Effect of slow neutron radiation on the pre-exponential factor of thermally activated crystallization in Se96In4 chalcogenide glass

This paper reports the applicability of the inverse Meyer–Neldel rule between the pre-exponential factor and activation energy of non-isothermal crystallization of Se96In4 chalcogenide glass under the influence of slow neutron irradiation, for different exposure times. The change in the kinetic parameters of the crystallization (crystallization temperature Tc, rate of crystallization K, activation energy of crystallization Ec and order parameter n) is studied using a differential scanning calorimeter.

[1]  A. Kumar,et al.  Pre-exponential factor of Arrhenius equation for the isothermal crystallization of some Se–Ge, Se–In and Se–Te chalcogenide glasses , 2007 .

[2]  A. Kumar,et al.  Observation of compensation effect for isothermal crystallization in glassy Se80−xGe20Inx and Se78−xGe22Bix alloys , 2006 .

[3]  A. Kumar,et al.  Pre-exponential factor for the crystallization of some chalcogenide glasses: applicability of Meyer-Neldel rule , 2006 .

[4]  A. Kumar,et al.  Applicability of Meyer–Neldel rule for isothermal crystallization in glassy Se70Te30−xSbx alloys , 2006 .

[5]  D. Kumar,et al.  Investigation of compensation effect for isothermal crystallization in glassy Se80−xTe20Mx (M = Cd, Ge, Sb) alloys , 2005 .

[6]  P. Villares,et al.  A comparative study on the glass-forming ability of some alloys in the Sb–As–Se system by differential scanning calorimetry , 2005 .

[7]  J. Keinonen,et al.  Defect formation and annealing behavior of InP implanted by low-energy 15N ions , 1998 .

[8]  J. Dankovicová Czech , 1997, Journal of the International Phonetic Association.

[9]  F. Zhou,et al.  Nucleation and growth characteristics of amorphous FeSiB(Cu)(Nb) alloys during isothermal crystallization process , 1994 .

[10]  J. Šesták,et al.  Kinetic compensation effect as a mathematical consequence of the exponential rate constant , 1991 .

[11]  M. Clavaguera-Mora,et al.  Glass formation and crystallization kinetics of some GeSbSe glasses , 1990 .

[12]  M. Clavaguera-Mora,et al.  Crystallization kinetics of some Ge-Sb-Se glasses , 1988 .

[13]  B. Appleton,et al.  Chapter 2 ion-beam- and laser-induced surface modifications , 1985 .

[14]  M. Baró,et al.  Glass formation and crystallization in the GeSe2-Sb2Te3 system , 1984 .

[15]  H. Güntherodt,et al.  Glassy Metals I , 1981 .

[16]  Tatsuo Shimizu,et al.  Effects of annealing on gap states in amorphous Si films , 1978 .

[17]  J. Bennett,et al.  Calculation of the Avrami parameters for heterogeneous solid state reactions using a modification of the Kissinger method , 1978 .

[18]  H. Pinsler,et al.  Selenium crystallization induced by corotron charging , 1976 .

[19]  V. Halpern Localized electron states in the arsenic chalcogenides , 1976 .

[20]  A. Holmes-Siedle Radiation sensitivity and amorphous materials-present and future , 1974 .

[21]  A. Hrubý Evaluation of glass-forming tendency by means of DTA , 1972 .

[22]  P. Fang A model of Meyer-Neldel rule , 1969 .

[23]  M. Avrami Kinetics of Phase Change. II Transformation‐Time Relations for Random Distribution of Nuclei , 1940 .

[24]  M. Avrami Kinetics of Phase Change. I General Theory , 1939 .