Ultra-Small-Angle X-ray Scattering Instrument at the Advanced Photon Source: History, Recent Development, and Current Status

The 25-year history and development of an ultra-small-angle X-ray scattering (USAXS) instrument dedicated to serving materials research is presented and discussed. The instrument’s successful track record is attributed to three factors. The first, and surely the most important, is that all development has been driven by scientific research directions and opportunities. Second, the USAXS instrument is a core capability rather than an add-on facility, with measurement capability from micrometers to nanometers, which is precisely the size range where microstructures determine physical properties. The third is that the instrument’s range of capabilities has continually expanded, now including 2D collimation, imaging, and dynamics. And finally, USAXS has enjoyed the benefit of a management structure that has consistently appreciated the unique experimental measurement capabilities that USAXS delivers.

[1]  Pete R. Jemian,et al.  Effective pinhole-collimated ultrasmall-angle x-ray scattering instrument for measuring anisotropic microstructures , 2002 .

[2]  Gabrielle G. Long,et al.  X-ray imaging with ultra-small-angle X-ray scattering as a contrast mechanism , 2004 .

[3]  G. G. Long,et al.  Effect of photodeposited iron oxide and tin oxide on the consolidation of porous Vycor glass , 1990 .

[4]  D. Black,et al.  High‐resolution small‐angle X‐ray scattering camera for anomalous scattering , 1991 .

[5]  Jan Ilavsky,et al.  Nika : software for two-dimensional data reduction , 2012 .

[6]  Fan Zhang,et al.  Ultra‐small‐angle X‐ray scattering at the Advanced Photon Source , 2009 .

[7]  Sotiris E. Pratsinis,et al.  Structure of Flame-Made Silica Nanoparticles by Ultra-Small-Angle X-ray Scattering , 2004 .

[8]  L. Levine,et al.  Ultra-small-angle X-ray scattering-X-ray photon correlation spectroscopy studies of incipient structural changes in amorphous calcium phosphate-based dental composites. , 2012, Journal of biomedical materials research. Part A.

[9]  I. Fankuchen,et al.  X-Ray Examination of Pure Alumina Gel , 1949 .

[10]  Andrew G. Glen,et al.  APPL , 2001 .

[11]  A. Allen,et al.  Multi‐scale Microstructure Characterization of Solid Oxide Fuel Cell Assemblies With Ultra Small‐Angle X‐Ray Scattering , 2009 .

[12]  B. L. Weeks,et al.  Changes in Pore Size Distribution upon Thermal Cycling of TATB‐based Explosives Measured by Ultra‐Small Angle X‐Ray Scattering , 2006 .

[13]  J. Ilavsky,et al.  Lattice strain and damage evolution of 9-12%Cr ferritic/martensitic steel during in situ tensile test by X-ray diffraction and small angle scattering , 2010 .

[14]  P. Jemian Characterization of Steels by Anomalous Small - X-Ray Scattering. , 1990 .

[15]  P. Fauchais,et al.  Operating parameters for suspension and solution plasma-spray coatings , 2008 .

[16]  A. Allen,et al.  Application of USAXS Analysis and Non-interacting Approximation to Determine the Influence of Process Parameters and Ageing on the Thermal Conductivity of Electron-Beam Physical Vapor Deposited Thermal Barrier Coatings , 2007 .

[17]  U. Bonse,et al.  TAILLESS X‐RAY SINGLE‐CRYSTAL REFLECTION CURVES OBTAINED BY MULTIPLE REFLECTION , 1965 .

[18]  J. Ilavsky,et al.  Ostwald ripening of cobalt precipitates in silica aerogels? An ultra-small-angle X-ray scattering study , 2005 .

[19]  Pete R. Jemian,et al.  Irena: tool suite for modeling and analysis of small‐angle scattering , 2009 .

[20]  G. Beaucage,et al.  Morphology of Polyethylene-Carbon Black Composites , 1999 .

