Immobilization of Oxygen Atoms in the Pores of Microporous Metal–Organic Frameworks for C2H2 Separation and Purification

The development of porous metal–organic framework (MOF) solids displaying efficient separation and purification of acetylene is of cardinal significance but challenging in the chemical industry. Am...

[1]  R. Krishna,et al.  Constructing redox-active microporous hydrogen-bonded organic framework by imide-functionalization: Photochromism, electrochromism, and selective adsorption of C2H2 over CO2 , 2020 .

[2]  A. Alsalme,et al.  Microporous Copper Isophthalate Framework of mot Topology for C2H2/CO2 Separation , 2019, Crystal Growth & Design.

[3]  Liang Huang,et al.  Reversing C2H2-CO2 adsorption selectivity in an ultramicroporous metal-organic framework platform. , 2019, Chemical communications.

[4]  Ying Wang,et al.  Ultramicroporous Building Units as a Path to Bi-microporous Metal-Organic Frameworks with High Acetylene Storage and Separation Performance. , 2019, Angewandte Chemie.

[5]  A. Alsalme,et al.  A microporous metal-organic framework of sql topology for C2H2/CO2 separation , 2019, Inorganica Chimica Acta.

[6]  Cong-Li Gao Metal−organic framework with dual-functionalized sites for efficient C2H2/CO2 separation , 2019, Inorganic Chemistry Communications.

[7]  Omid T. Qazvini,et al.  Multipurpose Metal–Organic Framework for the Adsorption of Acetylene: Ethylene Purification and Carbon Dioxide Removal , 2019, Chemistry of Materials.

[8]  M. Zaworotko,et al.  Highly Selective, High-Capacity Separation of o-Xylene from C8 Aromatics by a Switching Adsorbent Layered Material. , 2019, Angewandte Chemie.

[9]  R. Liu,et al.  Water-Stable Europium 1,3,6,8-Tetrakis(4-carboxylphenyl)pyrene Framework for Efficient C2H2/CO2 Separation. , 2019, Inorganic chemistry.

[10]  R. Krishna,et al.  Pore Space Partition within a Metal-Organic Framework for Highly Efficient C2H2/CO2 Separation. , 2019, Journal of the American Chemical Society.

[11]  R. Krishna,et al.  Microporous Metal-Organic Framework with Dual Functionalities for Efficient Separation of Acetylene from Light Hydrocarbon Mixtures. , 2019, ACS sustainable chemistry & engineering.

[12]  Yao Wang,et al.  A ligand conformation preorganization approach to construct a copper–hexacarboxylate framework with a novel topology for selective gas adsorption , 2019, Inorganic Chemistry Frontiers.

[13]  Jiawei Wang,et al.  Inverse Adsorption Separation of CO2/C2H2 Mixture in Cyclodextrin-Based Metal-Organic Frameworks. , 2019, ACS applied materials & interfaces.

[14]  B. Li,et al.  Low-Cost and High-Performance Microporous Metal–Organic Framework for Separation of Acetylene from Carbon Dioxide , 2018, ACS Sustainable Chemistry & Engineering.

[15]  R. Krishna,et al.  Molecular Sieving of Ethane from Ethylene through the Molecular Cross-Section Size Differentiation in Gallate-based Metal-Organic Frameworks. , 2018, Angewandte Chemie.

[16]  Yaoyu Wang,et al.  A NbO-type MOF based on an aromatic-rich and N-functionalized diisophthalate ligand for high-performance acetylene storage and purification , 2018 .

[17]  B. Li,et al.  A Metal-Organic Framework with Suitable Pore Size and Specific Functional Sites for the Removal of Trace Propyne from Propylene. , 2018, Angewandte Chemie.

[18]  Zhiguo Zhang,et al.  A thermostable anion-pillared metal-organic framework for C2H2/C2H4 and C2H2/CO2 separations , 2018, Chemical Engineering Journal.

[19]  R. Krishna,et al.  Ethane/ethylene separation in a metal-organic framework with iron-peroxo sites , 2018, Science.

[20]  F. Rominger,et al.  Strategic Approach on N -Oxides in Gold Catalysis - A Case Study , 2018, Advanced Synthesis & Catalysis.

[21]  Yao Wang,et al.  Three isoreticular ssa-type MOFs derived from bent diisophthalate ligands: exploring the substituent effect on structural stabilities and selective C2H2/CH4 and CO2/CH4 adsorption properties. , 2018, Dalton transactions.

