Technology Trends in Biodegradable Polymers: Evidence from Patent Analysis

ABSTRACT The public and governmental awareness regarding more sustainable products have gained significant momentum in the last decade and are directing the future research of the next generation of materials and processes. In such a setting, biodegradable polymers are regarded as one of the technologies driving the innovation and current market growth because they provide an additional end of life option. Tracing the evolving trends of these emerging technologies will help researchers, investors, and policy makers to better evaluate the opportunities of the technology as well as to understand the technology's changing characteristics. Therefore, within this study, we perform bibliographic analyses based on patent information to delineate the current research landscape and to anticipate the future development trends by focusing on the cases of poly(lactic acid) (PLA), poly(hydroxyalkanoates) (PHAs), polycaprolactone (PCL), poly(butylene succinate) (PBS), and poly(butylene adipate-co-terephthalate) (PBAT). The following findings were made: First, PLA gets the highest attention from both academia and industry. Second, the overall international presence of biodegradable polymer patents is high, especially in the field of PHAs. Third, technology maturity and technology strength show that PLA is the most promising technology at present in technological terms, whereas PHAs, PCL, and PBS are uncertain technologies and PBAT has a rather low development potential.

[1]  Janghyeok Yoon,et al.  Tracing evolving trends in printed electronics using patent information , 2014, Journal of Nanoparticle Research.

[2]  T. Fukui,et al.  Biosynthesis of polyhydroxyalkanoate copolymers from methanol by Methylobacterium extorquens AM1 and the engineered strains under cobalt-deficient conditions , 2014, Applied Microbiology and Biotechnology.

[3]  Xiaodong Wang,et al.  Poly(ε-caprolactone) nanofibers with a self-induced nanohybrid shish-kebab structure mimicking collagen fibrils. , 2013, Biomacromolecules.

[4]  A. Stipanovic,et al.  Enhanced production of polyhydroxyalkanoates (PHAs) from beechwood xylan by recombinant Escherichia coli , 2013, Applied Microbiology and Biotechnology.

[5]  Hailong Liu,et al.  Improving polyhydroxyalkanoate production by knocking out the genes involved in exopolysaccharide biosynthesis in Haloferax mediterranei , 2013, Applied Microbiology and Biotechnology.

[6]  E. Sivaniah,et al.  New insights into activation and substrate recognition of polyhydroxyalkanoate synthase from Ralstonia eutropha , 2013, Applied Microbiology and Biotechnology.

[7]  Chao-Chan Wu,et al.  Technology exploration and forecasting of biofuels and biohydrogen energy from patent analysis , 2012 .

[8]  Z. Ishak,et al.  Biodegradability studies of poly(butylene succinate)/organo-montmorillonite nanocomposites under controlled compost soil conditions: Effects of clay loading and compatibiliser , 2012 .

[9]  Amy J. C. Trappey,et al.  A patent quality analysis for innovative technology and product development , 2012, Adv. Eng. Informatics.

[10]  Janghyeok Yoon,et al.  Detecting signals of new technological opportunities using semantic patent analysis and outlier detection , 2012, Scientometrics.

[11]  Janghyeok Yoon,et al.  Identifying patent infringement using SAO based semantic technological similarities , 2012, Scientometrics.

[12]  Guoqiang Chen,et al.  Biosynthesis and characterization of poly(3-hydroxydodecanoate) by β-oxidation inhibited mutant of Pseudomonas entomophila L48. , 2011, Biomacromolecules.

[13]  Jiyeon Ryu,et al.  Technology level evaluation methodology based on the technology growth curve , 2011 .

[14]  Kwangsoo Kim,et al.  Identifying rapidly evolving technological trends for R&D planning using SAO-based semantic patent networks , 2011, Scientometrics.

[15]  C. Pillai,et al.  Biodegradable Polymers- A Review on Recent Trends and Emerging Perspectives , 2011 .

[16]  Yuta Saito,et al.  Molecular weight change of polyhydroxyalkanoate (PHA) caused by the PhaC subunit of PHA synthase from Bacillus cereus YB-4 in recombinant Escherichia coli. , 2011, Biomacromolecules.

[17]  H. Ernst,et al.  The Patent Asset Index - A new approach to benchmark patent portfolios , 2011 .

[18]  K. Sudesh,et al.  Synthesis of polyhydroxyalkanoate from palm oil and some new applications , 2011, Applied Microbiology and Biotechnology.

[19]  Andreas Künkel,et al.  Ecoflex® and Ecovio®: Biodegradable, Performance-Enabling Plastics , 2011 .

[20]  Guo-qiang Chen,et al.  Microbial production of polyhydroxyalkanoate block copolymer by recombinant Pseudomonas putida , 2011, Applied Microbiology and Biotechnology.

[21]  E. Chiellini,et al.  Oxidation and biodegradation of polyethylene films containing pro-oxidant additives: Synergistic effects of sunlight exposure, thermal aging and fungal biodegradation , 2010 .

[22]  A. Albertsson,et al.  Polylactide stereocomplexation leads to higher hydrolytic stability but more acidic hydrolysis product pattern. , 2010, Biomacromolecules.

[23]  Koji Kobayashi,et al.  Microbial degradation of poly(butylene succinate) by Fusarium solani in soil environments , 2010 .

[24]  R. Auras,et al.  Atmospheric and soil degradation of aliphatic–aromatic polyester films , 2010 .

