Monitoring of a methane-seeping pockmark by cabled benthic observatory (Patras Gulf, Greece)

A new seafloor observatory, the gas monitoring module (GMM), has been developed for continuous and long-term measurements of methane and hydrogen sulphide concentrations in seawater, integrated with temperature (T), pressure (P) and conductivity data at the seafloor. GMM was deployed in April 2004 within an active gas-bearing pockmark in the Gulf of Patras (Greece), at a water depth of 42 m. Through a submarine cable linked to an onshore station, it was possible to remotely check, via direct phone connection, GMM functioning and to receive data in near-real time. Recordings were carried out in two consecutive campaigns over the periods April–July 2004, and September 2004–January 2005, amounting to a combined dataset of ca. 6.5 months. This represents the first long-term monitoring ever done on gas leakage from pockmarks by means of CH4+H2S+T+P sensors. The results show frequent T and P drops associated with gas peaks, more than 60 events in 6.5 months, likely due to intermittent, pulsation-like seepage. Decreases in temperature in the order of 0.1–1°C (up to 1.7°C) below an ambient T of ca. 17°C (annual average) were associated with short-lived pulses (10–60 min) of increased CH4+H2S concentrations. This seepage “pulsation” can either be an active process driven by pressure build-up in the pockmark sediments, or a passive fluid release due to hydrostatic pressure drops induced by bottom currents cascading into the pockmark depression. Redundancy and comparison of data from different sensors were fundamental to interpret subtle proxy signals of temperature and pressure which would not be understood using only one sensor.

[1]  GMM—a gas monitoring module for long-term detection of methane leakage from the seafloor , 2004 .

[2]  Giuseppe Etiope,et al.  New Directions: GEM—Geologic Emissions of Methane, the missing source in the atmospheric methane budget☆ , 2004 .

[3]  Libe Washburn,et al.  A Gas-Capture Buoy for Measuring Bubbling Gas Flux in Oceans and Lakes , 2001 .

[4]  G. Etiope,et al.  A new estimate of global methane flux from onshore and shallow submarine mud volcanoes to the atmosphere , 2004 .

[5]  G. Etiope,et al.  Methane and hydrogen sulfide seepage in the northwest Peloponnesus petroliferous basin (Greece): Origin and geohazard , 2006 .

[6]  Jens Greinert,et al.  Side-scan sonar investigations and hydroacoustic 'bubble' quantification in an area of surface-near gas hydrate occurrences: recent studies from Hydrate Ridge, offshore Oregon , 2002, OCEANS '02 MTS/IEEE.

[7]  Ira Leifer,et al.  The bubble mechanism for methane transport from the shallow sea bed to the surface: A review and sensitivity study , 2002 .

[8]  Kit Ming Lam,et al.  Environmental Hydraulics and Sustainable Water Management , 2004 .

[9]  K. Lam,et al.  Upward flux of methane in the Black Sea: does it reach the atmosphere? , 2005 .

[10]  G. Ferentinos,et al.  Active seepage in two contrasting pockmark fields in the Patras and Corinth gulfs, Greece , 2003 .

[11]  I. Leifer,et al.  Transient discharges from marine hydrocarbon seeps: spatial and temporal variability , 2004 .

[12]  W. Reeburgh,et al.  Attention turns to naturally occurring methane seepage , 2001 .

[13]  A. Lascaratos,et al.  Wind-induced upwellings and currents in the gulfs of patras, nafpaktos and korinthos, western greece , 1989 .

[14]  G. Papatheodorou,et al.  A pockmark field in the Patras Gulf (Greece) and its activation during the 14/7/93 seismic event , 1996 .

[15]  G. Papatheodorou,et al.  Gas-charged sediments in the Aegean and Ionian Seas, Greece , 1993 .