Functional silica nanoparticles synthesized by water-in-oil microemulsion processes.

Water-in-oil (W/O) microemulsion is a well-suitable confined reacting medium for the synthesis of structured functional nanoparticles of controlled size and shape. During the last decade, it allowed the synthesis of multi-functional silica nanoparticles with morphologies as various as core-shell, homogenous dispersion or both together. The morphology and properties of the different intermediates and final materials obtained through this route are discussed in the light of UV-Vis-NIR spectroscopy, dynamic light scattering (DLS) and X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM) and magnetometer SQUID analysis.

[1]  A. Demourgues,et al.  New Highly Divided Ce−Ca-Based Oxyfluorides with UV-Shielding Properties: Study of the Ce1-xCaxO2-x and Ce1-xCaxO2-x-y/2Fy Series , 2007 .

[2]  Hung-Ting Chen,et al.  Synthesis and functionalization of a mesoporous silica nanoparticle based on the sol-gel process and applications in controlled release. , 2007, Accounts of chemical research.

[3]  T. Nann,et al.  Single Quantum Dots in Silica Spheres by Microemulsion Synthesis , 2005 .

[4]  S. Cordier,et al.  A hybrid material based on [Mo6Br14]2− inorganic cluster units and [BEDO-TTF]+ organic monocationic radicals: Synthesis, structure and properties of (BEDO-TTF)2Mo6Br14(PhCN)4 , 2006 .

[5]  J. Schulman,et al.  Mechanism of Formation and Structure of Micro Emulsions by Electron Microscopy , 1959 .

[6]  É. Duguet,et al.  Magnetic nanoparticle design for medical diagnosis and therapy , 2004 .

[7]  Jing Cheng,et al.  Facile fabrication of multi-colors high fluorescent/superparamagnetic nanoparticles. , 2008, Journal of colloid and interface science.

[8]  A. Vekris,et al.  Synthesis, magnetic properties, surface modification and cytotoxicity evaluation of Y3Fe5−xAlxO12 (0⩽x⩽2) garnet submicron particles for biomedical applications , 2001 .

[9]  M. Mortier,et al.  Novel Nanomaterials Based on Inorganic Molybdenum Octahedral Clusters , 2009 .

[10]  J. Eastoe,et al.  Recent advances in nanoparticle synthesis with reversed micelles. , 2006, Advances in colloid and interface science.

[11]  M. Correa‐Duarte,et al.  Increasing the Complexity of Magnetic Core/Shell Structured Nanocomposites for Biological Applications , 2007 .

[12]  C. Ménager,et al.  Giant vesicles containing magnetic nanoparticles and quantum dots: feasibility and tracking by fiber confocal fluorescence microscopy. , 2007, Angewandte Chemie.

[13]  Seiichi Kondo,et al.  Surface characterization of ultramicro spherical particles of silica prepared by w/o microemulsion method , 1989 .

[14]  J. E. Mark,et al.  A novel technique for preparing organophilic silica by water-in-oil microemulsions , 1990 .

[15]  H. Gray,et al.  Electrochemical reduction of molybdenum(II) and tungsten(II) halide cluster ions. Electrogenerated chemiluminescence of tetradecachlorohexamolybdate(2-) ion , 1984 .

[16]  Wenjun Zhao,et al.  Bioconjugated silica nanoparticles: Development and applications , 2008 .

[17]  Shuming Nie,et al.  Mesoporous silica beads embedded with semiconductor quantum dots and iron oxide nanocrystals: dual-function microcarriers for optical encoding and magnetic separation. , 2006, Analytical chemistry.

[18]  Jicun Ren,et al.  Aqueous synthesis of CdTe@FeOOH and CdTe@Ni(OH)2 composited nanoparticles , 2006 .

[19]  M. López-Quintela,et al.  Synthesis of nanomaterials in microemulsions: formation mechanisms and growth control ☆ , 2003 .

[20]  J. Bartlett,et al.  Formation of silica nanoparticles in microemulsions. , 2007, Langmuir : the ACS journal of surfaces and colloids.

[21]  Dong-Hwang Chen,et al.  Fabrication of Magnetic Luminescent Nanocomposites via Adsorption-Precipitation of Metal Ions on Sulfonated Iron Oxide Nanoparticles , 2006 .

