Laser-induced incandescence: recent trends and current questions

This paper provides an overview of a workshop focused on fundamental experimental and theoretical aspects of soot measurements by laser-induced incandescence (LII). This workshop was held in Duisburg, Germany in September 2005. The goal of the workshop was to review the current understanding of the technique and identify gaps in this understanding associated with experimental implementation, model descriptions, and signal interpretation. The results of this workshop suggest that uncertainties in the understanding of this technique are sufficient to lead to large variability among model predictions from different LII models, among measurements using different experimental approaches, and between modeled and measured signals, even under well-defined conditions. This article summarizes the content and conclusions of the workshop, discusses controversial topics and areas of disagreement identified during the workshop, and highlights recent important references related to these topics. It clearly demonstrates that despite the widespread application of LII for soot-concentration and particle-size measurements there is still a significant lack in fundamental understanding for many of the underlying physical processes.

[1]  Fengshan Liu,et al.  Effects of primary particle diameter and aggregate size distribution on the temperature of soot particles heated by pulsed lasers , 2005 .

[2]  D. E. Rosner,et al.  Simultaneous measurements of soot volume fraction and particle size/ Microstructure in flames using a thermophoretic sampling technique , 1997 .

[3]  Walter Koechner,et al.  Solid-State Laser Engineering , 1976 .

[4]  Constantine M. Megaridis,et al.  Morphology of flame-generated soot as determined by thermophoretic sampling , 1987 .

[5]  I. G. Campbell,et al.  Development and application of laser induced incandescence (LII) as a diagnostic for soot particulate measurements , 1998 .

[6]  Clemens F. Kaminski,et al.  Quantitative three-dimensional imaging of soot volume fraction in turbulent non-premixed flames , 2002 .

[7]  Ö. Gülder,et al.  Two-dimensional imaging of soot volume fraction in laminar diffusion flames. , 1999, Applied optics.

[8]  D. Kayes,et al.  Time-resolved laser-induced incandescence of soot: the influence of experimental factors and microphysical mechanisms. , 2003, Applied optics.

[9]  B. Draine,et al.  Discrete-Dipole Approximation For Scattering Calculations , 1994 .

[10]  Ömer L. Gülder,et al.  Determination of the soot absorption function and thermal accommodation coefficient using low-fluence LII in a laminar coflow ethylene diffusion flame , 2004 .

[11]  E. Therssen,et al.  2D imaging of laser wing effects and of soot sublimation in laser-induced incandescence measurements , 2005 .

[12]  H. Michelsen Understanding and predicting the temporal response of laser-induced incandescence from carbonaceous particles , 2003 .

[13]  Robert J. Santoro,et al.  Aerosol dynamic processes of soot aggregates in a laminar ethene diffusion flame , 1993 .

[14]  Robert J. Santoro,et al.  Soot particle formation in laminar diffusion flames , 1987 .

[15]  G. Faeth,et al.  Optical Properties in the Visible of Overfire Soot in Large Buoyant Turbulent Diffusion Flames , 2000 .

[16]  Fengshan Liu,et al.  Influence of polydisperse distributions of both primary particle and aggregate size on soot temperature in low-fluence LII , 2006 .

[17]  C. McEnally,et al.  Experimental study of nonfuel hydrocarbons and soot in coflowing partially premixed ethylene/air flames , 2000 .

[18]  C. Schulz,et al.  TR-LII for sizing of carbon particles forming at room temperature , 2006 .

[19]  Hsueh-Chia Chang,et al.  Determination of the wavelength dependence of refractive indices of flame soot , 1990, Proceedings of the Royal Society of London. Series A: Mathematical and Physical Sciences.

[20]  D. E. Rosner,et al.  Soot volume fraction and temperature measurements in laminar nonpremixed flames using thermocouples , 1997 .

[21]  P O Witze,et al.  Time-resolved laser-induced incandescence and laser elastic-scattering measurements in a propane diffusion flame. , 2001, Applied optics.

[22]  Ronald K. Hanson,et al.  Soot pyrometry using modulated absorption/emission , 2001 .

[23]  Edwin Corporan,et al.  Simultaneous planar laser-induced incandescence, OH planar laser-induced fluorescence, and droplet Mie scattering in swirl-stabilized spray flames. , 2005, Applied optics.

[24]  F. Cignoli,et al.  Time-delayed detection of laser-induced incandescence for the two-dimensional visualization of soot in flames. , 1994, Applied optics.

[25]  D. E. Rosner,et al.  Fractal-like Aggregates: Relation between Morphology and Physical Properties. , 2000, Journal of colloid and interface science.

[26]  P. Roth,et al.  Two-color TR-LII applied to in-cylinder Diesel particle sizing , 2003 .

