An introduction to superhydrophobicity.

This paper is derived from a training session prepared for COST P21. It is intended as an introduction to superhydrophobicity to scientists who may not work in this area of physics or to students. Superhydrophobicity is an effect where roughness and hydrophobicity combine to generate unusually hydrophobic surfaces, causing water to bounce and roll off as if it were mercury and is used by plants and animals to repel water, stay clean and sometimes even to breathe underwater. The effect is also known as The Lotus Effect(®) and Ultrahydrophobicity. In this paper we introduce many of the theories used, some of the methods used to generate surfaces and then describe some of the implications of the effect.

[1]  Jin Zhai,et al.  Wetting and anti-wetting on aligned carbon nanotube films. , 2006, Soft matter.

[2]  R. Hoffman A study of the advancing interface. I. Interface shape in liquid—gas systems , 1975 .

[3]  A. Fujishima,et al.  Effects of the Surface Roughness on Sliding Angles of Water Droplets on Superhydrophobic Surfaces , 2000 .

[4]  G McHale,et al.  Topography driven spreading. , 2004, Physical review letters.

[5]  Robert N. Wenzel,et al.  Surface Roughness and Contact Angle. , 1949 .

[6]  P. Roach,et al.  Porous materials show superhydrophobic to superhydrophilic switching. , 2005, Chemical communications.

[7]  A. Adamson Physical chemistry of surfaces , 1960 .

[8]  R. Pogreb,et al.  Wetting properties of the multiscaled nanostructured polymer and metallic superhydrophobic surfaces. , 2006, Langmuir : the ACS journal of surfaces and colloids.

[9]  Neelesh A Patankar,et al.  Transition between superhydrophobic states on rough surfaces. , 2004, Langmuir : the ACS journal of surfaces and colloids.

[10]  Tomohiro Onda,et al.  Super-Water-Repellent Fractal Surfaces , 1995 .

[11]  Kazuhito Hashimoto,et al.  Effects of Surface Structure on the Hydrophobicity and Sliding Behavior of Water Droplets , 2002 .

[12]  W. Cai,et al.  Superhydrophobic bionic surfaces with hierarchical microsphere/SWCNT composite arrays. , 2007, Langmuir : the ACS journal of surfaces and colloids.

[13]  Jürgen Rühe,et al.  Condensation and wetting transitions on microstructured ultra-hydrophobic surfaces. , 2007, Langmuir : the ACS journal of surfaces and colloids.

[14]  W. Thorpe PLASTRON RESPIRATION IN AQUATIC INSECTS , 1950, Biological reviews of the Cambridge Philosophical Society.

[15]  D. Quéré,et al.  Contact angle hysteresis generated by strong dilute defects. , 2009, The journal of physical chemistry. B.

[16]  Zhongze Gu,et al.  Control of water droplet motion by alteration of roughness gradient on silicon wafer by laser surface treatment , 2008 .

[17]  Lichao Gao,et al.  Contact angle hysteresis explained. , 2006, Langmuir : the ACS journal of surfaces and colloids.

[18]  Marcus L. Roper,et al.  Imbibition by polygonal spreading on microdecorated surfaces. , 2007, Nature materials.

[19]  Didem Öner,et al.  Ultrahydrophobic Surfaces. Effects of Topography Length Scales on Wettability , 2000 .

[20]  Zhongze Gu,et al.  Fabrication of super-hydrophobic film with dual-size roughness by silica sphere assembly , 2007 .

[21]  David Quéré,et al.  Wetting transitions on rough surfaces , 2004 .

[22]  Zhiguang Guo,et al.  Effects of system parameters on making aluminum alloy lotus. , 2006, Journal of colloid and interface science.

[23]  A. Cassie,et al.  Wettability of porous surfaces , 1944 .

[24]  Uwe Thiele,et al.  Wetting of textured surfaces , 2002 .

[25]  B. Widom Capillarity and Wetting Phenomena: Drops, Bubbles, Pearls, Waves , 2003 .

[26]  Tai Hun Kwon,et al.  Effects of intrinsic hydrophobicity on wettability of polymer replicas of a superhydrophobic lotus leaf , 2007 .

[27]  E. Reyssat,et al.  Wicking within forests of micropillars , 2007 .

[28]  Yanchun Han,et al.  Macroporous fluoropolymeric films templated by silica colloidal assembly: A possible route to super-hydrophobic surfaces , 2006 .

