DIRECT PHOTO-DEPOSITION OF SILICON DIOXIDE FILMS USING A XENON EXCIMER LAMP

Abstract Recently excimer lamps have opened up the field of intense vacuum ultra-violet (VUV) light generation. With theoretical efficiencies reaching 40%, the power available from such lamps based on dielectric barrier discharge generation can be superior to those of typical low pressure mercury lamps with shorter UV wavelengths generated. Here we present, for the first time, the use of these lamps for the direct photo-deposition of silicon dioxide from silane and nitrous oxide mixtures. Deposition rates achieved on our unoptimised system are comparable with those obtained with low pressure mercury lamps. The results indicate promising further applications of such lamps towards semiconductor and optoelectronic materials processing.

[1]  Yoshio Tanaka Continuous Emission Spectra of Rare Gases in the Vacuum Ultraviolet Region , 1955 .

[2]  Ulrich Kogelschatz,et al.  UV excimer radiation from dielectric-barrier discharges , 1988 .

[3]  V. Nassisi Experimental studies of a XeCl laser having UV preionization perpendicular and parallel to the electrode surfaces , 1991 .

[4]  J. Gannon,et al.  Silver‐Manganese Evaporated Ohmic Contacts to p‐type Gallium Arsenide , 1968 .

[5]  Ian W. Boyd,et al.  A study of thin silicon dioxide films using infrared absorption techniques , 1982 .

[6]  Ian W. Boyd,et al.  Silicon‐silicon dioxide interface: An infrared study , 1987 .

[7]  J. K. Srivastava,et al.  Low‐temperature growth of silicon dioxide films: A study of chemical bonding by ellipsometry and infrared spectroscopy , 1987 .

[8]  Baldur Eliasson,et al.  Investigation of resonance and excimer radiation from a dielectric barrier discharge in mixtures of mercury and the rare gases , 1990 .

[9]  C. Vinckier,et al.  Yields of the plasma oxidation of silicon by neutral oxygen-atoms and negative oxygen atom ions , 1990 .

[10]  Ulrich Kogelschatz,et al.  Investigation of the mechanism of the UV-induced palladium deposition process from thin solid palladium acetate films , 1990 .

[11]  B. Eliasson,et al.  Ozone Generation with Narrow–Band UV Radiation , 1991 .

[12]  J. Stathis,et al.  Trapped positive charge in plasma‐enhanced chemical vapor deposited silicon dioxide films , 1990 .

[13]  R. Gordon,et al.  Kinetic Modeling of the Chemical Vapor Deposition of Silicon Dioxide from Silane or Disilane and Nitrous Oxide , 1990 .

[14]  C. Licoppe,et al.  Photo-assisted deposition of thin films on III–V semiconductors with UV and IR lamps , 1990 .

[15]  Ian W. Boyd,et al.  Low temperature VUV enhanced growth of thin silicon dioxide films , 1990 .

[16]  J. Perrin,et al.  SiO2 deposition by direct photolysis at 185 nm of N2O and SiH4 , 1990 .

[17]  Ulrich Kogelschatz,et al.  Generation of excimer emission in dielectric barrier discharges , 1991 .

[18]  Ulrich Kogelschatz,et al.  Silent-discharge driven excimer UV sources and their applications , 1992 .

[19]  D. Lile,et al.  Surface characterization of InP using photoluminescence , 1987 .

[20]  D. Lorents,et al.  Characteristics of electron‐beam‐excited Xe*2 at low pressures as a vacuum ultraviolet source , 1988 .

[21]  Paul J. Crutzen,et al.  Evaluated Kinetic and Photochemical Data for Atmospheric Chemistry: Supplement I CODATA Task Group on Chemical Kinetics , 1982 .