Uranium(III)-carbon multiple bonding supported by arene δ-bonding in mixed-valence hexauranium nanometre-scale rings

[1]  C. Barnes,et al.  Formation of Methane versus Benzene in the Reactions of (C5 Me5 )2 Th(CH3 )2 with [CH3 PPh3 ]X (X=Cl, Br, I) Yielding Thorium-Carbene or Thorium-Ylide Complexes. , 2017, Angewandte Chemie.

[2]  F. Tuna,et al.  Rare‐Earth‐ and Uranium‐Mesoionic Carbenes: A New Class of f‐Block Carbene Complex Derived from an N‐Heterocyclic Olefin , 2017, Angewandte Chemie.

[3]  Y. Joly,et al.  The role of the 5f valence orbitals of early actinides in chemical bonding , 2017, Nature Communications.

[4]  F. Tuna,et al.  Actinide covalency measured by pulsed electron paramagnetic resonance spectroscopy. , 2017, Nature chemistry.

[5]  R. Baumbach,et al.  Incipient class II mixed valency in a plutonium solid-state compound. , 2017, Nature chemistry.

[6]  Guang Wu,et al.  Synthesis, Thermochemistry, Bonding, and 13C NMR Chemical Shift Analysis of a Phosphorano-Stabilized Carbene of Thorium , 2017 .

[7]  A. J. Blake,et al.  The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes , 2017 .

[8]  Daniel S. Levine,et al.  Evidence for the Existence of Group 3 Terminal Methylidene Complexes , 2017 .

[9]  F. Tuna,et al.  Uranium-Carbene-Imido Metalla-Allenes: Ancillary-Ligand-Controlled cis-/trans-Isomerisation and Assessment of trans Influence in the R2 C=U(IV) =NR' Unit (R=Ph2 PNSiMe3 ; R'=CPh3 ). , 2016, Chemistry.

[10]  F. Tuna,et al.  Uranium Metalla-Allenes with Carbene Imido R2 C=U(IV) =NR' Units (R=Ph2 PNSiMe3 ; R'=CPh3 ): Alkali-Metal-Mediated Push-Pull Effects with an Amido Auxiliary. , 2016, Chemistry.

[11]  R. Scopelliti,et al.  Synthesis and Structure of Nitride-Bridged Uranium(III) Complexes. , 2016, Journal of the American Chemical Society.

[12]  A. J. Blake,et al.  Emergence of comparable covalency in isostructural cerium(iv)– and uranium(iv)–carbon multiple bonds , 2016, Chemical science.

[13]  S. Liddle The Renaissance of Non-Aqueous Uranium Chemistry. , 2015, Angewandte Chemie.

[14]  S. Liddle Inverted sandwich arene complexes of uranium , 2015 .

[15]  Z. Mazej,et al.  The first example of a mixed valence ternary compound of silver with random distribution of Ag(I) and Ag(II) cations. , 2015, Dalton transactions.

[16]  S. Odoh,et al.  Investigation of the electronic ground states for a reduced pyridine(diimine) uranium series: evidence for a ligand tetraanion stabilized by a uranium dimer. , 2015, Journal of the American Chemical Society.

[17]  S. Liddle,et al.  Covalent Uranium Carbene Chemistry , 2015 .

[18]  A. J. Blake,et al.  Reactivity of the uranium(IV) carbene complex [U(BIPM(TMS))(Cl)(μ-Cl)₂Li(THF)₂] (BIPM(TMS) = {C(PPh₂NSiMe₃)₂}) towards carbonyl and heteroallene substrates: metallo-Wittig, adduct formation, C-F bond activation, and [2 + 2]-cycloaddition reactions. , 2014, Dalton transactions.

[19]  W. Evans,et al.  Magnetic susceptibility of uranium complexes. , 2014, Chemical reviews.

[20]  W. Hieringer,et al.  Synthesis and characterization of a uranium(II) monoarene complex supported by δ backbonding. , 2014, Angewandte Chemie.

[21]  A. J. Blake,et al.  Synthesis, Characterization, and Reactivity of a Uranium(VI) Carbene Imido Oxo Complex** , 2014, Angewandte Chemie.