[22]  Banglin Chen,et al.  Highly selective room temperature acetylene sorption by an unusual triacetylenic phosphine MOF. , 2018, Chemical communications.

[23]  Tony Pham,et al.  Robust Ultramicroporous Metal-Organic Frameworks with Benchmark Affinity for Acetylene. , 2018, Angewandte Chemie.

[24]  Kimoon Kim,et al.  Separation of Acetylene from Carbon Dioxide and Ethylene by a Water-Stable Microporous Metal-Organic Framework with Aligned Imidazolium Groups inside the Channels. , 2018, Angewandte Chemie.

[25]  R. Krishna,et al.  Exploring the Effect of Ligand-Originated MOF Isomerism and Methoxy Group Functionalization on Selective Acetylene/Methane and Carbon Dioxide/Methane Adsorption Properties in Two NbO-Type MOFs. , 2018, ACS applied materials & interfaces.

[26]  B. Li,et al.  Efficient separation of C2H2 from C2H2/CO2 mixtures in an acid-base resistant metal-organic framework. , 2018, Chemical communications.

[27]  Shu’ni Li,et al.  Assembly of [Cu2(COO)4] and [M3(μ3-O)(COO)6] (M = Sc, Fe, Ga, and In) building blocks into porous frameworks towards ultra-high C2H2/CO2 and C2H2/CH4 separation performance. , 2018, Chemical communications.

[28]  Craig M. Brown,et al.  Separation of Xylene Isomers through Multiple Metal Site Interactions in Metal-Organic Frameworks. , 2018, Journal of the American Chemical Society.

[29]  Qilong Ren,et al.  Sorting of C4 Olefins with Interpenetrated Hybrid Ultramicroporous Materials by Combining Molecular Recognition and Size-Sieving. , 2017, Angewandte Chemie.

[30]  Xiao‐Hui Liu,et al.  Microporous Cobalt(II)-Organic Framework with Open O-Donor Sites for Effective C2H2 Storage and C2H2/CO2 Separation at Room Temperature. , 2017, Inorganic chemistry.

[31]  Yao Wang,et al.  A family of ssa-type copper-based MOFs constructed from unsymmetrical diisophthalates: synthesis, characterization and selective gas adsorption , 2017 .

[32]  Hong‐Cai Zhou,et al.  A zirconium metal-organic framework with an exceptionally high volumetric surface area. , 2017, Dalton transactions.

[33]  Wei Zhou,et al.  Porous metal–organic frameworks for fuel storage , 2017, Coordination Chemistry Reviews.

[34]  Xiao-Ming Chen,et al.  Controlling guest conformation for efficient purification of butadiene , 2017, Science.

[35]  Nan-nan Zhang,et al.  Quest for the Ncb-type Metal-Organic Framework Platform: A Bifunctional Ligand Approach Meets Net Topology Needs. , 2017, Inorganic chemistry.

[36]  Z. Ji,et al.  A New Microporous Metal-Organic Framework for Highly Selective C2H2/CH4 and C2H2/CO2 Separation at Room Temperature , 2017 .

[37]  Wei Zhou,et al.  Optimized Separation of Acetylene from Carbon Dioxide and Ethylene in a Microporous Material. , 2017, Journal of the American Chemical Society.

[38]  Yuanjing Cui,et al.  Microporous Metal-Organic Framework with Exposed Amino Functional Group for High Acetylene Storage and Excellent C2H2/CO2 and C2H2/CH4 Separations , 2017 .

[39]  Tony Pham,et al.  Highly Selective Separation of C2H2 from CO2 by a New Dichromate-Based Hybrid Ultramicroporous Material. , 2017, ACS applied materials & interfaces.

[40]  L. Daemen,et al.  An ultra-tunable platform for molecular engineering of high-performance crystalline porous materials , 2016, Nature Communications.

[41]  Tony Pham,et al.  Benchmark C2H2/CO2 and CO2/C2H2 Separation by Two Closely Related Hybrid Ultramicroporous Materials , 2016 .

[42]  Chao Zou,et al.  Doubly Interpenetrated Metal–Organic Framework for Highly Selective C 2 H 2 /CH 4 and C 2 H 2 /CO 2 Separation at Room Temperature , 2016 .

[43]  R. Krishna,et al.  A Porous Zirconium-Based Metal-Organic Framework with the Potential for the Separation of Butene Isomers. , 2016, Chemistry.

[44]  Z. Ji,et al.  A novel metal-organic framework for high storage and separation of acetylene at room temperature , 2016 .

