A Comparison of Producer Gas, Biochar, and Activated Carbon from Two Distributed Scale Thermochemical Conversion Systems Used to Process Forest Biomass

Thermochemical biomass conversion systems have the potential to produce heat, power, fuels and other products from forest biomass at distributed scales that meet the needs of some forest industry facilities. However, many of these systems have not been deployed in this sector and the products they produce from forest biomass have not been adequately described or characterized with regards to chemical properties, possible uses, and markets. This paper characterizes the producer gas, biochar, and activated carbon of a 700 kg h −1 prototype gasification system and a 225 kg h −1 pyrolysis system used to process coniferous sawmill and forest residues. Producer gas from sawmill residues processed with the gasifier had higher energy content than gas from forest residues, with averages of 12.4 MJ m −3 and 9.8 MJ m −3 , respectively. Gases from the pyrolysis system averaged 1.3 MJ m −3 for mill residues and 2.5 MJ m −3 for forest residues. Biochars produced have

[1]  P. Badger,et al.  Use of mobile fast pyrolysis plants to densify biomass and reduce biomass handling costs—A preliminary assessment , 2006 .

[2]  D. Peterson,et al.  Market Assessment of Biomass Gasification and Combustion Technology for Small- and Medium-Scale Applications , 2009 .

[3]  H. Teng,et al.  Preparation of activated carbon from bituminous coal with phosphoric acid activation , 1998 .

[4]  Mark D. Coleman,et al.  Bioenergy production systems and biochar application in forests: potential for renewable energy, soil enhancement, and carbon sequestration , 2011 .

[5]  Eric Croiset,et al.  High-Yield Biomass Charcoal† , 1996 .

[6]  Hongwei Wu,et al.  Biochar as a Fuel: 1. Properties and Grindability of Biochars Produced from the Pyrolysis of Mallee Wood under Slow-Heating Conditions , 2009 .

[7]  François Béguin,et al.  Surface functionality and porosity of activated carbons obtained from chemical activation of wood , 2000 .

[8]  M. Hanna,et al.  THERMOCHEMICAL BIOMASS GASIFICATION—A REVIEW OF THE CURRENT STATUS OF THE TECHNOLOGY , 2009 .

[9]  J. Mcdonagh,et al.  Biochar for Environmental Management , 2015 .

[10]  Wulf Amelung,et al.  Aggregate‐occluded black carbon in soil , 2006 .

[11]  Kj Krzysztof Ptasinski,et al.  Torrefaction of wood: Part 2. Analysis of products , 2006 .

[12]  E. Halliop,et al.  The production of chemically-activated carbon , 1999 .

[13]  André Faaij,et al.  Pre-treatment technologies, and their effect on international bioenergy supply chain logistics. Techno-economic evaluation of torrefaction, fast pyrolysis and pelletisation , 2008 .

[14]  Roger Perry,et al.  Low-cost adsorbents for waste and wastewater treatment: a review , 1992 .

[15]  Guk-Rwang Won American Society for Testing and Materials , 1987 .

[16]  D. Calkin,et al.  Forest treatment residues for thermal energy compared with disposal by onsite burning: Emissions and energy return , 2010 .

[17]  E. Demirbas,et al.  Adsorption of heavy metal ions from aqueous solutions by activated carbon prepared from apricot stone. , 2005, Bioresource technology.

[18]  Magdy M. A. Salama,et al.  Distributed generation technologies, definitions and benefits , 2004 .

[19]  D. Sparks,et al.  Methods of soil analysis. Part 3 - chemical methods. , 1996 .

[20]  A. Demirbas,et al.  Sustainable cofiring of biomass with coal , 2003 .

[21]  J. Rath,et al.  Cracking reactions of tar from pyrolysis of spruce wood , 2001 .

[22]  J. Lehmann Bio-energy in the black , 2007 .

[23]  S. Minteer Production of Methanol from Biomass , 2006 .

[24]  Choo Yuen May,et al.  Production and Characterization of Bio-Char from the Pyrolysis of Empty Fruit Bunches , 2011 .

[25]  A. Faaij,et al.  Exploration of the possibilities for production of Fischer Tropsch liquids and power via biomass gasification , 2002 .

[26]  W. Covington,et al.  Slash Pile Burning Effects on Soil Biotic and Chemical Properties and Plant Establishment: Recommendations for Amelioration , 2004 .

[27]  D. W. Nelson,et al.  Total Carbon, Organic Carbon, and Organic Matter , 1983, SSSA Book Series.

[28]  Bryce J. Stokes,et al.  U.S. Billion-ton Update: Biomass Supply for a Bioenergy and Bioproducts Industry , 2011 .

[29]  Kj Krzysztof Ptasinski,et al.  Biomass upgrading by torrefaction for the production of biofuels: A review , 2011 .

[30]  Y. Son,et al.  Gasification and power generation characteristics of woody biomass utilizing a downdraft gasifier , 2011 .

[31]  B. Jenkins,et al.  Combustion properties of biomass , 1998 .

[32]  J. Turnbull,et al.  Use of biomass in electric power generation: the california experience , 1993 .

[33]  T. Elder,et al.  Pilot-scale gasification of woody biomass , 2011 .

[34]  M. Alma,et al.  Pyrolysis of laurel (Laurus nobilis L.) extraction residues in a fixed-bed reactor: Characterization of bio-oil and bio-char , 2010 .

[35]  D. Tillman Biomass cofiring: the technology, the experience, the combustion consequences , 2000 .

[36]  A. Crosky,et al.  Physical Properties of Biochar , 2012 .

[37]  J. Lehmann,et al.  Biochar for environmental management : science, technology and implementation , 2015 .

[38]  Richard D. Bergman,et al.  Drying and control of moisture content and dimensional changes , 2010 .

[39]  H. Teng,et al.  Activated carbon production from low ash subbituminous coal with CO2 activation , 1998 .

[40]  David A. Laird,et al.  The Charcoal Vision : A Win – Win – Win Scenario for Simultaneously Producing Bioenergy , Permanently Sequestering Carbon , while Improving Soil and Water Quality , 2008 .

[41]  A. Dalai,et al.  Biochar as a precursor of activated carbon , 1996, Applied biochemistry and biotechnology.

[42]  D. Mohan,et al.  Pyrolysis of Wood/Biomass for Bio-oil: A Critical Review , 2006 .