Preparation of nanocapsules containing the two-phase core materials

In this study, copolymer nanocapsules containing the two-phase core materials were prepared by mini-emulsion polymerization using styrene (St) and methylmethacrylate (MMA) as comonomer, in which the ZnO nanoparticles organic suspension was prepared by solvothermal synthesis method. The obtained materials were characterized by dynamic light scattering (DLS), transmission electron microscopy (TEM), atomic force microscopy (AFM), UV-visible spectrophotometry and fluorescence spectrometer. The particle size of the prepared ZnO nanoparticles dispersed in the organic solvent was less than 20 nm. The resulting polymer nanocapsules have 100–200 nm in diameter and ∼ 10–20 nm in the wall thickness. The surface of the polymer nanocapsules is smooth and clear.

[1]  Y. Lou,et al.  Core-shell gold nanoparticle assembly as novel electrocatalyst of CO oxidation , 2000 .

[2]  Xiaopeng Zhao,et al.  Preparation of a kind of red encapsulated electrophoretic ink , 2004 .

[3]  M. Nethaji,et al.  Synthesis of a self-assembled molecular capsule that traps pyridine molecules by a combination of hydrogen bonding and copper(II) coordination. , 2003, Angewandte Chemie.

[4]  I. Dékány,et al.  Synthesis of ZnO nanoparticles on a clay mineral surface in dimethyl sulfoxide medium. , 2004, Langmuir : the ACS journal of surfaces and colloids.

[5]  B. Cho,et al.  "Grafting-from" polymerization inside a polyelectrolyte hollow-capsule microreactor. , 2005, Angewandte Chemie.

[6]  Giovanni Luca,et al.  Production of lipospheres as carriers for bioactive compounds. , 2002, Biomaterials.

[7]  Thomas Kietzke,et al.  Novel approaches to polymer blends based on polymer nanoparticles , 2003, Nature materials.

[8]  T. Hyeon,et al.  Synthesis of Nanorattles Composed of Gold Nanoparticles Encapsulated in Mesoporous Carbon and Polymer Shells , 2002 .

[9]  Y. Kawashima,et al.  pH-sensitive microsphere delivery increases oral bioavailability of calcitonin. , 2004, Journal of controlled release : official journal of the Controlled Release Society.

[10]  T. Park,et al.  Comparative study on sustained release of human growth hormone from semi-crystalline poly(L-lactic acid) and amorphous poly(D,L-lactic-co-glycolic acid) microspheres: morphological effect on protein release. , 2004, Journal of controlled release : official journal of the Controlled Release Society.

[11]  J P Wang,et al.  The relation between narrow-dispersed microcapsules and surfactants , 2005, Journal of microencapsulation.

[12]  H. Möhwald,et al.  Gas-filled polyelectrolyte capsules. , 2005, Angewandte Chemie.

[13]  D. W. Wang,et al.  Electrophoretic ink using urea-formaldehyde microspheres , 2006, Journal of microencapsulation.

[14]  Xiaopeng Zhao,et al.  Preparation of microcapsules containing two-phase core materials. , 2004, Langmuir : the ACS journal of surfaces and colloids.

[15]  Younan Xia,et al.  Monodispersed Colloidal Spheres: Old Materials with New Applications , 2000 .

[16]  C. Graillat,et al.  Encapsulation of an organic phthalocyanine blue pigment into polystyrene latex particles using a miniemulsion polymerization process , 2003 .

[17]  강종석,et al.  소형입자 유화중합(Miniemulsion Polymerization)의 최근 연구동향 , 2005 .

[18]  M. Antonietti,et al.  Synthesis of Inorganic and Metallic Nanoparticles by Miniemulsification of Molten Salts and Metals , 2001 .

[19]  K. Landfester Miniemulsions for nanoparticle synthesis , 2003 .

[20]  A. Lützen Self-assembled molecular capsules--even more than nano-sized reaction vessels. , 2005, Angewandte Chemie.

[21]  K. Klabunde,et al.  Synthesis, Isolation, and Chemical Reactivity Studies of Nanocrystalline Zinc Oxide , 2000 .

[22]  Yingwu Luo,et al.  Nanoencapsulation of a hydrophobic compound by a miniemulsion polymerization process , 2004 .

[23]  Sung‐Ho Kim,et al.  Development of a polymeric nanoparticulate drug delivery system. In vitro characterization of nanoparticles based on sugar-containing conjugates. , 2002, International journal of pharmaceutics.

[24]  M. Iso,et al.  Synthesis of uniform PMMA microspheres employing modified SPG (shirasu porous glass) emulsification technique , 1995 .

[25]  Markus Antonietti,et al.  Preparation of polymeric nanocapsules by miniemulsion polymerization. , 2001 .

[26]  Eunkyoung Kim,et al.  Preparation and optical properties of polystyrene nanocapsules containing photochromophores , 2003 .

[27]  Xiaopeng Zhao,et al.  Synthesis of functional microcapsules containing suspensions responsive to electric fields. , 2005, Journal of colloid and interface science.