[45]  Chun-sen Liu,et al.  A CoII-based metal–organic framework based on [Co6(μ3-OH)4] units exhibiting selective sorption of C2H2 over CO2 and CH4 , 2016 .

[46]  Rajamani Krishna,et al.  Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene , 2016, Science.

[47]  M. O'keeffe,et al.  UTSA-74: A MOF-74 Isomer with Two Accessible Binding Sites per Metal Center for Highly Selective Gas Separation. , 2016, Journal of the American Chemical Society.

[48]  R. Krishna,et al.  Extraordinary Separation of Acetylene-Containing Mixtures with Microporous Metal-Organic Frameworks with Open O Donor Sites and Tunable Robustness through Control of the Helical Chain Secondary Building Units. , 2016, Chemistry.

[49]  R. Krishna,et al.  An Adsorbate Discriminatory Gate Effect in a Flexible Porous Coordination Polymer for Selective Adsorption of CO2 over C2H2. , 2016, Journal of the American Chemical Society.

[50]  Bin Li,et al.  Control of interpenetration in a microporous metal-organic framework for significantly enhanced C2H2/CO2 separation at room temperature. , 2016, Chemical communications.

[51]  Wei‐Xiong Zhang,et al.  Efficient purification of ethene by an ethane-trapping metal-organic framework , 2015, Nature Communications.

[52]  W. Jin,et al.  Natural gas purification using a porous coordination polymer with water and chemical stability. , 2015, Inorganic chemistry.

[53]  Yuanjing Cui,et al.  A microporous metal–organic framework with both open metal and Lewis basic pyridyl sites for highly selective C2H2/CH4 and C2H2/CO2 gas separation at room temperature , 2013 .

[54]  W. Zhou,et al.  Microporous metal-organic frameworks for storage and separation of small hydrocarbons. , 2012, Chemical communications.

[55]  M. W. George,et al.  Selective CO2 uptake and inverse CO2/C2H2 selectivity in a dynamic bifunctional metal–organic framework , 2012 .

[56]  V. Blatov Nanocluster analysis of intermetallic structures with the program package TOPOS , 2012, Structural Chemistry.

[57]  Rajamani Krishna,et al.  Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites , 2012, Science.

[58]  N. Mizuno,et al.  Inverse and high CO2/C2H2 sorption selectivity in flexible organic-inorganic ionic crystals. , 2012, Angewandte Chemie.

[59]  Peyman Z. Moghadam,et al.  p-Xylene-selective metal-organic frameworks: a case of topology-directed selectivity. , 2011, Journal of the American Chemical Society.

[60]  De-Li Chen,et al.  Atomic charges derived from electrostatic potentials for molecular and periodic systems. , 2010, The journal of physical chemistry. A.

[61]  W. Zhou,et al.  Open metal sites within isostructural metal-organic frameworks for differential recognition of acetylene and extraordinarily high acetylene storage capacity at room temperature. , 2010, Angewandte Chemie.

[62]  S. Grimme,et al.  A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu. , 2010, The Journal of chemical physics.

[63]  Hong-Cai Zhou,et al.  Selective gas adsorption and separation in metal-organic frameworks. , 2009, Chemical Society reviews.

[64]  Anthony L. Spek,et al.  Structure validation in chemical crystallography , 2009, Acta crystallographica. Section D, Biological crystallography.

[65]  Song Gao,et al.  Preparation, crystal structure and properties of two novel metal-organic frameworks assembled from pyridine-3,5-dicarboxylic acid N-oxide , 2008 .

[66]  S. Kitagawa,et al.  Storage and sorption properties of acetylene in jungle-gym-like open frameworks. , 2008, Chemistry, an Asian journal.

[67]  A. Matzger,et al.  Dramatic tuning of carbon dioxide uptake via metal substitution in a coordination polymer with cylindrical pores. , 2008, Journal of the American Chemical Society.

[68]  Y. Kawazoe,et al.  Highly controlled acetylene accommodation in a metal–organic microporous material , 2005, Nature.

[69]  G. Kresse,et al.  Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set , 1996 .

[70]  A. Spek PLATON SQUEEZE: a tool for the calculation of the disordered solvent contribution to the calculated structure factors. , 2015, Acta crystallographica. Section C, Structural chemistry.

[71]  G. Sheldrick A short history of SHELX. , 2008, Acta crystallographica. Section A, Foundations of crystallography.

[72]  Alan L. Myers,et al.  Thermodynamics of mixed‐gas adsorption , 1965 .