Recovery of nano-Al2O3 from waste aluminum electrolytic solution generated during the manufacturing of capacitors

AbstractThe purpose of this study was to develop a resource recovery procedure for recovering nano-Al2O3 from the waste aluminum electrolytic solution generated during the manufacturing of capacitors. The high concentrations aluminum contained in electrolytic solutions have a high resource potential and economic value. In this study, the co-precipitation method was used to recover the waste aluminum electrolytic solution. The results show that the purity and particle size of the recovered Al2O3 were 99.943% and 0.174 μm, similar with the commercial Al2O3 powder. Additionally, about 80% of the used ammonia could be recycled and reused in the reaction process. The processing technology presented in this work is thus feasible, and the application methods and economies of scale achievable with this approach are competitive and have commercial development value.

[1]  L. C. Nehru,et al.  Structural and phase transition of α-Al2O3 powders obtained by co-precipitation method , 2016 .

[2]  Zhenming Xu,et al.  Disposing and recycling waste printed circuit boards: disconnecting, resource recovery, and pollution control. , 2015, Environmental science & technology.

[3]  G. Demopoulos,et al.  Comparative molecular characterization of aluminum hydroxy‐gels derived from chloride and sulphate salts , 2014 .

[4]  M. S. Ghamsari,et al.  Facile route for preparation of highly crystalline γ-Al2O3 nanopowder , 2012 .

[5]  Wang Ming-jing Effect of creating hole corrosion process on the specific capacitance of capacitors anode foil , 2011 .

[6]  S. N. Ashrafizadeh,et al.  Removal of oily hydrocarbon contaminants from wastewater by γ-alumina nanofiltration membranes , 2010 .

[7]  G. Pugazhenthi,et al.  Comparative Study of Ultrasound Stimulation and Conventional Heating Methods on the Preparation of Nanosized γ-Al2O3 , 2010 .

[8]  K K Sahu,et al.  An overview of the recovery of acid from spent acidic solutions from steel and electroplating industries. , 2009, Journal of hazardous materials.

[9]  H. Park,et al.  Facile Route to Synthesize Large-Mesoporous γ-Alumina by Room Temperature Ionic Liquids , 2007 .

[10]  R. Laine,et al.  Nano-α-Al2O3 by liquid-feed flame spray pyrolysis , 2006, Nature materials.

[11]  J. A. Kittrick,et al.  Relative Solubility of Corundum, Gibbsite, Boehmite, and Diaspore at Standard State Conditions , 1988 .