Laser writing of superconducting patterns on YBa2Cu3Ox films

A novel process for the direct laser writing of thin‐film high Tc patterns is demonstrated. The process consists of deposition of a high quality film (308 nm laser ablation from a YBa2Cu3Ox target with a 750 °C substrate temperature and a 150 mTorr O2 ambient), annealing in an inert atmosphere (Ar at 400 °C for 5–20 min) to reduce the oxygen content and depress or eliminate the superconducting transition temperature, and direct‐write laser heating (1.06 μm at ≊0.5 kW/cm2 for ≊5 min) in an oxygen atmosphere at ≊590 Torr to selectively regenerate the high Tc material. rf eddy current and four‐point resistivity probe results confirm this process for both SrTiO3 and LaAlO3 substrates. Scanning electron micrographs indicate that this is a very mild processing sequence with no observable changes in film morphology.

[1]  N. S. Nogar,et al.  Effects of beam parameters on excimer laser deposition of YBa2Cu3O7−δ , 1990 .

[2]  E. Abraham,et al.  Some calculations of temperature profiles in thin films with laser heating , 1987 .

[3]  D. Aspnes,et al.  Optical properties of high-T/sub c/ superconductors , 1989 .

[4]  R. Buckley,et al.  Diffuse reflectance and its relationship to oxygen content in YBa 2 Cu 3 O 7− δ and Bi 2.1 (CaxSr 1− x)n +1 CunO 2 n +4+ δ ( n = 1, 2) , 1989 .

[5]  P. Kelly,et al.  Theory of transient temperature response of a two‐layer system heated with a localized laser beam , 1986 .

[6]  T. Van Duzer,et al.  Superconductor electronic device applications , 1989 .

[7]  Q. Ma,et al.  Novel method of patterning YBaCuO superconducting thin films , 1989 .

[8]  B. Batlogg,et al.  Structural anomalies, oxygen ordering and superconductivity in oxygen deficient Ba2YCu3Ox , 1990 .

[9]  M. Eyett,et al.  Direct laser writing of superconducting patterns into semiconducting ceramic Y-Ba-Cu-O , 1988 .

[10]  J. Tsao,et al.  Nonreciprocal laser‐microchemical processing: Spatial resolution limits and demonstration of 0.2‐μm linewidths , 1984 .

[11]  K. Tu,et al.  Thermogravimetric study of the recovery of oxygen‐deficient superconducting YBa2Cu3O7−δ oxides in ambient oxygen , 1989 .

[12]  E. O'Sullivan,et al.  Study of oxygen transport in Ba2YCu3O7−δ using a solid‐state electrochemical cell , 1988 .

[13]  H. Koinuma,et al.  Reversible Resistivity Control of Ba2YCu3O7-δ Thin Films by Laser Annealing , 1988 .

[14]  Selwyn,et al.  Oxygen intercalation in the perovskite superconductor YBa2Cu3O6+x. , 1988, Physical review. B, Condensed matter.

[15]  N. S. Nogar,et al.  Effect of deposition rate on properties of YBa2Cu3O7−δ superconducting thin films , 1990 .

[16]  K. Kadowaki,et al.  Specific heat measurements of high-Tc superconductor YBa2Cu3O7 between 78 K and 260 K , 1987 .

[17]  H. Kwok,et al.  Laser patterning and critical current measurements of submicrometer lines of Y-Ba-Cu-O , 1989 .

[18]  Robert R. Krchnavek,et al.  Transport in reversibly laser‐modified YBa2Cu3O7−x superconducting thin films , 1989 .