Self-Actuation of Liquid Metal via Redox Reaction.

Presented here is a method for actuating a gallium-based liquid-metal alloy without the need for an external power supply. Liquid metal is used as an anode to drive a complementary oxygen reduction reaction, resulting in the spontaneous growth of hydrophilic gallium oxide on the liquid-metal surface, which induces flow of the liquid metal into a channel. The extent and duration of the actuation are controllable throughout the process, and the induced flow is both reversible and repeatable. This self-actuation technique can also be used to trigger other electrokinetic or fluidic mechanisms.

[1]  Feng Xu,et al.  Liquid on Paper: Rapid Prototyping of Soft Functional Components for Paper Electronics , 2015, Scientific Reports.

[2]  Fu-Cheng Wang,et al.  Ultrahigh contrast light valve driven by electrocapillarity of liquid gallium , 2009 .

[3]  Michael D. Dickey,et al.  Emerging Applications of Liquid Metals Featuring Surface Oxides , 2014, ACS applied materials & interfaces.

[4]  Aaron T. Ohta,et al.  Rapid electrocapillary deformation of liquid metal with reversible shape retention , 2015 .

[5]  Xin-bo Zhang,et al.  Oxygen Electrocatalysts in Metal—Air Batteries: From Aqueous to Nonaqueous Electrolytes , 2015 .

[6]  Wenqi Hu,et al.  Continuous Electrowetting of Non-toxic Liquid Metal for RF Applications , 2014, IEEE Access.

[7]  Dimitrios Peroulis,et al.  A 12–18 GHz electrostatically tunable liquid metal RF MEMS resonator with quality factor of 1400–1840 , 2011, 2011 IEEE MTT-S International Microwave Symposium.

[8]  Jing Liu,et al.  Self‐Fueled Biomimetic Liquid Metal Mollusk , 2015, Advanced materials.

[9]  K. Kalantar-zadeh,et al.  Generation of catalytically active materials from a liquid metal precursor. , 2015, Chemical communications.

[10]  C. Kim,et al.  Surface-tension-driven microactuation based on continuous electrowetting , 2000, Journal of Microelectromechanical Systems.

[11]  S. Tang,et al.  Liquid metal enabled pump , 2014, Proceedings of the National Academy of Sciences.

[12]  Gregory H. Huff,et al.  Frequency reconfigurable patch antenna using liquid metal as switching mechanism , 2013 .

[13]  Jacob J. Adams,et al.  A reconfigurable liquid metal antenna driven by electrochemically controlled capillarity , 2015 .

[14]  Aaron T. Ohta,et al.  Liquid-Metal-Based Reconfigurable Components for RF Front Ends , 2015, IEEE Potentials.

[15]  Michael D. Dickey,et al.  Giant and switchable surface activity of liquid metal via surface oxidation , 2014, Proceedings of the National Academy of Sciences.

[16]  Yong-Lae Park,et al.  A Soft Strain Sensor Based on Ionic and Metal Liquids , 2013, IEEE Sensors Journal.

[17]  M. Pourbaix Atlas of Electrochemical Equilibria in Aqueous Solutions , 1974 .

[18]  Michael D. Dickey,et al.  Recapillarity: Electrochemically Controlled Capillary Withdrawal of a Liquid Metal Alloy from Microchannels , 2015 .

[19]  G. Beni,et al.  Continuous electrowetting effect , 1982 .

[20]  G. Mumcu,et al.  Frequency-Agile Bandpass Filters Using Liquid Metal Tunable Broadside Coupled Split Ring Resonators , 2013, IEEE Microwave and Wireless Components Letters.

[21]  Dan Xu,et al.  Oxygen electrocatalysts in metal-air batteries: from aqueous to nonaqueous electrolytes. , 2014, Chemical Society reviews.