[22]  V. Marchi-Artzner,et al.  One-pot synthesis and characterizations of bi-functional phosphor-magnetic @SiO(2) nanoparticles: controlled and structured association of Mo(6) cluster units and gamma-Fe(2)O(3) nanocrystals. , 2008, Chemical communications.

[23]  Philippe Rostaing,et al.  Diffusion Dynamics of Glycine Receptors Revealed by Single-Quantum Dot Tracking , 2003, Science.

[24]  Jooho Moon,et al.  Preparation of Ag/SiO2 nanosize composites by a reverse micelle and sol-gel technique , 1999 .

[25]  Shuming Nie,et al.  Quantum dots and multifunctional nanoparticles: new contrast agents for tumor imaging. , 2006, Nanomedicine.

[26]  Chenjie Xu,et al.  Au-Fe3O4 dumbbell nanoparticles as dual-functional probes. , 2008, Angewandte Chemie.

[27]  Chemical Synthesis and Silica Encapsulation of NiPt Nanoparticles , 2007 .

[28]  Weihong Tan,et al.  Synthesis and Characterization of Silica-Coated Iron Oxide Nanoparticles in Microemulsion: The Effect of Nonionic Surfactants , 2001 .

[29]  Y. Bando,et al.  Water‐in‐Oil Microemulsion Preparation and Characterization of Cs2[Mo6X14]@SiO2 Phosphor Nanoparticles Based on Transition Metal Clusters (X = Cl, Br, and I) , 2008 .

[30]  M. Pileni Control of the Size and Shape of Inorganic Nanocrystals at Various Scales from Nano to Macrodomains , 2007 .

[31]  J. Etourneau,et al.  Memory effect and super-spin-glass ordering in an aggregated nanoparticle sample , 2004 .

[32]  D. Astruc,et al.  Mo6X8i Nanocluster cores (X = Br, I): From inorganic solid state compounds to hybrids , 2006 .

[33]  Q. Lu,et al.  Fe3O4/CdSe/ZnS magnetic fluorescent bifunctional nanocomposites , 2006 .

[34]  H. Chang,et al.  Simple synthesis of functionalized superparamagnetic magnetite/silica core/shell nanoparticles and their application as magnetically separable high-performance biocatalysts. , 2008, Small.

[35]  Jackie Y Ying,et al.  Silica-coated nanocomposites of magnetic nanoparticles and quantum dots. , 2005, Journal of the American Chemical Society.

[36]  N. Labhsetwar,et al.  Synthesis and Magnetic Characterization of Zinc Ferrite Nanoparticles with Different Environments: Powder, Colloidal Solution, and Zinc Ferrite−Silica Core−Shell Nanoparticles , 2002 .

[37]  Andrew A. Burns,et al.  Fluorescent core-shell silica nanoparticles: towards "Lab on a Particle" architectures for nanobiotechnology. , 2006, Chemical Society reviews.

[38]  K. Osseo-Asare,et al.  Preparation of SiO2 nanoparticles in a non-ionic reverse micellar system , 1990 .

[39]  Jun Ding,et al.  Monodisperse silica nanoparticles encapsulating upconversion fluorescent and superparamagnetic nanocrystals. , 2008, Chemical communications.

[40]  Franck Artzner,et al.  Small Bioactivated Magnetic Quantum Dot Micelles , 2008 .

[41]  Serge Ravaine,et al.  Periodic Distribution of Planar Defects in Colloidal Photonic Crystals , 2008 .

[42]  Hyungrak Kim,et al.  Synthesis and characterization of Co/CdSe core/shell nanocomposites: bifunctional magnetic-optical nanocrystals. , 2005, Journal of the American Chemical Society.

[43]  Sara Lögdberg,et al.  Recent developments in the application of nanoparticles prepared from w/o microemulsions in heterogeneous catalysis , 2008 .

[44]  W. Tan,et al.  Multifunctional Quantum‐Dot‐Based Magnetic Chitosan Nanobeads , 2005 .

[45]  M. Kishida,et al.  Novel Synthesis of Silica‐Coated Ferrite Nanoparticles Prepared Using Water‐in‐Oil Microemulsion , 2002 .

[46]  D. Nocera,et al.  Spectroscopic and photophysical properties of hexanuclear rhenium(III) chalcogenide clusters. , 2003, Journal of the American Chemical Society.

[47]  Zeev Rosenzweig,et al.  Superparamagnetic Fe2O3 Beads−CdSe/ZnS Quantum Dots Core−Shell Nanocomposite Particles for Cell Separation , 2004 .

