Structure of tert-Butyl Alcohol−Water Mixtures Studied by the RISM Theory

We calculated the site−site radial distribution functions for binary mixtures of tert-butyl alcohol (TBA) and water over the whole range of TBA molar fraction. The description uses the reference interaction site model (RISM) integral equation theory in the dielectrically consistent approach of Perkyns and Pettitt (DRISM), and the closure approximation of Kovalenko and Hirata (KH) providing appropriate description for association of polar molecular species of density ranging from gas to liquid. We employed the extended simple point charge (SPC/E) model for water, and the optimized potential for liquid simulations (OPLS) force field for TBA. The partial radial distribution functions obtained for the TBA−water mixture are in qualitative agreement with those available from neutron diffraction experiments and molecular dynamics simulations. It is found that hydrogen bonds between all species are enhanced with rise of the TBA concentration. The tetrahedral-like network of hydrogen bonding in dilute TBA aqueous ...