[29]  Jacques Jonsmann,et al.  Ultralow hysteresis superhydrophobic surfaces by excimer laser modification of SU-8. , 2006, Langmuir : the ACS journal of surfaces and colloids.

[30]  G. McHale,et al.  Water‐repellent soil and its relationship to granularity, surface roughness and hydrophobicity: a materials science view , 2005 .

[31]  Dan Wu,et al.  Fabrication of superhydrophobic surfaces from microstructured ZnO-based surfaces via a wet-chemical route. , 2005, Langmuir : the ACS journal of surfaces and colloids.

[32]  Thomas J McCarthy,et al.  Condensation on ultrahydrophobic surfaces and its effect on droplet mobility: ultrahydrophobic surfaces are not always water repellant. , 2006, Langmuir : the ACS journal of surfaces and colloids.

[33]  S. K. Nema,et al.  Deposition of superhydrophobic nanostructured Teflon-like coating using expanding plasma arc , 2007 .

[34]  S. Doerr,et al.  Self-organization of hydrophobic soil and granular surfaces , 2007 .

[35]  G McHale,et al.  Wetting and wetting transitions on copper-based super-hydrophobic surfaces. , 2005, Langmuir : the ACS journal of surfaces and colloids.

[36]  McHale,et al.  Wetting of a High-Energy Fiber Surface , 1997, Journal of colloid and interface science.

[37]  W. Barthlott,et al.  Purity of the sacred lotus, or escape from contamination in biological surfaces , 1997, Planta.

[38]  Gareth H. McKinley,et al.  Designing Superoleophobic Surfaces , 2007, Science.

[39]  Julia M. Yeomans,et al.  Impalement of fakir drops , 2007 .

[40]  D. Quéré Wetting and Roughness , 2008 .

[41]  R. Cerbino Capillarity and Wetting Phenomena: Drops, Bubbles, Pearls, Waves , 2006 .

[42]  Abraham Marmur,et al.  Drops down the hill: theoretical study of limiting contact angles and the hysteresis range on a tilted plate. , 2005, Langmuir : the ACS journal of surfaces and colloids.

[43]  A. Dupuis,et al.  The collapse transition on superhydrophobic surfaces , 2008, 0803.1564.

[44]  Michael Nosonovsky,et al.  Multiscale roughness and stability of superhydrophobic biomimetic interfaces. , 2007, Langmuir : the ACS journal of surfaces and colloids.

[45]  Wei Chen,et al.  Ultrahydrophobic and Ultralyophobic Surfaces: Some Comments and Examples , 1999 .

[46]  Wilhelm Barthlott,et al.  Characterization and Distribution of Water-repellent, Self-cleaning Plant Surfaces , 1997 .

[47]  Lichao Gao,et al.  Teflon is hydrophilic. Comments on definitions of hydrophobic, shear versus tensile hydrophobicity, and wettability characterization. , 2008, Langmuir : the ACS journal of surfaces and colloids.

[48]  V M Starov,et al.  Spreading of liquid drops over porous substrates. , 2003, Advances in colloid and interface science.

[49]  S. Dong,et al.  A general route to transform normal hydrophilic cloths into superhydrophobic surfaces. , 2007, Chemical communications.

[50]  Gareth H. McKinley,et al.  Superhydrophobic Carbon Nanotube Forests , 2003 .

[51]  R. N. Wenzel RESISTANCE OF SOLID SURFACES TO WETTING BY WATER , 1936 .

[52]  K. Hanabusa,et al.  Construction of superhydrophobic surfaces by fibrous aggregation of perfluoroalkyl chain-containing organogelators. , 2006, Chemical communications.

[53]  Li Li,et al.  Artificial lotus leaf structures from assembling carbon nanotubes and their applications in hydrophobic textiles , 2007 .

[54]  J. S. Turner,et al.  The Extended Organism: The Physiology of Animal-Built Structures , 2000 .

[55]  G. McHale,et al.  Contact-angle hysteresis on super-hydrophobic surfaces. , 2004, Langmuir : the ACS journal of surfaces and colloids.

[56]  S. Michielsen,et al.  Design of a superhydrophobic surface using woven structures. , 2007, Langmuir : the ACS journal of surfaces and colloids.

[57]  Kenneth J. Bell,et al.  The leidenfrost phenomenon: film boiling of liquid droplets on a flat plate , 1966 .

