Preparation and stability of butterfly pea color extract loaded in microparticles prepared by spray drying

Butterfly pea is one of the most interesting sources of natural color used in food and cosmetics. Anthocyanins are the main coloring compounds in its petals and could be extracted easily with water. The pH of medium, temperature, and light were found to affect stability of the color aqueous extract from butterfly pea petals. Acidity and alkalinity of the solvent did not only change shade of the color but also affected the color stability. The color presented the most stable in pH 4 solution under darkness and the least stable in pH 7 solution under UV light. The higher the temperature the more the color loss. In an attempt to improve the color stability, microparticulated system prepared by spray drying technique was employed in this study. Hydroxylpropylmethyl cellulose (HPMC) and gelatin were used as carrier polymers. The operating condition providing optimum production yield was determined using 2 3 factorial design. The factors were % solid in the feed solution, inlet temperature, and solution feed rate. The optimized condition was 5% w/w of solid in the feed solution, 130 I inlet temperature, and 10 ml/min of solution feed rate for both HPMC and gelatin. Color stability of the microparticulated particles was studied under heat and UV light. Gelatin microparticulated system presented better protection against UV light than HPMC microparticulated system and aqueous color solution. Therefore, polymer type should be carefully selected for preparing the microparticulated particles. However, no protection against thermal degradation was observed in both gelatin and HPMC microparticulated systems.

[1]  K. Duangmal,et al.  Colour evaluation of freeze-dried roselle extract as a natural food colorant in a model system of a drink , 2008 .

[2]  G. Burdock Safety assessment of hydroxypropyl methylcellulose as a food ingredient. , 2007, Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association.

[3]  R. Bodmeier,et al.  Encapsulation of lipophilic drugs within enteric microparticles by a novel coacervation method. , 2006, International journal of pharmaceutics.

[4]  Muriel Jacquot,et al.  Flavour encapsulation and controlled release – a review , 2006 .

[5]  J. Oszmiański,et al.  The effects of heating, UV irradiation, and storage on stability of the anthocyanin-polyphenol copigment complex , 2003 .

[6]  A. Dash,et al.  Evaluation of red cabbage dye as a potential natural color for pharmaceutical use. , 2002, International journal of pharmaceutics.

[7]  Kodjo Boady Djagny,et al.  Gelatin: A Valuable Protein for Food and Pharmaceutical Industries: Review , 2001, Critical reviews in food science and nutrition.

[8]  C. Biliaderis,et al.  Degradation kinetics of beetroot pigment encapsulated in polymeric matrices , 2001 .

[9]  H. Kristensen,et al.  Preparation of redispersible dry emulsions by spray drying. , 2001, International journal of pharmaceutics.

[10]  H. Corke,et al.  Production and Properties of Spray‐dried Amaranthus Betacyanin Pigments , 2000 .

[11]  T. Fossen,et al.  Analytical, Nutritional and Clinical Methods Section Colour and stability of the six common anthocyanidin 3-glucosides in aqueous solutions , 2000 .

[12]  Torgils Fossen,et al.  Colour and stability of pure anthocyanins influenced by pH including the alkaline region , 1998 .

[13]  Matsui,et al.  Eight new anthocyanins, ternatins C1-C5 and D3 and preternatins A3 and C4 from young clitoria ternatea flowers , 1998, Journal of natural products.

[14]  F. Pina,et al.  Photochemical and thermal degradation of anthocyanidins , 1993 .

[15]  J. Verghese Isolation of curcumin from Curcuma longa L. rhizome , 1993 .

[16]  H. Masaki,et al.  Major anthocyanin of the flowers of hibiscus (Hibiscus rosa-sinensis L.). , 1990 .

[17]  R. Brouillard Chapter 1 – Chemical Structure of Anthocyanins , 1982 .

[18]  J. Adams Thermal degradation of anthocyanins with particular reference to the 3‐glycosides of cyanidin. I. In acidified aqueous solution at 100 °C , 1973 .