Predicting ammonia losses following the application of livestock manure to land.

A series of experiments was conducted using small wind tunnels to assess the influence of a range of environmental, manure and management variables on ammonia emissions following application of different manure types to grassland and arable land. Wind speed and dry matter content (for cattle slurry in particular) were identified as the parameters with greatest influence on ammonia emissions from slurries. For solid manures, rainfall was identified as the parameter with most influence on ammonia emissions. A Michaelis-Menten function was used to describe emission rates following manure application. Linear regression was then used to develop statistical models relating the Michaelis-Menten function parameters to the experimental variables for each manure type/land use combination. The fitted models accounted for between 62% and 94% of the variation in the data. Validation of the models for cattle slurry to grassland and pig slurry to arable land against independent data sets obtained from experiments using the micrometeorological mass balance measurement technique showed that the models overestimated losses, which was most probably due to inherent differences between the wind tunnel and the micrometerological mass balance measurement techniques.

[1]  J. P. Frost,et al.  Effect of acidification with sulphuric acid on the volatilization of ammonia from cow and pig slurries , 1989, The Journal of Agricultural Science.

[2]  H. Marschner,et al.  Estimation of ammonia losses after application of liquid cattle manure on grassland , 1997 .

[3]  B. F. Pain,et al.  Reduction of ammonia emission by slurry application techniques. , 2000 .

[4]  E. Holland,et al.  Gaseous Nitrogen Emissions from Grasslands , 1997 .

[5]  A. Neftel,et al.  A simple empirical model based on regression analysis to estimate ammonia emissions after manure application , 1998 .

[6]  J. P. Frost Effect of spreading method, application rate and dilution on ammonia volatilization from cattle slurry , 1994 .

[7]  Jørgen E. Olesen,et al.  Effects of temperature, wind speed and air humidity on ammonia volatilization from surface applied cattle slurry , 1991, The Journal of Agricultural Science.

[8]  S. G. Sommer,et al.  Infiltration of slurry liquid and volatilization of ammonia from surface applied pig slurry as affected by soil water content , 1999, The Journal of Agricultural Science.

[9]  B. F. Pain,et al.  Ammonia volatilization from cattle slurry following surface application to grassland , 1990, Plant and Soil.

[10]  Theo Demmers,et al.  Ammonia emission factors for UK agriculture. , 2000 .

[11]  J. Clemens,et al.  NH3 and N2O Emissions after Landspreading of Slurry as Influenced by Application Technique and Dry Matter-Reduction. I. NH3 Emissions , 1997 .

[12]  P. Cellier,et al.  A mechanistic model for estimating ammonia volatilization from slurry applied to bare soil , 1997 .

[13]  K. A. Smith,et al.  A survey of the production and use of animal manures in England and Wales , 2001 .

[14]  K. Smith,et al.  A survey of the production and use of animal manures in England and Wales. I. Pig manure , 2000 .

[15]  D. R. Lockyer A system for the measurement in the field of losses of ammonia through volatilisation , 1984 .

[16]  A. Beljaars,et al.  Ammonia volatilization from arable land after application of cattle slurry. 2. Derivation of a transfer model. , 1990 .

[17]  S. Jarvis,et al.  Ammonia emissions following the land spreading of solid manures. , 1997 .

[18]  R. Gordon,et al.  Effect of Meteorological Parameters on Ammonia Loss from Manure in the Field , 1988 .

[19]  J. P. Frost,et al.  Effect of separation and acidification of cattle slurry on ammonia volatilization and on the efficiency of slurry nitrogen for herbage production , 1990, The Journal of Agricultural Science.

[20]  R. Barnes,et al.  Use of Mean Square Prediction Error Analysis and Reproducibility Measures to Study near Infrared Calibration Equation Performance , 1999 .

[21]  B. F. Pain,et al.  Loss of nitrogen through ammonia volatilisation during and following the application of pig or cattle slurry to grassland , 1989 .

[22]  T. Misselbrook,et al.  Effects of nitrification inhibitor and acid addition to cattle slurry on nitrogen losses and herbage yields , 1994 .

[23]  José I. Martínez,et al.  Ammonia volatilization following surface-applied pig and cattle slurry in France , 1995, The Journal of Agricultural Science.

[24]  B. F. Pain,et al.  Slurry application techniques to reduce ammonia emissions: results of some UK field-scale experiments , 2002 .

[25]  H. T. Søgaard,et al.  Ammonia volatilization from field-applied animal slurry - the ALFAM model. , 2002 .

[26]  Jørgen E. Olesen,et al.  Effects of Dry Matter Content and Temperature on Ammonia Loss from Surface-Applied Cattle Slurry , 1991 .

[27]  A. Ersbøll,et al.  Soil Tillage Effects on Ammonia Volatilization from Surface‐Applied or Injected Animal Slurry , 1994 .