[25]  Antonio U. B. Queiroz,et al.  Innovation and Industrial Trends in Bioplastics , 2009 .

[26]  I. Vroman,et al.  Biodegradable Polymers , 2009, Materials.

[27]  C. Moore Synthetic polymers in the marine environment: a rapidly increasing, long-term threat. , 2008, Environmental research.

[28]  Kumar Sudesh,et al.  Sustainability of Biobased and Biodegradable Plastics , 2008 .

[29]  Jöns Hilborn,et al.  Poly(lactic acid) fiber : An overview , 2007 .

[30]  Mu-Hsuan Huang,et al.  Using Essential Patent Index and Essential Technological Strength to evaluate industrial technological innovation competitiveness , 2007, Scientometrics.

[31]  Murat Bengisu,et al.  Forecasting emerging technologies with the aid of science and technology databases , 2006 .

[32]  N. Meade,et al.  Modelling and forecasting the diffusion of innovation – A 25-year review , 2006 .

[33]  Frank M. Bass,et al.  A New Product Growth for Model Consumer Durables , 2004, Manag. Sci..

[34]  Hélène Dernis,et al.  Triadic Patent Families Methodology , 2004 .

[35]  S. Ray,et al.  New poly(butylene succinate)/layered silicate nanocomposites. II. Effect of organically modified layered silicates on structure, properties, melt rheology, and biodegradability , 2003 .

[36]  Holger Ernst,et al.  Patent information for strategic technology management , 2003 .

[37]  Hua Yang,et al.  Biodegradable poly(epsilon-caprolactone)-poly(ethylene glycol) block copolymers: characterization and their use as drug carriers for a controlled delivery system. , 2003, Biomaterials.

[38]  K. Welzel Einfluss der chemischen Struktur auf die enzymatische Hydrolyse von Polyester-Nanopartikeln , 2003 .

[39]  E. Chiellini,et al.  Biodegradation of thermally-oxidized, fragmented low-density polyethylenes , 2003 .

[40]  D. Jendrossek Extracellular Polyhydroxyalkanoate (PHA) Depolymerases: The Key Enzymes of PHA Degradation , 2002 .

[41]  J. Derraik The pollution of the marine environment by plastic debris: a review. , 2002, Marine pollution bulletin.

[42]  K. Debackere,et al.  Measuring Progress and Evolution in Science and Technology - Ii: The Multiple Uses of Technometric Indicators , 2002 .

[43]  R. Müller Biodegradability of Polymers: Regulations and Methods for Testing , 2002 .

[44]  P. Gruber,et al.  Polylactic Acid Technology , 2000 .

[45]  J C Middleton,et al.  Synthetic biodegradable polymers as orthopedic devices. , 2000, Biomaterials.

[46]  Elke Marten Korrelationen zwischen der Struktur und der enzymatischen Hydrolyse von Polyestern , 2000 .

[47]  M. Okada,et al.  A catalytic approach for cationic living polymerization : Sc(OTf)3-Catalyzed ring-opening polymerization of lactones , 2000 .

[48]  I. Kleeberg Untersuchungen zum mikrobiellen Abbau von aliphatisch-aromatischen Copolyestern sowie Isolierung und Charakterisierung eines polyesterspaltenden Enzyms , 1999 .

[49]  Holger Ernst,et al.  Patent portfolios for strategic R & D planning , 1998 .

[50]  R. Nelson,et al.  The benefits and costs of strong patent protection: a contribution to the current debate , 1998 .

[51]  T. Fujimaki Processability and properties of aliphatic polyesters, ‘BIONOLLE’, synthesized by polycondensation reaction , 1998 .

[52]  W. Deckwer,et al.  Biodegradation behavior and material properties of aliphatic/aromatic polyesters of commercial importance , 1997 .

[53]  M. Trajtenberg,et al.  University Versus Corporate Patents: A Window On The Basicness Of Invention , 1997 .

[54]  A. Steinbüchel,et al.  Large-scale production of poly(3-hydroxyvaleric acid) by fermentation ofChromobacterium violaceum, processing, and characterization of the homopolyester , 1995 .

[55]  Hermann Simon,et al.  Management strategischer Wettbewerbsvorteile , 1995 .

[56]  F. Kawai Breakdown of plastics and polymers by microorganisms. , 1995, Advances in biochemical engineering/biotechnology.

[57]  Philip Hans Franses,et al.  A method to select between Gompertz and logistic trend curves , 1994 .

[58]  A. Anderson,et al.  Occurrence, metabolism, metabolic role, and industrial uses of bacterial polyhydroxyalkanoates. , 1990, Microbiological reviews.

[59]  F. Rombouts,et al.  Modeling of the Bacterial Growth Curve , 1990, Applied and environmental microbiology.

[60]  M. Trajtenberg A Penny for Your Quotes : Patent Citations and the Value of Innovations , 1990 .

[61]  E. V. Vleet,et al.  Marine birds and plastic pollution , 1987 .

[62]  K. Sakai,et al.  Degradation Mechanism of Poly(vinyl alcohol) by Successive Reactions of Secondary Alcohol Oxidase and β-Diketone Hydrolase from Pseudomonas sp. , 1986 .

[63]  Ariel Pakes,et al.  Estimates of the Value of Patent Rights in European Countries During Thepost-1950 Period , 1985 .

[64]  Tomoo Suzuki,et al.  Hydrolysis of Polyesters by Rhizopus delemar Lipase , 1978 .