]  F. Harb,et al.  Source Rock Quality from Oil Biomarkers of the Abu Gharadig Basin in the North Western Desert, Egypt , 2015 .

[10]  J. Connan,et al.  Properties of gases and petroleum liquids derived from terrestrial kerogen at various maturation levels , 1980 .

[11]  B. Simoneit,et al.  Organic geochemical indicators of palaeoenvironmental conditions of sedimentation , 1978 .

[12]  M. E. El Nady,et al.  Petroleum geochemistry of crude oils and oil: source rock correlation of some wells in the North Western Desert, Egypt , 2016, Arabian Journal of Geosciences.

[13]  M. E. El Nady,et al.  Significance of Aromatic Hydrocarbons in Recognizing Source Depositional Environments and Maturation of Some Egyptian Crude Oils , 2009 .

[14]  W. E. Diasty,et al.  Application of biological markers in the recognition of the geochemical characteristics of some crude oils from Abu Gharadig Basin, north Western Desert – Egypt , 2012 .