[48]  X. Hou,et al.  4-(N,N-Dimethylamino)benzoic Acid as a New Class of Simple Chromogenic and Fluorogenic Anion Host Exhibiting High Selectivity to HPO42- and SO42- , 2006 .

[49]  D. Pang,et al.  Cell-targeting multifunctional nanospheres with both fluorescence and magnetism. , 2005, Small.

[50]  R. Juang,et al.  An overview of the structure and magnetism of spinel ferrite nanoparticles and their synthesis in microemulsions , 2007 .

[51]  Scott C. Brown,et al.  Nanoparticles for bioimaging. , 2006, Advances in colloid and interface science.

[52]  Kemin Wang,et al.  Dye-doped nanoparticles for bioanalysis , 2007 .

[53]  Pablo Ballester,et al.  Cover Picture: Inclusion of Cavitands and Calix[4]arenes into a Metallobridged para‐(1H‐Imidazo[4,5‐f][3,8]phenanthrolin‐2‐yl)‐Expanded Calix[4]arene (Angew. Chem. Int. Ed. 1‐2/2007) , 2007 .

[54]  João Rodrigues,et al.  From simple monopyridine clusters [Mo6Br13(Py-R)][n-Bu4N] and hexapyridine clusters [Mo6X8(Py-R)6][OSO2CF3]4 (X = Br or I) to cluster-cored organometallic stars, dendrons, and dendrimers. , 2006, Inorganic chemistry.

[55]  Yadong Yin,et al.  Magnetically Tunable Colloidal Photonic Structures in Alkanol Solutions , 2008 .

[56]  Yoshio Kobayashi,et al.  Preparation and Properties of Silica-Coated Cobalt Nanoparticles† , 2003 .

[57]  K. Holmberg Surfactant-templated nanomaterials synthesis. , 2004, Journal of colloid and interface science.

[58]  Hao Zeng,et al.  Syntheses, Properties, and Potential Applications of Multicomponent Magnetic Nanoparticles† , 2008 .

[59]  C. Contag,et al.  It's not just about anatomy: In vivo bioluminescence imaging as an eyepiece into biology , 2002, Journal of magnetic resonance imaging : JMRI.

[60]  M. Kishida,et al.  Synthesis and Optical Properties of SiO2-Coated CeO2 Nanoparticles , 2003 .

[61]  Chung-Yuan Mou,et al.  Bifunctional magnetic silica nanoparticles for highly efficient human stem cell labeling. , 2007, Nano letters.

[62]  Miguel A. Correa-Duarte,et al.  Composite Silica Spheres with Magnetic and Luminescent Functionalities , 2006 .

[63]  R. Marchand,et al.  Synthesis of CeO2@SiO2 core-shell nanoparticles by water-in-oil microemulsion. Preparation of functional thin film. , 2006, Journal of colloid and interface science.

[64]  Timothy Thatt Yang Tan,et al.  Size control, shape evolution, and silica coating of near-infrared-emitting PbSe quantum dots , 2007 .

[65]  M. López-Quintela,et al.  Microemulsion dynamics and reactions in microemulsions , 2004 .

[66]  Lining Sun,et al.  Bifunctional magnetic-optical nanocomposites: grafting lanthanide complex onto core-shell magnetic silica nanoarchitecture. , 2007, Langmuir : the ACS journal of surfaces and colloids.

[67]  Superscratch-resistant glass by means of a transparent nanostructured inorganic coating , 2007 .

[68]  Wei Guo,et al.  Fabrication of Magnetic Luminescent Nanocomposites by a Layer-by-Layer Self-assembly Approach , 2004 .

[69]  Bai Yang,et al.  Bifunctional Fe3O4/CdS nanocomposites synthesized by surface-initiated atom transfer radical polymerization , 2005 .

[70]  Victor S-Y Lin,et al.  Mesoporous silica nanoparticles for intracellular delivery of membrane-impermeable proteins. , 2007, Journal of the American Chemical Society.

[71]  Z. J. Zhang,et al.  Synthesis and magnetic characterization of Mn and Co spinel ferrite-silica nanoparticles with tunable magnetic core , 2003 .

[72]  J. Dominguez‐Vera,et al.  Quantum Dots Decorated with Magnetic Bionanoparticles , 2008 .