[27]  C. Koshland,et al.  Nanoparticle production by UV irradiation of combustion generated soot particles , 2004 .

[28]  A. Leipertz,et al.  Determination of primary particle size distributions from time-resolved laser-induced incandescence measurements. , 2004, Applied optics.

[29]  D. Brüggemann,et al.  Laser-induced incandescence and Raman measurements in sooting methane and ethylene flames , 2002 .

[30]  Alan R. Jones,et al.  Light scattering for particle characterization , 1999 .

[31]  J. Seitzman,et al.  Soot volume fraction and particle size measurements with laser-induced incandescence. , 1997, Applied optics.

[32]  K. Gurton,et al.  Trans-spectral absorption and scattering of electromagnetic radiation by diesel soot. , 1991, Applied optics.

[33]  Christopher R. Shaddix,et al.  Aspects of soot dynamics as revealed by measurements of broadband fluorescence and flame luminosity in flickering diffusion flames , 1997 .

[34]  R. L. Wal Soot precursor carbonization: Visualization using LIF and LII and comparison using bright and dark field TEM , 1998 .

[35]  Quantitative measurements of the soot distribution in a realistic common rail D.I. Diesel engine , 2002 .

[36]  D. L. Urban,et al.  Extinction and Scattering Properties of Soot Emitted from Buoyant Turbulent Diffusion Flames. Appendix D , 2001 .

[37]  M. Aldén,et al.  Picosecond laser-induced fluorescence from gas-phase polycyclic aromatic hydrocarbons at elevated temperatures. II. Flame-seeding measurements , 2001 .

[38]  Henning Bockhorn,et al.  Progress in characterization of soot formation by optical methods , 2002 .

[39]  C. Shaddix,et al.  Laser-induced incandescence measurements of soot production in steady and flickering methane, propane, and ethylene diffusion flames , 1996 .

[40]  H. Bladh,et al.  Characteristics of laser-induced incandescence from soot in studies of a time-dependent heat- and mass-transfer model , 2004 .

[41]  C. D. Scott,et al.  Diagnostics of laser-produced plume under carbon nanotube growth conditions , 2000 .

[42]  L. Melton,et al.  Soot diagnostics based on laser heating. , 1984, Applied optics.

[43]  D. Hahn,et al.  Assessment of soot particle vaporization effects during laser-induced incandescence with time-resolved light scattering. , 2005, Applied optics.

[44]  K. J. Weiland,et al.  Laser-induced incandescence: Development and characterization towards a measurement of soot-volume fraction , 1994 .

[45]  N. Tait,et al.  PLIF imaging of fuel fraction in practical devices and LII imaging of soot , 1993 .

[46]  R. V. Vander Wal,et al.  Optical and microscopy investigations of soot structure alterations by laser-induced incandescence , 1998 .

[47]  Robert J. Santoro,et al.  Spatially resolved measurements of soot volume fraction using laser-induced incandescence , 1994 .

[48]  Ümit Özgür Köylü,et al.  Range of validity of the Rayleigh-Debye-Gans theory for optics of fractal aggregates. , 1996, Applied optics.

[49]  H. Bockhorn,et al.  Assessment of soot volume fractions from laser-induced incancescence by comparison with extinction measurements in laminar, premixed, flat flames , 1996 .

[50]  Michael G. Littman,et al.  Comparative study of soot formation on the centerline of axisymmetric laminar diffusion flames: Fuel and temperature effects , 1987 .

[51]  M. Aldén,et al.  Soot-visualization strategies using laser techniques , 1995 .

[52]  Christof Schulz,et al.  Laser-induced incandescence for soot diagnostics at high pressures. , 2003, Applied optics.

[53]  J. Steinfeld,et al.  Fluorescence excitation and emission spectra of polycyclic aromatic hydrocarbons at flame temperatures , 1980 .

[54]  F. Cignoli,et al.  Simultaneous one-dimensional visualization of OH, polycyclic aromatic hydrocarbons, and soot in a laminar diffusion flame. , 1992, Optics letters.

[55]  Fengshan Liu,et al.  Effects of primary soot particle size distribution on the temperature of soot particles heated by a nanosecond pulsed laser in an atmospheric laminar diffusion flame , 2006 .

[56]  R. L. Wal Soot Precursor Material: Visualization Via Simultaneous LIF-LII and Characterization Via TEM , 1996 .

[57]  M. Mishchenko,et al.  Efficient finite-difference time-domain scheme for light scattering by dielectric particles: application to aerosols. , 2000, Applied optics.

[58]  A. F. Sarofim,et al.  Optical Constants of Soot and Their Application to Heat-Flux Calculations , 1969 .

