The rotating cylinder electrode: its continued development and application

The application of rotating cylinder electrodes (RCEs) in electrochemistry has been reviewed for the period 1982–1995. Among the applications highlighted are the novel design of cell geometries and reactors for a range of electrochemical processes, voltammetry and analysis, electrodeposition and corrosion. This range amply indicates the widespread acceptance of the RCE for studies in a number of interdisciplinary fields.

[1]  Charles W. Tobias,et al.  Roughness Development in Metal Electrodeposition I . Experimental Results , 1989 .

[2]  A. Kuhn,et al.  The electrodeposition of copper-silver and copper-nickel alloy powders from aqueous ammoniacal solutions , 1984 .

[3]  V. Sobolík,et al.  Study of Taylor-Couette flow using a three-segment electrodiffusion probe , 1995 .

[4]  M. Matlosz,et al.  Experimental investigation of the primary and secondary current distribution in a rotating cylinder Hull cell , 1992 .

[5]  A. Kuhn,et al.  Electrodeposition of Silver Alloy Powders on Rotating and Vibrating Cathodes , 1983 .

[6]  K. Striebel,et al.  KINETIC STUDIES USING A ROTATING CYLINDER ELECTRODE. I. ELECTRON TRANSFER RATES IN FERROUS/FERRIC SULFATE ON PLATINUM , 1986 .

[7]  C. Bamford,et al.  Comprehensive Chemical Kinetics , 1976 .

[8]  K. D. Efird,et al.  Correlation of steel corrosion in pipe flow with jet impingement and rotating cylinder tests , 1993 .

[9]  D. Gabe,et al.  High Speed Electrodeposition of Copper from Conventional Sulphate Electrolytes , 1970 .

[10]  J. M. Sánchez,et al.  Anode-support system for the direct electrorefining of cement copper Part I: Process conditions using horizontal rotary cathodes , 1995 .

[11]  The Rotating Cylinder Hull Cell: Design and Application , 1993 .

[12]  Hanswalter Giesekus,et al.  Progress and Trends in Rheology II , 1982 .

[13]  K. Sridharan,et al.  ELECTRODEPOSITION OF AMORPHOUS IRON-NICKEL-PHOSPHORUS ALLOY COATINGS , 1994 .

[14]  ChengPo-Chung,et al.  Prediction of Product-Selectivity in an Electroorganic Process by Mathematical Modeling of Reaction Mechanism. A Rotating Cylinder Electrode System , 1991 .

[15]  D. Gabe,et al.  Enhanced mass transfer using roughened rotating cylinder electrodes in turbulent flow , 1987 .

[16]  Harry L. Swinney,et al.  Flow regimes in a circular Couette system with independently rotating cylinders , 1986, Journal of Fluid Mechanics.

[17]  A. Wragg.  Use of electrochemical techniques to study natural convection heat and mass transfer , 1991 .

[18]  K. Denpo,et al.  Fluid Flow Effects on CO2 Corrosion Resistance of Oil Well Materials , 1993 .

[19]  P. Kathirgamanathan,et al.  Direct electrodeposition of poly(pyrrole) on continuous carbon-loaded microporous membrane films , 1994 .

[20]  D. Gabe.  Rotating electrodes for use in electrodeposition process control (the 36th William Blum lecture) , 1995 .

[21]  P. Sides,et al.  On the use of rotating electrodes in the measurement of the diffusion coefficient of aluminum fluoride in cryolitic melts , 1989 .

[22]  K. Cathro.  Mass Transport during Zinc Electrowinning at High Current Density , 1992 .

[23]  B. E. Brown,et al.  Effect of Flow Rates on Localized Corrosion Behavior of 304 Stainless Steel in Ozonated 0.5 N NaCl , 1992 .

[24]  E. Podlaha,et al.  Electrodeposition of High Mo Content Ni‐Mo Alloys under Forced Convection , 1993 .

[25]  R. Naybour.  Morphologies of zinc electrodeposited from zinc-saturated aqueous alkaline solution , 1968 .

[26]  D. R. Gabe,et al.  ROTATING ELECTRODE CURRENT DENSITY CELLS TO SIMULATE HIGH SPEED ELECTRODEPOSITION , 1991 .

[27]  M. Orazem,et al.  The Impinging Jet Electrode: Measurement of the Hydrodynamic Constant and Its Use for Evaluating Film Persistency , 1990 .

[28]  Youssef Mikhail,et al.  Rotating Cylinder Electrode Study of the Electrodeposition of New Corrosion‐Resistant Nickel‐Zinc‐Phosphorus Alloys , 1989 .

[29]  Derek Pletcher,et al.  A First Course in Electrode Processes , 1991 .

[30]  D. Schiffrin,et al.  The use of high speed rotating disc electrodes for the study of erosion-corrosion of copper base alloys in sea water , 1988 .

[31]  R. Czernuszewicz,et al.  Novel cylindrical rotating electrode for anaerobic surface ― enhanced Raman spectroscopy , 1988 .

