Three-year ground based measurements of aerosol optical depth over the Eastern Mediterranean: the urban environment of Athens

Abstract. Three years (2006–2008) of ground-based observations of the Aerosol Optical Depth (AOD) in the urban environment of Athens, in the Eastern Mediterranean, are analysed in this work. Measurements were acquired with a Multi-Filter Rotating Shadowband Radiometer at five wavelengths. The daily average AOD at 500 nm is 0.23, and the mean Angstrom coefficient calculated between 415 and 867 nm is 1.41. The annual variability of AOD has a spring maximum dominated by coarse dust particles from the Sahara (AOD 0.34–0.42), while the diurnal pattern is typical for urban sites, with AOD steadily increasing throughout the day. The greatest contribution to the annually averaged AOD, accounting for almost 40%, comes from regional and local sources (namely the Istanbul metropolitan area, the extended areas of biomass burning around the north coast of the Black Sea, power plants spread throughout the Balkans and the industrial area in the Po valley, with average daily AOD in the range of 0.25–0.35). An additional important contribution (23%) is dust from Africa, whereas the rest of Europe contributes another 22%. The geographical distribution of the above sources in conjunction with the prevailing synoptic situation and contribution of local sources, lead to mixed types of aerosols over Athens, with highly variable contribution of fine and coarse particles to AOD in the range 10%–90%. This is the first long-term, ground based data set available for Athens, and it has also been used for the validation of satellite derived AOD by MODIS, showing good agreement on an annual basis, but with an overestimation of satellite AODs in the warm period.

[1]  Menas Kafatos,et al.  Dust storm and black cloud influence on aerosol optical properties over Cairo and the Greater Delta region, Egypt , 2008 .

[2]  Arnon Karnieli,et al.  Light scattering by dust and anthropogenic aerosol at a remote site in the Negev desert, Israel , 2002 .

[3]  J. Michalsky,et al.  Objective algorithms for the retrieval of optical depths from ground-based measurements. , 1994, Applied optics.

[4]  R. Hillamo,et al.  Size-segregated mass distributions of aerosols over Eastern Mediterranean: seasonal variability and comparison with AERONET columnar size-distributions , 2007 .

[5]  J. Baldasano,et al.  Aerosol characterization in Northern Africa, Northeastern Atlantic, Mediterranean Basin and Middle East from direct-sun AERONET observations , 2009 .

[6]  T. Cokacar,et al.  Optical properties of mineral dust outbreaks over the northeastern Mediterranean , 2003 .

[7]  D. Hatzidimitriou,et al.  Aerosol physical and optical properties in the Eastern Mediterranean Basin, Crete, from Aerosol Robotic Network data , 2006 .

[8]  Trevor D. Davies,et al.  Cluster analysis: A technique for estimating the synoptic meteorological controls on air and precipitation chemistry—Method and applications , 1992 .

[9]  J. Burrows,et al.  Megacities as hot spots of air pollution in the East Mediterranean , 2011 .

[10]  Olivier Favez,et al.  Long-term measurements of carbonaceous aerosols in the Eastern Mediterranean: evidence of long-range transport of biomass burning , 2008 .

[11]  Christos Zerefos,et al.  On the origin of SO2 above northern Greece , 2000 .

[12]  Sara Basart,et al.  The Potential of the Synergistic Use of Passive and Active Remote Sensing Measurements for the Validation of a Regional Dust Model , 2009 .

[13]  T. Eck,et al.  Classification of aerosol properties derived from AERONET direct sun data , 2006 .

[14]  H. Kambezidis,et al.  Diurnal variation of the aerosol optical depth for two distinct cases in the Athens area, Greece , 2005 .

[15]  Timo Mäkelä,et al.  Chemical composition and sources of fine and coarse aerosol particles in the Eastern Mediterranean , 2008 .

[16]  Christos Zerefos,et al.  Measurements of Saharan dust aerosols over the Eastern Mediterranean using elastic backscatter-Raman lidar, spectrophotometric and satellite observations in the frame of the EARLINET project , 2005 .