[58]  Ming Zhou,et al.  Superhydrophobic surfaces prepared by microstructuring of silicon using a femtosecond laser. , 2006, Langmuir : the ACS journal of surfaces and colloids.

[59]  X. Ye,et al.  Tuning wettability and getting superhydrophobic surface by controlling surface roughness with well-designed microstructures , 2005, The 13th International Conference on Solid-State Sensors, Actuators and Microsystems, 2005. Digest of Technical Papers. TRANSDUCERS '05..

[60]  David Hu,et al.  The Integument of Water-walking Arthropods: Form and Function , 2007 .

[61]  Glen McHale,et al.  Dual‐Scale Roughness Produces Unusually Water‐Repellent Surfaces , 2004 .

[62]  Glen McHale,et al.  The use of high aspect ratio photoresist (SU-8) for super-hydrophobic pattern prototyping , 2004 .

[63]  G. McHale All solids, including teflon, are hydrophilic (to some extent), but some have roughness induced hydrophobic tendencies. , 2009, Langmuir : the ACS journal of surfaces and colloids.

[64]  Neelesh A Patankar,et al.  Mimicking the lotus effect: influence of double roughness structures and slender pillars. , 2004, Langmuir : the ACS journal of surfaces and colloids.

[65]  Lei Jiang,et al.  Preparation of a super-hydrophobic poly(vinyl chloride) surface via solvent–nonsolvent coating , 2006 .

[66]  Michael I. Newton,et al.  Super-hydrophobic and super-wetting surfaces: Analytical potential? , 2004 .

[67]  E. Yoon,et al.  Replication of surfaces of natural leaves for enhanced micro-scale tribological property , 2007 .

[68]  L. Mahadevan,et al.  How aphids lose their marbles , 2002, Proceedings of the Royal Society of London. Series B: Biological Sciences.

[69]  M. Denny,et al.  Air and water : the biology and physics of life's media , 1993 .

[70]  P. Gennes Wetting: statics and dynamics , 1985 .

[71]  Michael Newton,et al.  Progess in superhydrophobic surface development. , 2008, Soft matter.

[72]  T. J. McCarthy,et al.  How Wenzel and cassie were wrong. , 2007, Langmuir : the ACS journal of surfaces and colloids.

[73]  P. Roach,et al.  Superhydrophobic to superhydrophilic transitions of sol–gel films for temperature, alcohol or surfactant measurement , 2007 .

[74]  S. Bhatia,et al.  Manipulation of liquid droplets using amphiphilic, magnetic one-dimensional photonic crystal chaperones , 2004, Nature materials.

[75]  L. Tanner,et al.  The spreading of silicone oil drops on horizontal surfaces , 1979 .

[76]  G. McHale,et al.  Superhydrophobic surfaces: a model approach to predict contact angle and surface energy of soil particles , 2009 .

[77]  Joong Tark Han,et al.  Diverse access to artificial superhydrophobic surfaces using block copolymers. , 2005, Langmuir : the ACS journal of surfaces and colloids.

[78]  Lei Zhai,et al.  Decorated Electrospun Fibers Exhibiting Superhydrophobicity , 2007 .

[79]  M. Stratmann,et al.  Chemical structure and morphology of thin, organo-silicon plasma-polymer films as a function of process parameters , 2001 .

[80]  Zhifeng Ren,et al.  Dropwise condensation on superhydrophobic surfaces with two-tier roughness , 2007 .

[81]  Stephan Herminghaus,et al.  Roughness-induced non-wetting , 2000 .

[82]  G McHale,et al.  Cassie and Wenzel: were they really so wrong? , 2007, Langmuir : the ACS journal of surfaces and colloids.

[83]  Chang‐Hwan Choi,et al.  Fabrication of a dense array of tall nanostructures over a large sample area with sidewall profile and tip sharpness control , 2006 .

[84]  David Quéré,et al.  Surface chemistry: Fakir droplets. , 2002, Nature materials.

[85]  Pascal Colpo,et al.  Tuneable Rough Surfaces- A New Approach for Elaboration of Superhydrophobic Films , 2005 .

[86]  K. Böhringer,et al.  Directing droplets using microstructured surfaces. , 2006, Langmuir : the ACS journal of surfaces and colloids.

[87]  S. Karuppuchamy,et al.  Super-hydrophilic amorphous titanium dioxide thin film deposited by cathodic electrodeposition , 2005 .