Carbon monoxide total column retrievals from TROPOMI shortwave infrared measurements

Abstract. The Tropospheric Monitoring Instrument (TROPOMI) spectrometer is the single payload of the Copernicus Sentinel 5 Precursor (S5P) mission. It measures Earth radiance spectra in the shortwave infrared spectral range around 2.3 µm with a dedicated instrument module. These measurements provide carbon monoxide (CO) total column densities over land, which for clear sky conditions are highly sensitive to the tropospheric boundary layer. For cloudy atmospheres over land and ocean, the column sensitivity changes according to the light path through the atmosphere. In this study, we present the physics-based operational S5P algorithm to infer atmospheric CO columns satisfying the envisaged accuracy (

[1]  M. Buchwitz,et al.  Three years of global carbon monoxide from SCIAMACHY: comparison with MOPITT and first results related to the detection of enhanced CO over cities , 2007 .

[2]  H. Levy Normal Atmosphere: Large Radical and Formaldehyde Concentrations Predicted , 1971, Science.

[3]  J. Lamarque,et al.  Observations of carbon monoxide and aerosols from the Terra satellite: Northern Hemisphere variability , 2004 .

[4]  Gang Li,et al.  The HITRAN 2008 molecular spectroscopic database , 2005 .

[5]  E. Ustinov Inverse problem of photometric observation of solar radiation reflected by an optically dense planetary atmosphere. Mathematical methods and weighting functions of linearized inverse problem. , 1992 .

[6]  Masakatsu Nakajima,et al.  Thermal and near infrared sensor for carbon observation Fourier-transform spectrometer on the Greenhouse Gases Observing Satellite for greenhouse gases monitoring. , 2009, Applied optics.

[7]  J. Landgraf,et al.  Linearization of a radiative transfer model in spherical geometry , 2006 .

[8]  Peter Bergamaschi,et al.  Inverse modelling of national and European CH4 emissions using the atmospheric zoom model TM5 , 2005 .

[9]  Ilse Aben,et al.  CH4 retrievals from space‐based solar backscatter measurements: Performance evaluation against simulated aerosol and cirrus loaded scenes , 2010 .

[10]  D. Winker,et al.  Initial performance assessment of CALIOP , 2007 .

[11]  Ilse Aben,et al.  Uncertainties in the space-based measurements of CO2 columns due to scattering in the Earth's atmosphere , 2007 .

[12]  O. Hasekamp,et al.  Accurate modeling of spectral fine-structure in Earth radiance spectra measured with the Global Ozone Monitoring Experiment. , 2007, Applied optics.

[13]  J. Hovenier,et al.  Global distributions of effective cloud fraction and cloud top pressure derived from oxygen A band spectra measured by the Global Ozone Monitoring Experiment: Comparison to ISCCP data , 2002 .

[14]  J. F. Meirink,et al.  Inverse Modeling of Global and Regional CH4 Emissions Using SCIAMACHY Satellite Retrievals , 2009 .

[15]  M. Buchwitz,et al.  SCIAMACHY: Mission Objectives and Measurement Modes , 1999 .

[16]  O. P. Hasekamp,et al.  A linearized vector radiative transfer model for atmospheric trace gas retrieval , 2002 .

[17]  D. Gesch,et al.  Global multi-resolution terrain elevation data 2010 (GMTED2010) , 2011 .

[18]  Karen E. Cady-Pereira,et al.  Uncertainties in atmospheric surface pressure fields from global analyses , 2008 .

[19]  O. Hasekamp,et al.  Linearization of radiative transfer with respect to surface properties , 2002 .

[20]  Otto P. Hasekamp,et al.  LINTRAN v2.0: A linearised vector radiative transfer model for efficient simulation of satellite-born nadir-viewing reflection measurements of cloudy atmospheres , 2014 .

[21]  Otto P. Hasekamp,et al.  Insights into Tikhonov regularization: application to trace gas column retrieval and the efficient calculation of total column averaging kernels , 2014 .

[22]  T. Borsdorff,et al.  The direct fitting approach for total ozone column retrievals: a sensitivity study on GOME-2/MetOp-A measurements , 2015 .

[23]  E. Vermote,et al.  The MODIS Aerosol Algorithm, Products, and Validation , 2005 .

[24]  Thomas Trautmann,et al.  A linearized radiative transfer model for ozone profile retrieval using the analytical forward-adjoint perturbation theory approach , 2001 .

[25]  V. Malathy Devi,et al.  Multispectrum analysis of 12CH4 from 4100 to 4635 cm−1: 1. Self-broadening coefficients (widths and shifts) , 2005 .

[26]  Stefan Noel,et al.  Quantification and mitigation of the impact of scene inhomogeneity on Sentinel-4 UVN UV-VIS retrievals , 2012 .

