A Computational Model of the Structure and Extinction of Strained, Opposed Flow, Premixed Methane-

The application of laminar flamelet concepts to turbulent flame propagation requires a detailed understanding of strained laminar flames. Here we use numerical methods, including are-length continuation, to simulate the complex chemical kinetic behavior in premixed methane-air flames that are stabilized between two opposed-flow burners. We predict both the detailed structure and the extinction limits for these flames over a range of fuel-air mixtures. In addition to discussing the flame structure, a sensitivity analysis provides further insight on the chemical behavior near extinction. Finally, we discuss the comparison of the predictions with Law's experimental extinction data. An especially important aspect of this comparison is the recognition that fluid mechanical aspects of the traditional strained-flame analysis are deficient in representing experiments such as Law's. We develop and solve a new system of equations that is able to describe the experiments much more accurately.

[1]  R. F. Heinemann,et al.  Multiplicity and stability of the hydrogen-oxygen-nitrogen flame: the influence of chemical pathways and kinetics on transitions between steady states , 1980 .

[2]  Forman A. Williams,et al.  Laminar flow between parallel plates with injection of a reactant at high reynolds number , 1978 .

[3]  James A. Miller,et al.  The Chemkin Thermodynamic Data Base , 1990 .

[4]  H. Keller The Bordering Algorithm and Path Following Near Singular Points of Higher Nullity , 1983 .

[5]  J. T’ien,et al.  Combustion and extinction in the stagnation-point boundary layer of a condensed fuel , 1978 .

[6]  H. B. Keller,et al.  Driven cavity flows by efficient numerical techniques , 1983 .

[7]  M. Smooke,et al.  Extinction of Strained Premixed Laminar Flames With Complex Chemistry , 1987 .

[8]  David M. Wardlaw,et al.  Study of the recombination reaction methyl + methyl .fwdarw. ethane. 2. Theory , 1988 .

[9]  Peter Glarborg,et al.  Kinetic modeling and sensitivity analysis of nitrogen oxide formation in well-stirred reactors , 1986 .

[10]  T. Chapman,et al.  Stagnation-point viscous flow of an incompressible fluid between porous plates with uniform blowing , 1975 .

[11]  M. Smooke,et al.  Calculation of extinction limits for premixed laminar flames in a stagnation point flow , 1987 .

[12]  G. Dixon-Lewis,et al.  Flame structure and flame reaction kinetics II. Transport phenomena in multicomponent systems , 1968, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.

[13]  Michael J. Pilling,et al.  Study of the recombination reaction methyl + methyl .fwdarw. ethane. 1. Experiment , 1988 .