Relationships among tracer ages

[1] Measurements of chemical tracers whose spatial gradients are primarily due to the time dependence of sources and/or sinks are often used to define “tracer ages” in an effort to diagnose transport. However, a major problem with interpreting these tracer ages is that different tracers can yield different ages, and at present, it is not clear what aspects of the transport are measured by the different tracers. We use the concept of a distribution of transit times to compare the timescales derived from different tracers, including CFCs, tritium-helium, and radioactive tracers. By performing a systematic study over a range of transit time distributions we examine under what conditions two tracers yield similar or different ages. It is shown that there can be significant differences in tracer ages and that in general, tracer ages are not fundamental timescales of the flow. Furthermore, even if ages from two tracers are similar these ages can be very different from the mean (ideal) age or the age of a third tracer. It is also shown that significant temporal variations in tracer ages can occur for steady transport and that these changes are of similar magnitude to the changes in CFC and tritium-helium ages observed in the North Atlantic and North Pacific over the 1980s and 1990s. Accounting for the changes in tracer ages caused by steady transport is necessary before attributing changes in tracer ages to changes in transport. The possibility of using the differences in ages from different tracers to infer information about the transit time distribution is also examined. It is shown that two tracer ages can constrain the first two moments (mean age and width) of the distribution, but how tightly these are constrained depends on the tracers used, the certainty of the age calculations, and the flow characteristics.

[1]  Wolfgang Roether,et al.  Temporal evolution of CFC 11 and CFC 12 concentrations in the ocean interior , 1996 .

[2]  Y. Watanabe,et al.  Probability of a reduction in the formation rate of the subsurface water in the North Pacific during the 1980s and 1990s , 2001 .

[3]  W. J. Jenkins,et al.  The distribution of 3He in the western Atlantic ocean , 1976 .

[4]  J. Lupton,et al.  Transformation and age of water masses , 2001 .

[5]  Timothy M. Hall,et al.  Age as a diagnostic of stratospheric transport , 1994 .

[6]  B. Klein,et al.  Property distributions and transient-tracer ages in Levantine Intermediate Water in the Eastern Mediterranean , 1998 .

[7]  L. N. Plummer,et al.  Environmental tracers for age dating young ground water , 1993 .

[8]  W. Roether,et al.  Validity limits of carbon tetrachloride as an ocean tracer , 2001 .

[9]  N. Gruber Anthropogenic CO2 in the Atlantic Ocean , 1998 .

[10]  R. Weiss,et al.  Basin-wide distributions of chlorofluorocarbons CFC-11 and CFC-12 in the North Pacific: 1985–1989 , 1996 .

[11]  K. Johnson,et al.  Anthropogenic CO2 inventory of the Indian Ocean , 1999 .

[12]  D. Wallace,et al.  Carbon tetrachloride and chlorofluorocarbons in the South Atlantic Ocean, 19°S , 1994 .

[13]  A. Basu,et al.  The Inverse Gaussian Distribution , 1993 .

[14]  William J. Jenkins,et al.  A comparison of ocean tracer dating techniques on a meridional section in the eastern North Atlantic , 1997 .

[15]  Constant ventilation age of thermocline water in the eastern subtropical North Pacific Ocean from chlorofluorocarbon measurements over a 12‐year period , 2000 .

[16]  W. B. Mann,et al.  Preparation and calibration of the 1978 National Bureau of Standards tritiated-water standards , 1980 .

[17]  L. N. Plummer,et al.  Dating of shallow groundwater: Comparison of the transient tracers 3H/3He, chlorofluorocarbons, and 85Kr , 1994 .

[18]  B. Klein,et al.  Apparent loss of CFC‐113 in the upper ocean , 2001 .

[19]  P. Cook,et al.  Recent advances in dating young groundwater: chlorofluorocarbons, and 85Kr , 1997 .

[20]  E. Carmack,et al.  Deep-water renewal and biological production in Lake Baikal , 1991, Nature.

[21]  W. Smethie,et al.  Investigation of subsurface water flow along the continental margin of the Eurasian Basin using the transient tracers tritium, 3He, and CFCs , 1998 .

[22]  J. Leslie The Inverse Gaussian Distribution: Theory, Methodology, and Applications , 1990 .

[23]  L. Paul Steele,et al.  Sulfur hexafluoride—A powerful new atmospheric tracer , 1996 .

[24]  R. Sonnerup On the relations among CFC derived water mass ages , 2001 .

[25]  R. Weiss,et al.  Deep‐water renewal in Lake Issyk‐Kul , 2002 .

[26]  A. Watson,et al.  On the use of carbon tetrachloride as a transient tracer of Weddell Sea deep and bottom waters , 1996 .

[27]  Thomas W. N. Haine,et al.  A Generalized Transport Theory: Water-Mass Composition and Age , 2002 .

[28]  W. Jenkins,et al.  Observations of temporal changes of tritium- 3 He age in the eastern North Atlantic thermocline: Evidence for changes in ventilation? , 1998 .

[29]  Eric Deleersnijder,et al.  Toward a general theory of the age in ocean modelling , 1999 .

[30]  Wolfgang Roether,et al.  Repeated CFC sections at the Greenwich Meridian in the Weddell Sea , 2002 .

[31]  Peter G. Cook,et al.  Determining Timescales for Groundwater Flow and Solute Transport , 2000 .

[32]  Samar Khatiwala,et al.  Age Tracers in an Ocean GCM , 2001 .

[33]  R. Fine Tracers, time scales, and the thermohaline circulation: The lower limb in the North Atlantic Ocean , 1995 .

[34]  D. Waugh,et al.  AGE OF STRATOSPHERIC AIR: THEORY, OBSERVATIONS, AND MODELS , 2002 .

[35]  Dylan B. A. Jones,et al.  Empirical age spectra for the midlatitude lower stratosphere from in situ observations of CO2: Quantitative evidence for a subtropical “barrier” to horizontal transport , 2001 .

[36]  W. Broecker,et al.  Comparison of 39Ar and 14C ages for waters in the deep ocean , 2000 .

[37]  W. Roether,et al.  Tritium and90Sr in North Atlantic surface water , 1978 .

[38]  Jesús Carrera,et al.  Simulation of groundwater age distributions , 1998 .

[39]  R. Weiss,et al.  Reconstructed histories of the annual mean atmospheric mole fractions for the halocarbons CFC‐11 CFC‐12, CFC‐113, and carbon tetrachloride , 2000 .

[40]  S. Doney,et al.  Climatic variability in upper ocean ventilation rates diagnosed using chlorofluorocarbons , 1998 .

[41]  C. Wunsch Oceanic age and transient tracers: Analytical and numerical solutions , 2002 .

[42]  Timothy M. Hall,et al.  Transit-Time and Tracer-Age Distributions in Geophysical Flows , 2000 .

[43]  Eric Deleersnijder,et al.  The concept of age in marine modelling I. Theory and preliminary model results , 2001 .

[44]  J. Leroy Folks Inverse Gaussian Distribution , 2004 .

[45]  R. Weiss,et al.  Simultaneous determination of sulfur hexafluoride and three chlorofluorocarbons in water and air , 2002 .

[46]  T. Haine,et al.  Inferring the concentration of anthropogenic carbon in the ocean from tracers , 2002 .

[47]  Jorge L. Sarmiento,et al.  Tracer dating and ocean ventilation , 1990 .