[22]  K. Meyer,et al.  Activation of Small Molecules by Molecular Uranium Complexes , 2014 .

[23]  J. Ziller,et al.  Identification of the +2 oxidation state for uranium in a crystalline molecular complex, [K(2.2.2-cryptand)][(C5H4SiMe3)3U]. , 2013, Journal of the American Chemical Society.

[24]  W. Lukens,et al.  Quantifying the σ and π interactions between U(V) f orbitals and halide, alkyl, alkoxide, amide and ketimide ligands. , 2013, Journal of the American Chemical Society.

[25]  A. J. Blake,et al.  The nature of the U=C double bond: pushing the stability of high-oxidation-state uranium carbenes to the limit. , 2013, Chemistry.

[26]  M. Ephritikhine Uranium carbene compounds , 2013 .

[27]  Trevor W. Hayton,et al.  Recent developments in actinide-ligand multiple bonding. , 2013, Chemical communications.

[28]  Bess Vlaisavljevich,et al.  Investigations of the Electronic Structure of Arene-Bridged Diuranium Complexes , 2013 .

[29]  A. Gaunt,et al.  Recent developments in synthesis and structural chemistry of nonaqueous actinide complexes. , 2013, Chemical reviews.

[30]  B. Scott,et al.  Tetrahalide complexes of the [U(NR)2]2+ ion: synthesis, theory, and chlorine K-edge X-ray absorption spectroscopy. , 2013, Journal of the American Chemical Society.

[31]  Christophe Copéret,et al.  Siloxides as supporting ligands in uranium(III)-mediated small-molecule activation. , 2012, Angewandte Chemie.

[32]  F. Heinemann,et al.  Oxidation state delineation via U L(III)-edge XANES in a series of isostructural uranium coordination complexes. , 2012, Inorganic chemistry.

[33]  A. J. Blake,et al.  Synthesis of a uranium(VI)-carbene: reductive formation of uranyl(V)-methanides, oxidative preparation of a [R2C═U═O]2+ analogue of the [O═U═O]2+ uranyl ion (R = Ph2PNSiMe3), and comparison of the nature of U(IV)═C, U(V)═C, and U(VI)═C double bonds. , 2012, Journal of the American Chemical Society.

[34]  Richard L. Martin,et al.  Determining relative f and d orbital contributions to M-Cl covalency in MCl6(2-) (M = Ti, Zr, Hf, U) and UOCl5(-) using Cl K-edge X-ray absorption spectroscopy and time-dependent density functional theory. , 2012, Journal of the American Chemical Society.

[35]  W. Lukens,et al.  Probing the 5f orbital contribution to the bonding in a U(V) ketimide complex. , 2012, Journal of the American Chemical Society.

[36]  L. Andrews,et al.  Infrared Spectra of the η2-M(NC)-CH3, CH3-MNC, and CH2═M(H)NC Complexes Prepared by Reactions of Thorium and Uranium Atoms with Acetonitrile , 2012 .

[37]  Joseph W. Ziller,et al.  Synthesis, structure, and magnetism of an f element nitrosyl complex, (C5Me4H)3UNO. , 2012, Journal of the American Chemical Society.

[38]  A. J. Blake,et al.  A formal high oxidation state inverse-sandwich diuranium complex: a new route to f-block-metal bonds. , 2011, Angewandte Chemie.

[39]  Michael J. Ferguson,et al.  Actinide metals with multiple bonds to carbon: synthesis, characterization, and reactivity of U(IV) and Th(IV) bis(iminophosphorano)methandiide pincer carbene complexes. , 2011, Inorganic chemistry.

[40]  A. J. Blake,et al.  A delocalized arene-bridged diuranium single-molecule magnet. , 2011, Nature chemistry.

[41]  M. Ephritikhine,et al.  Uranium(IV) Nucleophilic Carbene Complexes , 2011 .

[42]  S. Liddle,et al.  Early metal bis(phosphorus-stabilised)carbene chemistry. , 2011, Chemical Society reviews.

