Synthesis of a uranium(VI)-carbene: reductive formation of uranyl(V)-methanides, oxidative preparation of a [R2C═U═O]2+ analogue of the [O═U═O]2+ uranyl ion (R = Ph2PNSiMe3), and comparison of the nature of U(IV)═C, U(V)═C, and U(VI)═C double bonds.
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A. J. Blake | F. Tuna | E. McInnes | A. Blake | W. Lewis | F. Moro | E. Davies | J. McMaster | S. Liddle | D. Mills | O. Cooper | Oliver J. Cooper | D. P. Mills