[17]  Michael Cusack,et al.  Variability in regional background aerosols within the Mediterranean , 2009 .

[18]  C. Zerefos,et al.  Raman lidar and sunphotometric measurements of aerosol optical properties over Thessaloniki, Greece during a biomass burning episode , 2003 .

[19]  Mihalis Vrekoussis,et al.  Dust transport over the eastern Mediterranean derived from Total Ozone Mapping Spectrometer, Aerosol Robotic Network, and surface measurements , 2007 .

[20]  A. Bais,et al.  Study of the effect of different type of aerosols on UV-B radiation from measurements during EARLINET , 2003 .

[21]  O. Torres,et al.  Natural versus anthropogenic aerosols in the eastern Mediterranean basin derived from multiyear TOMS and MODIS satellite data , 2009 .

[22]  Ana Maria Silva,et al.  Aerosol extinction in a remote continental region of the Iberian Peninsula during summer , 2006 .

[23]  Vincent R. Gray Climate Change 2007: The Physical Science Basis Summary for Policymakers , 2007 .

[24]  C. Zerefos,et al.  Optical properties of different aerosol types: seven years of combined Raman-elastic backscatter lidar measurements in Thessaloniki, Greece , 2009 .

[25]  Christos Zerefos,et al.  Aerosol optical properties and large‐scale transport of air masses: Observations at a coastal and a semiarid site in the eastern Mediterranean during summer 1998 , 2001 .

[26]  Menas Kafatos,et al.  Transport of dust and anthropogenic aerosols across Alexandria, Egypt , 2009 .

[27]  J. Lelieveld,et al.  Global Air Pollution Crossroads over the Mediterranean , 2002, Science.

[28]  Anders Ångström,et al.  On the Atmospheric Transmission of Sun Radiation. II , 1930 .

[29]  A. Adamopoulos,et al.  ATMOSPHERIC PM10 PARTICLE CONCENTRATION MEASUREMENTS AT CENTRAL AND PERIPHERAL URBAN SITES IN ATHENS AND THESSALONIKI, GREECE , 2010 .

[30]  Richard Washington,et al.  Atmospheric controls on the annual cycle of North African dust , 2007 .

[31]  D. G. Kaskaoutisa,et al.  Aerosol climatology and discrimination of different types over Athens , Greece , based on MODIS data , 2007 .

[32]  Dimitris G. Kaskaoutis,et al.  Seasonal variation of columnar aerosol optical properties over Athens, Greece, based on MODIS data , 2008 .

[33]  Anders Ångström,et al.  On the Atmospheric Transmission of Sun Radiation and on Dust in the Air , 1929 .

[34]  R. Draxler An Overview of the HYSPLIT_4 Modelling System for Trajectories, Dispersion, and Deposition , 1998 .

[35]  J. Michalsky,et al.  Automated multifilter rotating shadow-band radiometer: an instrument for optical depth and radiation measurements. , 1994, Applied optics.

[36]  P. Formenti,et al.  Climatological aspects of aerosol optical properties in Northern Greece , 2003 .

[37]  O. Edenhofer,et al.  Mitigation from a cross-sectoral perspective , 2007 .

[38]  A. Bais,et al.  Nine years of UV aerosol optical depth measurements at Thessaloniki, Greece , 2007 .

[39]  Yoram J. Kaufman,et al.  Earth Observing System AM1 mission to Earth , 1998, IEEE Trans. Geosci. Remote. Sens..

[40]  A. Karnieli,et al.  Temporal trend in anthropogenic sulfur aerosol transport from central and eastern Europe to Israel , 2009 .

[41]  C. Zerefos,et al.  Dust specific extinction cross-sections over the Eastern Mediterranean using the BSC-DREAM model and sun photometer data: the case of urban environments , 2009 .

[42]  Menas Kafatos,et al.  Implications of high altitude desert dust transport from Western Sahara to Nile Delta during biomass burning season. , 2010, Environmental pollution.