[32]  J. Bisang,et al.  Study of the effect of electrode resistance on current density distribution in cylindrical electrochemical reactors , 1988 .

[33]  D. Macdonald,et al.  Development of Controlled Hydrodynamic Techniques for Corrosion Testing , 1992 .

[34]  D. Gabe,et al.  The production of compositionally modulated alloys by simulated high speed electrodeposition from a single solution , 1995 .

[35]  S. R. Taylor,et al.  Sodium Molybdate as a Corrosion Inhibitor of Mild Steel in Natural Waters Part 1: Flow Rate Effects , 1993 .

[36]  S. Nešić,et al.  Comparison of the Rotating Cylinder and Pipe Flow Tests for Flow-Sensitive Carbon Dioxide Corrosion , 1995 .

[37]  E. Gileadi,et al.  Rotating cylindrical strip microelectrodes , 1988 .

[38]  Y. Takeda,et al.  Decomposition of the Modulated Waves in a Rotating Couette System , 1994, Science.

[39]  J. Farmer.  Electrochemical Treatment of Mixed and Hazardous Wastes , 1994 .

[40]  H. Farag,et al.  The role of mass transfer in the electrolytic reduction of hexavalent chromium at gas evolving rotating cylinder electrodes , 1992 .

[41]  A. Eklund,et al.  Enhanced mass transfer to a rotating cylinder electrode with axial flow , 1988 .

[42]  D. C. Silverman.  Rotating Cylinder Electrode for Velocity Sensitivity Testing , 1984 .

[43]  M. Eisenberg,et al.  Ionic Mass Transfer and Concentration Polarization at Rotating Electrodes , 1953 .

[44]  G. Thompson,et al.  A rotating disc electrode with heat transfer facilities for corrosion studies , 1987 .

[45]  F. Walsh,et al.  Mass transport to reticulated vitreous carbon rotating cylinder electrodes , 1995 .

[46]  R. Winand.  Electrodeposition of metals and alloys-new results and perspectives , 1994 .

[47]  GMaskill Smith,et al.  The chemical engineer , 1946 .

[48]  B. Poulson.  Electrochemical measurements in flowing solutions , 1983 .

[49]  F. Walsh,et al.  Development of the Eco-Cascade- cell reactor , 1982 .

[50]  Harry L. Swinney,et al.  Hydrodynamic instabilities and the transition to turbulence , 1981 .

[51]  R. Mark Wightman,et al.  Electroanalytical properties of band electrodes of submicrometer width , 1985 .

[52]  J. Robert Selman,et al.  Mass-Transfer Measurements by the Limiting-Current Technique , 1978 .

[53]  G. Johansson.  Analysis of column effluents by controlled-potential coulometry , 1965 .

[54]  A. Pearlstein,et al.  Plating of copper in tubular holes with rotating screw electrodes , 1992 .

[55]  L. E. Vaaler.  Electrolytic Purification of Nickel Plating Solutions , 1978 .

[56]  D. Gabe,et al.  The Hull Cell , 1993 .

[57]  G. Sedahmed,et al.  Diffusion controlled corrosion of pipelines under turbulent flow conditions , 1990 .

[58]  F. Walsh.  The performance of a 500 amp rotating cylinder electrode reactor. Part 3: Methods for the determination of mass transport data and the choice of reactor model , 1993 .

[59]  A. West,et al.  Design Considerations for a cylindrical hull cell with forced convection , 1992 .

[60]  J. St-Pierre,et al.  Dissolved oxygen concentration in an undivided rotating cylinder electrode reactor , 1994 .

[61]  A. Bond,et al.  Voltammetry at linear gold and platinum microelectrode arrays produced by lithographic techniques , 1985 .

[62]  F. Walsh,et al.  Enhanced mass transfer at the rotating cylinder electrode. I. Characterization of a smooth cylinder and roughness development in solutions of constant concentration , 1984 .

[63]  F. Walsh,et al.  Formation of Finely Divided Silver-Tin Powders by Electrodeposition , 1981 .

[64]  F. Walsh,et al.  Effect of thiourea, benzotriazole and 4,5-dithiaoctane-1,8-disulphonic acid on the kinetics of copper deposition from dilute acid sulphate solutions , 1995 .

[65]  F. Mansfeld,et al.  Corrosion Inhibition in Neutral, Aerated Media , 1985 .

[66]  J. St-Pierre,et al.  Copper removal from aerated solution containing various metal ions using an undivided rotating cylinder electrode reactor , 1995 .

[67]  F. Walsh,et al.  Controlled-potential electrodeposition of metals at a rotating cylinder electrode (the Eco-Cell) , 1981 .

[68]  V. Noninski.  Corrosion studies with the self-cleaning rotating electrode (SRE) , 1990 .

[69]  F. Walsh,et al.  The performance of a 500 Amp rotating cylinder electrode reactor. Part 2: Batch recirculation studies and overall mass transport , 1991 .

[70]  Ralph N. Adams,et al.  Electrochemistry at Solid Electrodes , 1969 .

[71]  Julian L. Roberts,et al.  Electrochemistry for Chemists , 1995 .