[43]  Guang Wu,et al.  Synthesis of a phosphorano-stabilized U(IV)-carbene via one-electron oxidation of a U(III)-ylide adduct. , 2011, Journal of the American Chemical Society.

[44]  M. Ephritikhine,et al.  Exploring the uranyl organometallic chemistry: from single to double uranium-carbon bonds. , 2011, Journal of the American Chemical Society.

[45]  A. J. Blake,et al.  Uranium-carbon multiple bonding: facile access to the pentavalent uranium carbene [U{C(PPh2NSiMe3)2}(Cl)2(I)] and comparison of U(V)=C and U(IV)=C bonds. , 2011, Angewandte Chemie.

[46]  Luis Serrano-Andrés,et al.  Multiconfigurational Second-Order Perturbation Theory Restricted Active Space (RASPT2) Method for Electronic Excited States: A Benchmark Study. , 2011, Journal of chemical theory and computation.

[47]  A. J. Blake,et al.  Synthesis and structure of [U{C(PPh2NMes)2}2] (Mes = 2,4,6-Me3C6H2): A homoleptic uranium bis(carbene) complex with two formal U=C double bonds. , 2010, Dalton transactions.

[48]  L. Maron,et al.  A theoretical study of uranium(IV) bis-methyl complexes: towards the predictive formation of a transient uranium(IV) carbene complex. , 2010, Chemistry.

[49]  M. Ephritikhine,et al.  Easy access to uranium nucleophilic carbene complexes. , 2010, Dalton transactions.

[50]  B. Scott,et al.  Comparative study of f-element electronic structure across a series of multimetallic actinide and lanthanoid-actinide complexes possessing redox-active bridging ligands. , 2010, Inorganic chemistry.

[51]  Trevor W. Hayton,et al.  Metal-ligand multiple bonding in uranium: structure and reactivity. , 2010, Dalton transactions.

[52]  Ping Yang,et al.  Trends in covalency for d- and f-element metallocene dichlorides identified using chlorine K-edge X-ray absorption spectroscopy and time-dependent density functional theory. , 2009, Journal of the American Chemical Society.

[53]  M. Ephritikhine,et al.  The U=C double bond: synthesis and study of uranium nucleophilic carbene complexes. , 2009, Journal of the American Chemical Society.

[54]  L. Andrews,et al.  Reactions of actinide metal atoms with ethane: computation and observation of new Th and U ethylidene dihydride, metallacyclopropane dihydride, and vinyl metal trihydride complexes. , 2008, The journal of physical chemistry. A.

[55]  B. Scott,et al.  Mixed valency in a uranium multimetallic complex. , 2008, Angewandte Chemie.

[56]  Jun Yu Li,et al.  Infrared spectra and electronic structures of agostic uranium methylidene molecules. , 2008, Inorganic chemistry.

[57]  P. Hitchcock,et al.  Activation and reduction of diethyl ether by low valent uranium: formation of the trimetallic, mixed valence uranium oxo species [U(CpRR')(mu-I)2]3(mu3-O) (CpRR' = C5Me5, C5Me4H, C5H4SiMe3). , 2008, Chemical communications.

[58]  B. Roos,et al.  Agostic interaction in the methylidene metal dihydride complexes H2MCH2 (M=Y, Zr, Nb, Mo, Ru, Th, or U). , 2007, The journal of physical chemistry. A.

[59]  B. Roos,et al.  Infrared spectrum and bonding in uranium methylidene dihydride, CH2=UH2. , 2007, Inorganic chemistry.

[60]  D. Reinhoudt,et al.  Multicoordinate ligands for actinide/lanthanide separations. , 2007, Chemical Society reviews.

[61]  K. Meyer,et al.  Small molecule activation at uranium coordination complexes: control of reactivity via molecular architecture. , 2006, Chemical communications.

[62]  L. Andrews,et al.  Formation and characterization of the uranium methylidene complexes CH2 = UHX (X = F, Cl, and Br). , 2006, Inorganic chemistry.

[63]  J. Ziller,et al.  Molecular Octa-Uranium Rings with Alternating Nitride and Azide Bridges , 2005, Science.

