Pyrolysis biochar systems for recovering biodegradable materials: A life cycle carbon assessment.

A life cycle assessment (LCA) focused on biochar and bioenergy generation was performed for three thermal treatment configurations (slow pyrolysis, fast pyrolysis and gasification). Ten UK biodegradable wastes or residues were considered as feedstocks in this study. Carbon (equivalent) abatement (CA) and electricity production indicators were calculated. Slow pyrolysis systems offer the best performance in terms of CA, with net results varying from 0.07 to 1.25tonnes of CO(2)eq.t(-1) of feedstock treated. On the other hand, gasification achieves the best electricity generation outputs, with results varying around 0.9MWhet(-1) of feedstock. Moreover, selection of a common waste treatment practice as the reference scenario in an LCA has to be undertaken carefully as this will have a key influence upon the CA performance of pyrolysis or gasification biochar systems (P/GBS). Results suggest that P/GBS could produce important environmental benefits in terms of CA, but several potential pollution issues arising from contaminants in the biochar have to be addressed before biochar and bioenergy production from biodegradable waste can become common practice.

[1]  Davey L. Jones,et al.  Heavy metal contamination of a mixed waste compost: metal speciation and fate. , 2009, Bioresource technology.

[2]  L. Cárdenas,et al.  UK greenhouse gas inventory 1990 to 2006: annual report for submission under the Framework Convention on Climate Change , 2006 .

[3]  Enzo Favoino,et al.  HEAVY METALS AND ORGANIC COMPOUNDS FROM WASTES USED AS ORGANIC FERTILISERS , 2004 .

[4]  L. Cárdenas,et al.  UK Greenhouse Gas Inventory, 1990 to 2005 , 2006 .

[5]  John Gaunt,et al.  Bio-char Sequestration in Terrestrial Ecosystems – A Review , 2006 .

[6]  M. Velde,et al.  Biochar Application to Soils - A Critical Scientific Review of Effects on Soil Properties, Processes and Functions , 2010 .

[7]  Hsien Hui Khoo,et al.  Life cycle impact assessment of various waste conversion technologies. , 2009, Waste management.

[8]  D. Bosch,et al.  Economics of transporting poultry litter to achieve more effective use as fertilizer , 1992 .

[9]  Alice Bows,et al.  Reframing the climate change challenge in light of post-2000 emission trends , 2008, Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences.

[10]  Thomas H Christensen,et al.  Greenhouse gas accounting and waste management , 2009, Waste management & research : the journal of the International Solid Wastes and Public Cleansing Association, ISWA.

[11]  T. Wilbanks,et al.  Contribution of Working Group II to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change , 2007 .

[12]  T. Nussbaumer,et al.  Dioxin emissions from wood combustion , 1994 .

[13]  K. C. Das,et al.  Slow pyrolysis of poultry litter and pine woody biomass: Impact of chars and bio-oils on microbial growth , 2008, Journal of environmental science and health. Part A, Toxic/hazardous substances & environmental engineering.

[14]  J R Barton,et al.  Carbon--making the right choice for waste management in developing countries. , 2008, Waste management.

[15]  M. García-Pérez The Formation of Polyaromatic Hydrocarbons and Dioxins During Pyrolysis: A Review of the Literature with Descriptions of Biomass Composition, Fast Pyrolysis Technologies and Thermochemical Reactions June 2008 , 2008 .

[16]  V. Strezov,et al.  Thermal processing of paper sludge and characterisation of its pyrolysis products. , 2009, Waste management.

[17]  David Pennington,et al.  Recent developments in Life Cycle Assessment. , 2009, Journal of environmental management.

[18]  Simon Shackley,et al.  The feasibility and costs of biochar deployment in the UK , 2011 .

[19]  S. Sohi,et al.  Prospective life cycle carbon abatement for pyrolysis biochar systems in the UK , 2011 .

[20]  D. Tenenbaum Biochar: Carbon Mitigation from the Ground Up , 2009, Environmental health perspectives.

[21]  Masaru Yamaoka,et al.  Basic characteristics of low-temperature carbon products from waste sludge , 2003 .

[22]  Anh N. Phan,et al.  Characterisation of slow pyrolysis products from segregated wastes for energy production. , 2008 .

[23]  N. H. Ravindranath,et al.  2006 IPCC Guidelines for National Greenhouse Gas Inventories , 2006 .

[24]  J. Lehmann,et al.  Biochar for Environmental Management: Science and Technology , 2009 .

[25]  S. Sohi,et al.  An Assessment of the Benefits and Issues Associated with the Application of Biochar to Soil: A report commissioned by the UK Department for Environment, Food and Rural Affairs and Department of Energy and Climate Change , 2010 .

[26]  Brent A. Gloy,et al.  Life cycle assessment of biochar systems: estimating the energetic, economic, and climate change potential. , 2010, Environmental science & technology.

[27]  Paul Upham,et al.  Integrated assessment of bioelectricity technology options , 2009 .

[28]  Fabrizio Passarini,et al.  Integrated Waste Management. Technologies and Environmental Control , 2008 .

[29]  S. Polasky,et al.  Land Clearing and the Biofuel Carbon Debt , 2008, Science.

[30]  J. Satrio,et al.  Characterization of biochar from fast pyrolysis and gasification systems , 2009 .