[21]  Pete R. Jemian,et al.  Silicon photodiode detector for small‐angle X‐ray scattering , 1990 .

[22]  J. Ilavsky,et al.  Ultra-Small-Angle X-ray Scattering of Polymers , 2010 .

[23]  L. Levine,et al.  Ultra-small-angle X-ray scattering from dislocation structures. , 2005, Acta crystallographica. Section A, Foundations of crystallography.

[24]  J. Ilavsky,et al.  Characterization of Complex Thermal Barrier Deposits Pore Microstructures by a Combination of Imaging, Scattering, and Intrusion Techniques , 2009, International Thermal Spray Conference.

[25]  L. Pruitt,et al.  The effects of hydrogen peroxide and sterilization on the structure of ultra high molecular weight polyethylene , 1998 .

[26]  L. Levine,et al.  Quantitative characterization of the contrast mechanisms of ultra-small angle x-ray scattering imaging. , 2008 .

[27]  A. Allen,et al.  In situ ultra-small-angle X-ray scattering study of the solution-mediated formation and growth of nanocrystalline ceria , 2008 .

[28]  L. Levine,et al.  Ultra-Small-Angle X-ray Scattering—X-ray Photon Correlation Spectroscopy: A New Measurement Technique for In-Situ Studies of Equilibrium and Nonequilibrium Dynamics , 2012, Metallurgical and Materials Transactions A.

[29]  Pete R. Jemian,et al.  Glassy Carbon as an Absolute Intensity Calibration Standard for Small-Angle Scattering , 2010 .

[30]  K. Littrell,et al.  Time‐of‐flight implementation of an ultra‐small‐angle neutron scattering instrument , 2003 .

[31]  G. G. Long,et al.  Non-cavitation tensile creep in Lu-doped silicon nitride , 2002 .

[32]  G. G. Long,et al.  Evolution of the void structure in plasma-sprayed YSZ deposits during heating , 1999 .

[33]  D. Black,et al.  Small-angle-scattering determination of the microstructure of porous silica precursor bodies , 1990 .

[34]  D. Black,et al.  Ultra-small-angle X-ray scattering to bridge the gap between visible light scattering and standard small-angle scattering cameras , 1994 .

[35]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[36]  G. Beaucage,et al.  How does surface modification aid in the dispersion of carbon nanofibers? , 2005, The journal of physical chemistry. B.

[37]  P. Fauchais,et al.  Quantification of void networks of as-sprayed and annealed nanostructured yttria-stabilized zirconia (YSZ) deposits manufactured by suspension plasma spraying , 2010 .

[38]  P. Fauchais,et al.  Porous Architecture of SPS Thick YSZ Coatings Structured at the Nanometer Scale (~50 nm) , 2010 .

[39]  M. Agamalian,et al.  Design and performance of a thermal-neutron double-crystal diffractometer for USANS at NIST , 2005 .

[40]  G. Beaucage,et al.  Probing the dynamics of nanoparticle growth in a flame using synchrotron radiation , 2004, Nature materials.

[41]  J. A. Lake,et al.  An iterative method of slit‐correcting small angle X‐ray data , 1967 .

[42]  T. Narayanan,et al.  Optimization of a Bonse-Hart instrument by suppressing surface parasitic scattering. , 2008, Journal of synchrotron radiation.

[43]  G. G. Long,et al.  Comprehensive microstructural characterization and predictive property modeling of plasma-sprayed zirconia coatings , 2003 .

[44]  T. Narayanan,et al.  SAXS and USAXS on the high brilliance beamline at the ESRF , 2001 .

[45]  J. Lewis,et al.  Quantitative measurement of nanoparticle halo formation around colloidal microspheres in binary mixtures. , 2008, Langmuir.

[46]  G. G. Long,et al.  Microstructure-Property Correlations in Industrial Thermal Barrier Coatings , 2004 .

[47]  L. Levine,et al.  Development of ultra-small-angle X-ray scattering–X-ray photon correlation spectroscopy , 2011 .