[43]  Christos Zerefos,et al.  Four‐year aerosol observations with a Raman lidar at Thessaloniki, Greece, in the framework of European Aerosol Research Lidar Network (EARLINET) , 2005 .

[44]  I. Ziomas The mediterranean campaign of photochemical tracers—transport and chemical evolution (MEDCAPHOT-TRACE): an outline , 1998 .

[45]  M. M. Abdel Wahab,et al.  Seasonal and inter-annual variability of the aerosol content in Cairo (Egypt) as deduced from the comparison of MODIS aerosol retrievals with direct AERONET measurements , 2010 .

[46]  B. Holben,et al.  Validation of MODIS aerosol optical depth retrieval over land , 2002 .

[47]  N. Kubilay,et al.  Airborne desert dust and aeromicrobiology over the Turkish Mediterranean coastline , 2007 .

[48]  C. P. Jacovides,et al.  Spectral aerosol optical depth and Angstrom parameters in the polluted Athens atmosphere , 2005 .

[49]  Christos Zerefos,et al.  Three-year ground based measurements of aerosol optical depth over the Eastern Mediterranean: the urban environment of Athens , 2010 .

[50]  Tarek A. El-Ghazawi,et al.  A multisensor approach to dust storm monitoring over the Nile Delta , 2003, IEEE Trans. Geosci. Remote. Sens..

[51]  Jonathan Williams,et al.  C2–C8 NMHCs over the Eastern Mediterranean: Seasonal variation and impact on regional oxidation chemistry , 2009 .

[52]  J. Burrows,et al.  Pollution events over the East Mediterranean : Synergistic use of GOME, ground-based and sonde observations and models , 2007 .

[53]  E. Vermote,et al.  The MODIS Aerosol Algorithm, Products, and Validation , 2005 .

[54]  Robert E. Wolfe,et al.  Key characteristics of MODIS data products , 1998, IEEE Trans. Geosci. Remote. Sens..

[55]  J. Joseph,et al.  Desert aerosol transport in the Mediterranean region as inferred from the TOMS aerosol index , 2002 .

[56]  Alexander Smirnov,et al.  Diurnal variability of aerosol optical depth observed at AERONET (Aerosol Robotic Network) sites , 2002 .

[57]  Mihalis Vrekoussis,et al.  Origin and variability of particulate matter (PM10) mass concentrations over the Eastern Mediterranean , 2006 .

[58]  Richard Washington,et al.  Dust and the low‐level circulation over the Bodélé Depression, Chad: Observations from BoDEx 2005 , 2006 .

[59]  M. Blumthaler,et al.  Chemical, physical, and optical characterization of aerosols during PAUR II experiment , 2002 .

[60]  D. Melas,et al.  The Impact of Sea Breeze on Air Quality in Athens Area , 2005 .

[61]  Charles Ichoku,et al.  Signs of a negative trend in the MODIS aerosol optical depth over the Southern Balkans , 2010 .

[62]  Alexandros Papayannis,et al.  Vertical aerosol distribution over Europe: Statistical analysis of Raman lidar data from 10 European Aerosol Research Lidar Network (EARLINET) stations , 2004 .

[63]  W. Maenhaut,et al.  Aerosol mass closure and reconstruction of the light scattering coefficient over the Eastern Mediterranean Sea during the MINOS campaign , 2005 .

[64]  Christos Housiadas,et al.  Saharan dust levels in Greece and received inhalation doses , 2008 .

[65]  Basil W. Coutant,et al.  Qualitative and quantitative evaluation of MODIS satellite sensor data for regional and urban scale air quality , 2004 .

[66]  Yoram J. Kaufman,et al.  An Emerging Global Aerosol Climatology from the MODIS Satellite Sensors , 2008 .

[67]  G. Gobbi,et al.  Aerosol seasonal variability over the Mediterranean region and relative impact of maritime, continental and Saharan dust particles over the basin from MODIS data in the year 2001 , 2004 .

[68]  Xavier Querol,et al.  Spatial and temporal variability in aerosol properties over the Mediterranean basin based on 6-year (2000-2006) MODIS data , 2008 .