[59]  D. Dietrich,et al.  Laser-induced incandescence applied to droplet combustion. , 1995, Applied optics.

[60]  Paul Roth,et al.  In-cylinder sizing of diesel particles by time-resolved laser-induced incandescence (TR-LII) , 2002 .

[61]  C. Sorensen Light Scattering by Fractal Aggregates: A Review , 2001 .

[62]  Alan C. Eckbreth,et al.  Effects of laser-modulated particulate incandescence on Raman scattering diagnostics , 1977 .

[63]  H. Bladh,et al.  Experimental and theoretical comparison of spatially resolved laser-induced incandescence (LII) signals of soot in backward and right-angle configuration , 2006 .

[64]  Ümit Özgür Köylü,et al.  Computational Evaluation of Approximate Rayleigh–Debye–Gans/Fractal-Aggregate Theory for the Absorption and Scattering Properties of Soot , 1995 .

[65]  Takashi Kashiwagi,et al.  Comparisons of the soot volume fraction using gravimetric and light extinction techniques , 1995 .

[66]  Robert A. Fletcher,et al.  The evolution of soot precursor particles in a diffusion flame , 1998 .

[67]  Kirk A. Fuller,et al.  Light Scattering by Agglomerates: Coupled Electric and Magnetic Dipole Method , 1994 .

[68]  A. Leipertz,et al.  Two-dimensional soot-particle sizing by time-resolved laser-induced incandescence. , 1995, Optics letters.

[69]  C. Y. Cha,et al.  Transport phenomena in the rarefied gas transition regime , 1974 .

[70]  A. Doicu,et al.  Null-field method with discrete sources to electromagnetic scattering from composite objects , 2001 .

[71]  M. Aigner,et al.  Investigation of laminar pressurized flames for soot model validation using SV-CARS and LII , 2005 .

[72]  P. Roth,et al.  High temperature oxidation of suspended soot particles verified by CO and CO2 measurements , 1991 .

[73]  W. Duley,et al.  Aerosol‐particle sizes from light emission during excitation by TEA CO2 laser pulses , 1974 .

[74]  C. Kittel Introduction to solid state physics , 1954 .

[75]  M. Choi,et al.  Calibration and correction of laser-induced incandescence for soot volume fraction measurements , 1998 .

[76]  H. Horvath,et al.  UV-VIS-NIR spectral optical properties of soot and soot-containing aerosols , 2003 .

[77]  Robert J. Santoro,et al.  Soot particle measurements in diffusion flames , 1983 .

[78]  F. Beretta,et al.  Time Resolved Laser Induced Incandescence for Soot and Cenospheres Measurements in Oil Flames , 2000 .

[79]  Nelson P. Bryner,et al.  Comparison of a fractal smoke optics model with light extinction measurements , 1994 .

[80]  P. Roth,et al.  Comparison of LII and TEM sizing during synthesis of iron particle chains , 2005 .

[81]  D. E. Rosner,et al.  LII analysis of aggregate size distributions at high pressures , 1999 .

[82]  C. Dasch Continuous-wave probe laser investigation of laser vaporization of small soot particles in a flame. , 1984, Applied optics.

[83]  P. Roth,et al.  In-situ characterization of ultrafine particles by laser-induced incandescence , 1999 .

[84]  Ömer L. Gülder,et al.  Clouds over Soot Evaporation: Errors in Modeling Laser-Induced Incandescence of Soot , 2001 .

[85]  H. Michelsen Laser-induced incandescence of flame-generated soot on a picosecond time scale , 2006 .

[86]  A. Leipertz,et al.  Performance characteristics of soot primary particle size measurements by time-resolved laser-induced incandescence. , 1998, Applied optics.

[87]  Stephan Schraml,et al.  Soot temperature measurements and implications for time-resolved laser-induced incandescence (TIRE-LII) , 2000 .

[88]  G. Mulholland,et al.  Coupled dipole calculation of extinction coefficient and polarization ratio for smoke agglomerates , 1999 .

[89]  P. Roth,et al.  Nano-particle sizing by laser-induced-incandescence (LII) in a shock wave reactor , 2003 .

[90]  D. Young,et al.  Thermodynamic properties of carbon up to the critical point , 1973 .

[91]  Randy L. Vander Wal,et al.  Can soot primary particle size be determined using laser-induced incandescence? , 1999 .

[92]  N. Ladommatos,et al.  Quantitative investigation of soot distribution by laser-induced incandescence. , 2000, Applied optics.

[93]  L. Ganippa,et al.  Laser-induced incandescence particle size measurements in a heavy-duty diesel engine , 2006 .

