Design of metal oxide nanoparticles: Control of size, shape, crystalline structure and functionalization by aqueous chemistry

Abstract The aim of this paper is to show that a very simple but well controlled chemistry in an aqueous medium allows one to efficiently control the main characteristics of oxide nanoparticles. Examples concerning titania, alumina, iron and manganese oxides are discussed to illustrate various effects on the control of size, shape and structure of nanoparticles. Some examples of functionalization of these particles are also illustrated. Experimental data, procedures and detailed references can be found in the cited literature.

[1]  E. Tronc,et al.  Size tailoring of TiO2 anatase nanoparticles in aqueous medium and synthesis of nanocomposites. Characterization by Raman spectroscopy , 2003 .

[2]  D. Portehault,et al.  Synthesis of a manganese oxide nanocomposite through heteroepitaxy in aqueous medium. , 2009, Chemical communications.

[3]  Renaud Revel,et al.  Accurate Determination of Oxide Nanoparticle Size and Shape Based on X-Ray Powder Pattern Simulation : Application to Boehmite AlOOH , 2008 .

[4]  Didier Gourier,et al.  Nanoprobes with near-infrared persistent luminescence for in vivo imaging , 2007, Proceedings of the National Academy of Sciences.

[5]  D. Portehault,et al.  Structural and morphological control of manganese oxide nanoparticles upon soft aqueous precipitation through MnO4−/Mn2+ reaction , 2009 .

[6]  Jean-Pierre Jolivet,et al.  Synthesis of brookite TiO2 nanoparticlesby thermolysis of TiCl4 in strongly acidic aqueous media , 2001 .

[7]  E. Bourhis,et al.  Structure and Mechanical Properties of Mesostructured Functional Hybrid Coatings Based on Anisotropic Nanoparticles Dispersed in Poly(hydroxylethyl methacrylate) , 2008, Chemistry of Materials.

[8]  J. Overbeek.  The First Rideal Lecture. Microemulsions, a field at the border between lyophobic and lyophilic colloids , 1978 .

[9]  É. Duguet,et al.  Magnetic nanoparticle design for medical diagnosis and therapy , 2004 .

[10]  J. Jolivet,et al.  From TiCl3 to TiO2 nanoparticles (anatase, brookite and rutile): Thermohydrolysis and oxidation in aqueous medium , 2007 .

[11]  D. Portehault,et al.  A core-corona hierarchical manganese oxide and its formation by an aqueous soft chemistry mechanism. , 2008, Angewandte Chemie.

[12]  J. Dormann,et al.  Magnetic Relaxation in Fine‐Particle Systems , 2007 .

[13]  Fabrication and photoluminescence characteristics of Er3+-doped optical fiber sensitized by Si particles , 2007 .

[14]  J. Jolivet,et al.  Selective synthesis of brookite, anatase and rutile nanoparticles: thermolysis of TiCl4 in aqueous nitric acid , 2007 .

[15]  J. Tarascon,et al.  Structural evolution during the reaction of Li with nano-sized rutile type TiO2 at room temperature , 2007 .

[16]  R. Revel,et al.  Size and shape control of γ-AlOOH boehmite nanoparticles, a precursor of γ-Al2O3 catalyst , 2006 .

[17]  M. Antonietti,et al.  Mesocrystals and nonclassical crystallization , 2008 .

[18]  Jean-Pierre Jolivet,et al.  Size tailoring of oxide nanoparticles by precipitation in aqueous medium. A semi-quantitative modelling , 2004 .

[19]  A. Dessombz,et al.  Design of liquid-crystalline aqueous suspensions of rutile nanorods: evidence of anisotropic photocatalytic properties. , 2007, Journal of the American Chemical Society.

[20]  E. Tronc,et al.  Iron oxide chemistry. From molecular clusters to extended solid networks. , 2004, Chemical communications.

[21]  D. Portehault,et al.  Twinning Driven Growth of Manganese Oxide Hollow Cones through Self-Assembly of Nanorods in Water , 2009 .

[22]  D. Portehault,et al.  Design of Hierarchical Core−Corona Architectures of Layered Manganese Oxides by Aqueous Precipitation , 2008 .