Elaboration, structural study and validation of a new NASICON-type structure, Na0.72(Cr0.48,Al1.52)(Mo2.77,Al0.23)O12

A new NASICON-type phase, Na0.72(Cr0.48,Al1.52)(Mo2.77,Al0.23)O12, was synthesized by solid-state reaction. The structural unit consists of one octahedron M1O6 (M1 = Cr1/Al2) and one tetrahedron M2O4 (M2 = Mo1/Al1) sharing corners. The charge compensation is provided by Na+ cations.

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