[64]  J. Ziller,et al.  Structure, reactivity, and density functional theory analysis of the six-electron reductant, [(C5Me5)2U]2(mu-eta6:eta6-C6H6), synthesized via a new mode of (C5Me5)3M reactivity. , 2004, Journal of the American Chemical Society.

[65]  L. Zakharov,et al.  Synthesis and characterization of N-heterocyclic carbene complexes of uranium(III). , 2004, Inorganic chemistry.

[66]  J. Ziller,et al.  A monometallic f element complex of dinitrogen: (C5Me5)3U(eta1-N2). , 2003, Journal of the American Chemical Society.

[67]  J. Ziller,et al.  Comparative reactivity of sterically crowded nf3 (C5Me5)3Nd and (C5Me5)3U complexes with CO: formation of a nonclassical carbonium ion versus an f element metal carbonyl complex. , 2003, Journal of the American Chemical Society.

[68]  P. Hay,et al.  Dinuclear Trivalent and Mixed-Valence Uranium [(−CH2−)5]4-calix[4]tetrapyrrole Complexes with Short Intermetallic Distances , 2001 .

[69]  M. Ephritikhine,et al.  Reactions of aliphatic ketones R2CO (R=Me, Et, iPr and tBu) with the MCI4/Li(Hg) system (M=U or Ti): mechanistic analogies between the McMurry, Wittig, and Clemmensen reactions. , 2001, Chemistry.

[70]  P. Arnold,et al.  Arene-Bridged Diuranium Complexes: Inverted Sandwiches Supported by δ Backbonding , 2000 .

[71]  P. Hitchcock,et al.  A MIXED-VALENCE URANIUM(III/IV) BIMETALLIC ; STRUCTURE, MAGNETISM AND REACTIVITY , 1996 .

[72]  S. Coles,et al.  Synthesis and Single Crystal X-ray Diffraction Study on the First Isolable Carbonyl Complex of an Actinide, (C5Me4H)3U(CO) , 1995 .

[73]  J. Murrell Structure and Reactivity , 1989 .

[74]  J. Robbins,et al.  Preparation of the First Molecular Carbon Monoxide Complex of Uranium, (Me3SiC5H4)3UCO , 1986 .

[75]  T. Marks,et al.  Supported organoactinides. Surface chemistry and catalytic properties of alumina-bound (cyclopentadienyl)-and (pentamethylcyclopentadienyl)thorium and -uranium hydrocarbyls and hydrides , 1985 .

[76]  K. Higa,et al.  Uranium-carbon multiple-bond chemistry. 4. Addition of coordinated carbon monoxide across a uranium-carbon multiple bond , 1984 .

[77]  R. Cramer,et al.  Isocyanide Insertion into a Uranium‐Carbon Double Bond , 1984 .

[78]  R. Cramer,et al.  Uranium carbon multiple-bond chemistry. 3. Insertion of acetonitrile and the formation of a uranium nitrogen multiple bond , 1984 .

[79]  K. Higa,et al.  URANIUM-CARBON MULTIPLE BOND CHEMISTRY. 2. COUPLING OF BRIDGING AND TERMINAL CARBONYLS IN THE FORMATION OF AN IRON η1:η3-ALLYL COMPLEX , 1984 .

[80]  K. Higa,et al.  Uranium-carbon multiple bond chemistry. 2. Coupling of bridging and terminal carbonyls in the formation of an iron .eta.1:.eta.3-allyl complex , 1983 .

[81]  R. Bader,et al.  Description of conjugation and hyperconjugation in terms of electron distributions , 1983 .

[82]  R. B. Maynard,et al.  A uranium-carbon multiple bond. Crystal and molecular structure of (.eta.5-C5H5)3UCHP(CH3)2(C6H5) , 1981 .

[83]  R. B. Maynard,et al.  Uranium-carbon multiple bond. Crystal and molecular structure of (eta/sup 5/-C/sub 5/H/sub 5/)/sub 3/UCHP(CH/sub 3/)/sub 2/(C/sub 6/H/sub 5/) , 1981 .

[84]  J. C. Strauss,et al.  A benchmark study , 1972, AFIPS '72 (Fall, part II).