[27]  Vijay Natraj,et al.  A linearized two-stream radiative transfer code for fast approximation of multiple-scatter fields , 2011 .

[28]  Haili Hu,et al.  HDO and H 2 O total column retrievals from TROPOMI shortwave infrared measurements , 2016 .

[29]  Ilse Aben,et al.  Atmospheric Chemistry and Physics Sciamachy Co over Land and Oceans: 2003–2007 Interannual Variability , 2022 .

[30]  Merritt N. Deeter,et al.  CO retrievals based on MOPITT near-infrared observations , 2009 .

[31]  Ilse Aben,et al.  Improved water vapour spectroscopy in the 4174-4300 cm-1 region and its impact on SCIAMACHY HDO/H2O measurements , 2012 .

[32]  O. Hasekamp,et al.  Error analysis for CO and CH 4 total column retrievals from SCIAMACHY 2.3 μm spectra , 2008 .

[33]  Ilse Aben,et al.  Methane retrievals from Greenhouse Gases Observing Satellite (GOSAT) shortwave infrared measurements: Performance comparison of proxy and physics retrieval algorithms , 2012 .

[34]  S. Wofsy,et al.  Tropospheric chemistry: A global perspective , 1981 .

[35]  O. Hasekamp,et al.  Retrieval of cloud parameters from satellite‐based reflectance measurements in the ultraviolet and the oxygen A‐band , 2007 .

[36]  Akihiko Kuze,et al.  Toward accurate CO2 and CH4 observations from GOSAT , 2011 .

[37]  David A. Seal,et al.  The Shuttle Radar Topography Mission , 2007 .

[38]  Piet Stammes,et al.  Scattering matrices of imperfect hexagonal ice crystals , 1998 .

[39]  Otto P. Hasekamp,et al.  Linearization of a pseudo-spherical vector radiative transfer model , 2004 .

[40]  Philippe Bousquet,et al.  Sensitivity of the recent methane budget to LMDz sub-grid-scale physical parameterizations , 2015 .

[41]  David L. Phillips,et al.  A Technique for the Numerical Solution of Certain Integral Equations of the First Kind , 1962, JACM.

[42]  T. Borsdorff,et al.  Carbon monoxide total columns from SCIAMACHY 2.3 µm atmospheric reflectance measurements: towards a full-mission data product (2003–2012) , 2015 .

[43]  Ilse Aben,et al.  TROPOMI aboard Sentinel-5 Precursor: Prospective performance of CH4 retrievals for aerosol and cirrus loaded atmospheres , 2012 .

[44]  Peter Bergamaschi,et al.  European Geosciences Union Atmospheric Chemistry and Physics , 2005 .

[45]  Peter Bergamaschi,et al.  A multi-year methane inversion using SCIAMACHY, accounting for systematic errors using TCCON measurements , 2013 .

[46]  Ulrich Platt,et al.  Retrieval of CO from SCIAMACHY onboard ENVISAT : detection of strongly polluted areas and seasonal patterns in global CO abundances , 2017 .

[47]  G. Lichtenberg,et al.  Near infrared nadir retrieval of vertical column densities: methodology and application to SCIAMACHY , 2011 .

[48]  M. Wiegner,et al.  COP: a data library of optical properties of hexagonal ice crystals. , 1994, Applied optics.

[49]  Peter Bergamaschi,et al.  Atmospheric carbon gases retrieved from SCIAMACHY by WFM-DOAS: version 0.5 CO and CH 4 and impact of calibration improvements on CO 2 retrieval , 2006 .

[50]  Henk Eskes,et al.  TROPOMI on the ESA Sentinel-5 Precursor: A GMES mission for global observations of the atmospheric composition for climate, air quality and ozone layer applications , 2012 .

[51]  Ilse Aben,et al.  Retrievals of atmospheric CO2 from simulated space-borne measurements of backscattered near-infrared sunlight: accounting for aerosol effects. , 2009, Applied optics.

[52]  W. Weaver,et al.  Two-Stream Approximations to Radiative Transfer in Planetary Atmospheres: A Unified Description of Existing Methods and a New Improvement , 1980 .

[53]  Alexander Marshak,et al.  The verisimilitude of the independent pixel approximation used in cloud remote sensing , 1995 .

[54]  Ilse Aben,et al.  Carbon monoxide from shortwave infrared reflectance measurements: A new retrieval approach for clear sky and partially cloudy atmospheres , 2012 .

[55]  J. Drummond,et al.  The Measurements of Pollution in the Troposphere (MOPITT) Instrument: Overall Performance and Calibration Requirements , 1996 .

[56]  Richard G. Derwent,et al.  Multimodel simulations of carbon monoxide: Comparison with observations and projected near‐future changes , 2006 .

[57]  O. Boucher,et al.  The aerosol-climate model ECHAM5-HAM , 2004 .