Influence of various wood modifications on the properties of polyvinyl chloride/wood flour composites

Aminosilane, melamine and acetic anhydride treated wood flour were added to polyvinyl chloride (PVC) in order to process improved PVC/wood flour composites. The influence of wood treatment on water absorption and mechanical properties were evaluated. Treatments with amino-alkyl functional oligomeric siloxane and melamine in suitable concentration as well as acetylated wood flour composites showed decreased equilibrium moisture content and reduced speed of water absorption. Tensile strength, elongation at break and unnotched impact strength were considerably improved by the aminosilane treatments. The increase in strength and elongation was mainly influenced by the chemical structure and concentration of the used aminosilanes. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012

[1]  Michael P. Wolcott,et al.  Effects of processing method and fiber size on the structure and properties of wood-plastic composites , 2009 .

[2]  A. Klyosov,et al.  Wood-Plastic Composites , 2007 .

[3]  Chul B. Park,et al.  Surface characteristics of chemically modified newsprint fibers determined by inverse gas chromatography , 2007 .

[4]  Michael P. Wolcott,et al.  Opportunities for wood/natural fiber-plastic composites in residential and industrial applications , 2006 .

[5]  Laurent M. Matuana,et al.  Novel coupling agents for PVC/wood‐flour composites * , 2005 .

[6]  N. Sombatsompop,et al.  Average mixing torque, tensile and impact properties, and thermal stability of poly(vinyl chloride)/sawdust composites with different silane coupling agents , 2005 .

[7]  C. Mai,et al.  Wood modification with alkoxysilanes , 2004, Wood Science and Technology.

[8]  Haihong Jiang,et al.  Development of poly(vinyl chloride)/wood composites. A literature review , 2004 .

[9]  C. Hill,et al.  The use of organo alkoxysilane coupling agents for wood preservation , 2004 .

[10]  G. Michler,et al.  Modified polypropylene wood flour composites. II. Fracture, deformation, and mechanical properties , 2004 .

[11]  R. Wimmer,et al.  Impregnation of softwood cell walls with melamine-formaldehyde resin. , 2003, Bioresource technology.

[12]  D. Lukowsky Influence of the formaldehyde content of waterbased melamine formaldehyde resins on physical properties of Scots pine impregnated therewith , 2002, Holz als Roh- und Werkstoff.

[13]  M. Wålinder,et al.  Acid–base characterization of wood and selected thermoplastics , 2002 .

[14]  Craig Clemons,et al.  Wood-plastic composites in the United States: the interfacing of two industries , 2002 .

[15]  M. Brook,et al.  Hydrophobization of wood surfaces: covalent grafting of silicone polymers , 2001, Wood Science and Technology.

[16]  P. Larsson Brelid,et al.  Resistance of acetylated wood to biological degradation , 2000, Holz als Roh- und Werkstoff.

[17]  J. Balatinecz,et al.  X-ray photoelectron spectroscopy study of silane-treated newsprint-fibers , 1999, Wood Science and Technology.

[18]  W. Adam,et al.  Electron Energy Loss Spectroscopy (EELS) for Quantification of Cell-Wall Penetration of a Melamine Resin , 1999 .

[19]  A. Błędzki,et al.  Thermoplastics Reinforced with Wood Fillers: A Literature Review , 1998 .

[20]  Chul B. Park,et al.  Influence of interfacial interactions on the properties of PVC/cellulosic fiber composites , 1998 .

[21]  Chul B. Park,et al.  Effect of surface properties on the adhesion between PVC and wood veneer laminates , 1998 .

[22]  F. Jones,et al.  Recent studies of self-condensation and co-condensation of melamine-formaldehyde resins; cure at low temperatures , 1994 .

[23]  F. Chung Unified theory and guidelines on adhesion , 1991 .

[24]  B. Kokta,et al.  Composites of polyvinyl chloride–wood fibers. III: Effect of silane as coupling agent , 1990 .

[25]  R. Rowell,et al.  Dimensional stability, decay resistance, and mechanical properties of veneer-faced low-density particleboards made from acetylated wood , 1989 .