[94]  M. Aigner,et al.  Comparison of laser-induced incandescence method with scanning mobility particle sizer technique: the influence of probe sampling and laser heating on soot particle size distribution , 2005 .

[95]  S. Will,et al.  Comprehensive two-dimensional soot diagnostics based on laser-induced incandescence (LII) , 1996 .

[96]  L. Petarca,et al.  Fluorescence spectra and polycyclic aromatic species in a N-heptane diffusion flame , 1989 .

[97]  E. Therssen,et al.  Two-color laser-induced incandescence and cavity ring-down spectroscopy for sensitive and quantitative imaging of soot and PAHs in flames , 2004 .

[98]  R. L. Wal Laser-induced incandescence: detection issues. , 1996 .

[99]  R. V. Vander Wal,et al.  Laser-induced incandescence: excitation intensity. , 1998, Applied optics.

[100]  F. Fetting,et al.  Untersuchung der Bildung und des Wachstums von Rußteilchen in vorgemischten Kohlenwasserstoff – Sauerstoff Unterdruckflammen , 1987 .

[101]  P. Bengtsson,et al.  Laser-induced incandescence for soot particle size measurements in premixed flat flames. , 2000, Applied optics.

[102]  P. Bengtsson,et al.  Laser-induced incandescence for soot particle size and volume fraction measurements using on-line extinction calibration , 2001 .

[103]  Sivaram Arepalli,et al.  Spectral measurements in production of single-wall carbon nanotubes by laser ablation , 1999 .

[104]  D. Greenhalgh,et al.  Laser induced incandescence under high vacuum conditions , 2006 .

[105]  M. Aigner,et al.  LASER-BASED INVESTIGATION OF SOOT FORMATION IN LAMINAR PREMIXED FLAMES AT ATMOSPHERIC AND ELEVATED PRESSURES , 2005 .

[106]  P. Andreussi,et al.  BOUNDARY-LAYER BURNING OF FUEL SURFACES - THE SOOT FIELD , 1986 .

[107]  R. L. Wal,et al.  Simultaneous laser-induced emission of soot and polycyclic aromatic hydrocarbons within a gas-jet diffusion flame , 1997 .

[108]  H. Bockhorn,et al.  Two-dimensional imaging of soot volume fractions, particle number densities and particle radii in laminar and turbulent diffusion flames , 1998 .

[109]  W. Bachalo,et al.  A calibration-independent laser-induced incandescence technique for soot measurement by detecting absolute light intensity. , 2005, Applied optics.

[110]  L. Ganippa,et al.  On particulate characterization in a heavy-duty diesel engine by time-resolved laser-induced incandescence , 2006 .

[111]  R. Santoro,et al.  Two-dimensional imaging of soot volume fraction by the use of laser-induced incandescence. , 1995, Applied optics.

[112]  C. Allouis,et al.  Sizing soot and micronic carbonaceous particle in spray flames based on time resolved LII , 2003 .

[113]  H. Bockhorn,et al.  Size distributions of nanoscaled particles and gas temperatures from time-resolved laser-induced-incandescence measurements. , 2003, Applied optics.

[114]  D. E. Rosner,et al.  Energy transfer between an aerosol particle and gas at high temperature ratios in the Knudsen transition regime , 2000 .

[115]  Fengshan Liu,et al.  Laser induced incandescence measurements of soot volume fraction and effective particle size in a laminar co-annular non-premixed methane/air flame at pressures between 0.5–4.0 MPa , 2006 .

[116]  H. Bockhorn,et al.  Influence of the temporal response of the detection system on time-resolved laser-induced incandescence signal evolutions , 2006 .

[117]  F. Beretta,et al.  Depletion of fuel aromatic components and formation of aromatic species in a spray flame as characterized by fluorescence spectroscopy , 2001 .

[118]  P. Roth,et al.  In situ ultrafine particle sizing by a combination of pulsed laser heatup and particle thermal emission , 1996 .

[119]  David B. Geohegan,et al.  In situ imaging and spectroscopy of single-wall carbon nanotube synthesis by laser vaporization , 2000 .

[120]  Eric A. Rohlfing,et al.  Optical emission studies of atomic, molecular, and particulate carbon produced from a laser vaporization cluster source , 1988 .

[121]  C. L. Tien,et al.  Optical constants of soot in hydrocarbon flames , 1981 .

[122]  T. T. Charalampopoulos,et al.  Refractive indices of pyrolytic graphite, amorphous carbon, and flame soot in the temperature range 25° to 600°C☆ , 1993 .

[123]  R. Fraser,et al.  Spectrally Resolved Measurement of Flame Radiation to Determine Soot Temperature and Concentration , 2002 .